Synthesis and Structure - Property Relationships for Regular Multigraft Copolymers

Journal Article · Thu Jan 01 00:00:00 EST 2004 · Macromolecular Symposia

DOI:https://doi.org/10.1002/masy.200451110· OSTI ID:1003183

Mays, Jimmy ^[1]; Uhrig, David ^[1]; Gido, Samuel ^[2]; Zhu, Yuqing ^[2]; Weidisch, Roland ^[3]; Iatrou, Hermis ^[4]; Hadjichristidis, Nikos ^[4]; Hong, Kunlun ^[1]; Beyer, Frederick ^[5]; Lach, Ralph ^[6]; Buschnakowski, Matthew ^[7]

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1. ORNL
2. University of Massachusetts, Amherst
3. Polymer Research Institute, Dresden Germany
4. University of Athens, Athens, Greece
5. U.S. Army research Laboratory, Adelphi, MD
6. Polymer Research Institute, Dresden Germany / University Halle-Wittenberg
7. University Halle-Wittenberg, Halle Germany

Multigraft copolymers with polyisoprene backbones and polystyrene branches, having multiple regularly spaced branch points, were synthesized by anionic polymerization high vacuum techniques and controlled chlorosilane linking chemistry. The functionality of the branch points (1, 2 and 4) can be controlled, through the choice of chlorosilane linking agent. The morphologies of the various graft copolymers were investigated by transmission electron microscopy and X-ray scattering. It was concluded that the morphology of these complex architectures is governed by the behavior of the corresponding miktoarm star copolymer associated with each branch point (constituting block copolymer), which follows Milner's theoretical treatment for miktoarm stars. By comparing samples having the same molecular weight backbone and branches but different number of branches it was found that the extent of long range order decreases with increasing number of branch points. The stress-strain properties in tension were investigated for some of these multigraft copolymers. For certain compositions thermoplastic elastomer (TPE) behavior was observed, and in many instances the elongation at break was much higher (2-3X) than that of conventional triblock TPEs.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: DE-AC05-00OR22725
• OSTI ID: 1003183
• Journal Information: Macromolecular Symposia, Vol. 215, Issue 1; ISSN 1022--1360
• Country of Publication: United States
• Language: English

Related Subjects

71 CLASSICAL AND QUANTUM MECHANICS
GENERAL PHYSICS
BEHAVIOR
CHEMISTRY
COPOLYMERS
ELASTOMERS
ELONGATION
GRAFTS
MOLECULAR WEIGHT
MORPHOLOGY
POLYISOPRENE
POLYMERIZATION
POLYSTYRENE
RANGE
SCATTERING
STARS
SYNTHESIS
THERMOPLASTICS
TRANSMISSION ELECTRON MICROSCOPY