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Title: X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface

Abstract

Adsorption of diaza-18-crown-6 ether substituted with two tetracosane (-C{sub 24}H{sub 49}) alkyl chains (ACE-24) was investigated at the liquid-liquid interface. X-ray reflectivity measurements determined the structure of a close-packed monolayer at the hexane-water interface, which is consistent with conclusions drawn indirectly from earlier interfacial tension measurements on similar molecules. These data provide further insights into the role of interfacial processes involving azacrown ethers in ion separation techniques such as the permeation liquid membrane.

Authors:
; ; ; ;  [1]
  1. Warsaw
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE
OSTI Identifier:
1002297
Resource Type:
Journal Article
Journal Name:
Chemical Physics Letters
Additional Journal Information:
Journal Volume: 487; Journal Issue: (1-3) ; 02, 2010; Journal ID: ISSN 0009-2614
Publisher:
Elsevier
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ADSORPTION; CROWN ETHERS; INTERFACES; X-RAY SPECTROSCOPY; REFLECTIVITY; HEXANE; WATER

Citation Formats

Wojciechowski, Kamil, Gutberlet, Thomas, Tikhonov, Aleksey, Kashimoto, Kaoru, Schlossman, Mark, Julich), Russ. Acad. Sci.), Kyushu), and UIC). X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface. United States: N. p., 2010. Web. doi:10.1016/j.cplett.2010.01.017.
Wojciechowski, Kamil, Gutberlet, Thomas, Tikhonov, Aleksey, Kashimoto, Kaoru, Schlossman, Mark, Julich), Russ. Acad. Sci.), Kyushu), & UIC). X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface. United States. https://doi.org/10.1016/j.cplett.2010.01.017
Wojciechowski, Kamil, Gutberlet, Thomas, Tikhonov, Aleksey, Kashimoto, Kaoru, Schlossman, Mark, Julich), Russ. Acad. Sci.), Kyushu), and UIC). 2010. "X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface". United States. https://doi.org/10.1016/j.cplett.2010.01.017.
@article{osti_1002297,
title = {X-ray Reflectivity Study of the Adsorption of Azacrown Ether at Liquid-liquid Interface},
author = {Wojciechowski, Kamil and Gutberlet, Thomas and Tikhonov, Aleksey and Kashimoto, Kaoru and Schlossman, Mark and Julich) and Russ. Acad. Sci.) and Kyushu) and UIC)},
abstractNote = {Adsorption of diaza-18-crown-6 ether substituted with two tetracosane (-C{sub 24}H{sub 49}) alkyl chains (ACE-24) was investigated at the liquid-liquid interface. X-ray reflectivity measurements determined the structure of a close-packed monolayer at the hexane-water interface, which is consistent with conclusions drawn indirectly from earlier interfacial tension measurements on similar molecules. These data provide further insights into the role of interfacial processes involving azacrown ethers in ion separation techniques such as the permeation liquid membrane.},
doi = {10.1016/j.cplett.2010.01.017},
url = {https://www.osti.gov/biblio/1002297}, journal = {Chemical Physics Letters},
issn = {0009-2614},
number = (1-3) ; 02, 2010,
volume = 487,
place = {United States},
year = {Tue Mar 16 00:00:00 EDT 2010},
month = {Tue Mar 16 00:00:00 EDT 2010}
}