Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase

Bittner, Dror M.; Zaleski, Daniel P.; Tew, David P.; Walker, Nicholas R.; Legon, Anthony C.

doi:10.1002/anie.201511646

Title: Highly Unsaturated Platinum and Palladium Carbenes PtC₃ and PdC₃ Isolated and Characterized in the Gas Phase

Abstract

Carbenes of platinum and palladium, PtC₃ and PdC₃ , were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and abinitio calculations confirm that both molecules are linear. The geometry of PtC₃ was accurately determined by fitting to the experimental moments of inertia of twenty-six isotopologues. In conclusion, the results are consistent with the proposal of an autogenic isolobal relationship between O, Au⁺ , and Ptatoms.

Authors:

^[1];

^[2];

^[3];

^[1];

^[3]

Newcastle Univ., Newcastle upon Tyne (United Kingdom)
Newcastle Univ., Newcastle upon Tyne (United Kingdom); Argonne National Lab. (ANL), Argonne, IL (United States)
Bristol Univ. (United Kingdom)

Publication Date:: Tue Feb 16 00:00:00 EST 2016

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE; European Research Council (ERC); Engineering and Physical Sciences Research Council (EPSRC)

OSTI Identifier:: 1261130

Grant/Contract Number:: CPFTMW-307000; EPK5028931

Resource Type:: Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition); Journal Volume: 55; Journal Issue: 11; Journal ID: ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; ab initio calculations; carbenes; palladium; platinum; rotational spectroscopy

Citation Formats


                    Bittner, Dror M., Zaleski, Daniel P., Tew, David P., Walker, Nicholas R., and Legon, Anthony C. Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase.  United States: N. p., 2016. 
Web.  doi:10.1002/anie.201511646.

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                    Bittner, Dror M., Zaleski, Daniel P., Tew, David P., Walker, Nicholas R., & Legon, Anthony C. Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase.  United States.  https://doi.org/10.1002/anie.201511646

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                    Bittner, Dror M., Zaleski, Daniel P., Tew, David P., Walker, Nicholas R., and Legon, Anthony C. Tue .  
"Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase".  United States.  https://doi.org/10.1002/anie.201511646.  https://www.osti.gov/servlets/purl/1261130.

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@article{osti_1261130,

  title        = {Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase},

  author       = {Bittner, Dror M. and Zaleski, Daniel P. and Tew, David P. and Walker, Nicholas R. and Legon, Anthony C.},

  abstractNote = {Carbenes of platinum and palladium, PtC3 and PdC3 , were generated in the gas phase through laser vaporization of a metal target in the presence of a low concentration of a hydrocarbon precursor undergoing supersonic expansion. Rotational spectroscopy and abinitio calculations confirm that both molecules are linear. The geometry of PtC3 was accurately determined by fitting to the experimental moments of inertia of twenty-six isotopologues. In conclusion, the results are consistent with the proposal of an autogenic isolobal relationship between O, Au+ , and Ptatoms.},

  doi          = {10.1002/anie.201511646},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 11,

  volume       = 55,

  place        = {United States},

  year         = {Tue Feb 16 00:00:00 EST 2016},

  month        = {Tue Feb 16 00:00:00 EST 2016}

}

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Works referencing / citing this record:

Regulating PdC3/PtC3···thiophene interaction by small molecule doping (AgOTf, CuBr, CuI, CuBr2, PdCl2)
journal, June 2019

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Automated assignment of rotational spectra using artificial neural networks
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Title: Highly Unsaturated Platinum and Palladium Carbenes PtC3 and PdC3 Isolated and Characterized in the Gas Phase

Abstract

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Title: Highly Unsaturated Platinum and Palladium Carbenes PtC₃ and PdC₃ Isolated and Characterized in the Gas Phase

Photodissociation of Noble Metal-Doped Carbon Clusters
journal, December 2008

Platinum Group Metal Clusters: From Gas-Phase Structures and Reactivities towards Model Catalysts
journal, February 2014

Activated Methane on Small Cationic Platinum Clusters
journal, December 2011

Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear Bis(1,3-butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)]
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journal, September 1995

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journal, July 1985

The rotational spectrum, nuclear field shift effects, 195Pt nuclear spin–rotation constant, and electric dipole moment of PtSi
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journal, July 2011

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journal, August 1994

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journal, June 2001

Microwave Spectrum, Geometry, and Hyperfine Constants of PdCO
journal, June 2002

Infrared Spectra of Platinum Insertion and Methylidene Complexes Prepared in Oxidative C−H(X) Reactions of Laser-Ablated Pt Atoms with Methane, Ethane, and Halomethanes
journal, March 2009

Fourier transform microwave/millimeter-wave spectroscopy of the ScC2 (X̃2A1) radical: A model system for endohedral metallofullerenes
journal, August 2014

A perspective on chemistry in transient plasma from broadband rotational spectroscopy
journal, January 2014

Fourier transform infrared observation of the ν3(σu) vibration of NiC3Ni in solid Ar
journal, February 2008

Pure Rotational Spectrum and Structure of Platinum Monocarbonyl, PtCO
journal, October 2001

Aktiviertes Methan auf kleinen Platinclusterkationen
journal, December 2011

A supersonic molecular beam spectroscopic study of platinum monocarbide, PtC
journal, April 1995

Spectroscopy of Ethylenedione
journal, June 2015

Gas-Phase Structure Determination of Dihydroxycarbene, One of the Smallest Stable Singlet Carbenes
journal, March 2014

A fifth-order perturbation comparison of electron correlation theories
journal, May 1989

Gas-Phase Structure Determination of Dihydroxycarbene, one of the Smallest Stable Singlet Carbenes
conference, June 2014

Regulating PdC3/PtC3···thiophene interaction by small molecule doping (AgOTf, CuBr, CuI, CuBr2, PdCl2)
journal, June 2019

Automated assignment of rotational spectra using artificial neural networks
journal, September 2018

Automated Assignment of Rotational Spectra Using Artificial Neural Networks
conference, June 2018