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Title: Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation

Abstract

Initial steps of bimetallic Ru-Os cluster formation on MgO in the presence of H{sub 2} are analyzed by EXAFS and IR spectroscopy. Ru-Os bond formation takes place after decarbonylation of Ru{sub 3} clusters and subsequently, at higher temperatures, of Os{sub 3} clusters to generate coordinative unsaturation.

Authors:
;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1006017
Resource Type:
Journal Article
Journal Name:
Angew. Chem. Int. Ed.
Additional Journal Information:
Journal Volume: 48; Journal Issue: (51) ; 11, 2009; Journal ID: ISSN 1433-7851
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MOLECULAR CLUSTERS; RUTHENIUM; OSMIUM; SUBSTRATES; MAGNESIUM OXIDES; HYDROGEN; CARBONYLS; SPECTROSCOPY; CHEMICAL BONDS

Citation Formats

Kulkarni, A, Gates, B C, and UCD). Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation. United States: N. p., 2009. Web. doi:10.1002/anie.200904877.
Kulkarni, A, Gates, B C, & UCD). Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation. United States. https://doi.org/10.1002/anie.200904877
Kulkarni, A, Gates, B C, and UCD). 2009. "Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation". United States. https://doi.org/10.1002/anie.200904877.
@article{osti_1006017,
title = {Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation},
author = {Kulkarni, A and Gates, B C and UCD)},
abstractNote = {Initial steps of bimetallic Ru-Os cluster formation on MgO in the presence of H{sub 2} are analyzed by EXAFS and IR spectroscopy. Ru-Os bond formation takes place after decarbonylation of Ru{sub 3} clusters and subsequently, at higher temperatures, of Os{sub 3} clusters to generate coordinative unsaturation.},
doi = {10.1002/anie.200904877},
url = {https://www.osti.gov/biblio/1006017}, journal = {Angew. Chem. Int. Ed.},
issn = {1433-7851},
number = (51) ; 11, 2009,
volume = 48,
place = {United States},
year = {Wed Dec 23 00:00:00 EST 2009},
month = {Wed Dec 23 00:00:00 EST 2009}
}