Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation
Abstract
Initial steps of bimetallic Ru-Os cluster formation on MgO in the presence of H{sub 2} are analyzed by EXAFS and IR spectroscopy. Ru-Os bond formation takes place after decarbonylation of Ru{sub 3} clusters and subsequently, at higher temperatures, of Os{sub 3} clusters to generate coordinative unsaturation.
- Authors:
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1006017
- Resource Type:
- Journal Article
- Journal Name:
- Angew. Chem. Int. Ed.
- Additional Journal Information:
- Journal Volume: 48; Journal Issue: (51) ; 11, 2009; Journal ID: ISSN 1433-7851
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MOLECULAR CLUSTERS; RUTHENIUM; OSMIUM; SUBSTRATES; MAGNESIUM OXIDES; HYDROGEN; CARBONYLS; SPECTROSCOPY; CHEMICAL BONDS
Citation Formats
Kulkarni, A, Gates, B C, and UCD). Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation. United States: N. p., 2009.
Web. doi:10.1002/anie.200904877.
Kulkarni, A, Gates, B C, & UCD). Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation. United States. https://doi.org/10.1002/anie.200904877
Kulkarni, A, Gates, B C, and UCD). 2009.
"Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation". United States. https://doi.org/10.1002/anie.200904877.
@article{osti_1006017,
title = {Spectroscopic Elucidation of First Steps of Supported Bimetallic Cluster Formation},
author = {Kulkarni, A and Gates, B C and UCD)},
abstractNote = {Initial steps of bimetallic Ru-Os cluster formation on MgO in the presence of H{sub 2} are analyzed by EXAFS and IR spectroscopy. Ru-Os bond formation takes place after decarbonylation of Ru{sub 3} clusters and subsequently, at higher temperatures, of Os{sub 3} clusters to generate coordinative unsaturation.},
doi = {10.1002/anie.200904877},
url = {https://www.osti.gov/biblio/1006017},
journal = {Angew. Chem. Int. Ed.},
issn = {1433-7851},
number = (51) ; 11, 2009,
volume = 48,
place = {United States},
year = {Wed Dec 23 00:00:00 EST 2009},
month = {Wed Dec 23 00:00:00 EST 2009}
}
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