Selective Bifunctional Modification of a Non-catenated Metal-Organic Framework Material via 'Click' Chemistry
A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using 'click' chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were 'clicked' onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 1005950
- Journal Information:
- J. Am. Chem. Soc., Vol. 131, Issue (38) ; 09, 2009; ISSN 0002-7863
- Country of Publication:
- United States
- Language:
- ENGLISH
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