X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface
Abstract
Adsorption of diaza-18-crown-6 ether substituted with two tetracosane (-C{sub 24}H{sub 49}) alkyl chains (ACE-24) was investigated at the liquid-liquid interface. X-ray reflectivity measurements determined the structure of a close-packed monolayer at the hexane-water interface, which is consistent with conclusions drawn indirectly from earlier interfacial tension measurements on similar molecules. These data provide further insights into the role of interfacial processes involving azacrown ethers in ion separation techniques such as the permeation liquid membrane.
- Authors:
-
- Warsaw
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1002297
- Resource Type:
- Journal Article
- Journal Name:
- Chemical Physics Letters
- Additional Journal Information:
- Journal Volume: 487; Journal Issue: (1-3) ; 02, 2010; Journal ID: ISSN 0009-2614
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ADSORPTION; CROWN ETHERS; INTERFACES; X-RAY SPECTROSCOPY; REFLECTIVITY; HEXANE; WATER
Citation Formats
Wojciechowski, Kamil, Gutberlet, Thomas, Tikhonov, Aleksey, Kashimoto, Kaoru, Schlossman, Mark, Julich), Russ. Acad. Sci.), Kyushu), and UIC). X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface. United States: N. p., 2010.
Web. doi:10.1016/j.cplett.2010.01.017.
Wojciechowski, Kamil, Gutberlet, Thomas, Tikhonov, Aleksey, Kashimoto, Kaoru, Schlossman, Mark, Julich), Russ. Acad. Sci.), Kyushu), & UIC). X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface. United States. https://doi.org/10.1016/j.cplett.2010.01.017
Wojciechowski, Kamil, Gutberlet, Thomas, Tikhonov, Aleksey, Kashimoto, Kaoru, Schlossman, Mark, Julich), Russ. Acad. Sci.), Kyushu), and UIC). 2010.
"X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface". United States. https://doi.org/10.1016/j.cplett.2010.01.017.
@article{osti_1002297,
title = {X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface},
author = {Wojciechowski, Kamil and Gutberlet, Thomas and Tikhonov, Aleksey and Kashimoto, Kaoru and Schlossman, Mark and Julich) and Russ. Acad. Sci.) and Kyushu) and UIC)},
abstractNote = {Adsorption of diaza-18-crown-6 ether substituted with two tetracosane (-C{sub 24}H{sub 49}) alkyl chains (ACE-24) was investigated at the liquid-liquid interface. X-ray reflectivity measurements determined the structure of a close-packed monolayer at the hexane-water interface, which is consistent with conclusions drawn indirectly from earlier interfacial tension measurements on similar molecules. These data provide further insights into the role of interfacial processes involving azacrown ethers in ion separation techniques such as the permeation liquid membrane.},
doi = {10.1016/j.cplett.2010.01.017},
url = {https://www.osti.gov/biblio/1002297},
journal = {Chemical Physics Letters},
issn = {0009-2614},
number = (1-3) ; 02, 2010,
volume = 487,
place = {United States},
year = {Tue Mar 16 00:00:00 EDT 2010},
month = {Tue Mar 16 00:00:00 EDT 2010}
}
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