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Title: Reversible conversion of dominant polarity in ambipolar polymer/graphene oxide hybrids

Abstract

The possibility to selectively modulate the charge carrier transport in semiconducting materials is extremely challenging for the development of high performance and low-power consuming logic circuits. Systematical control over the polarity (electrons and holes) in transistor based on solution processed layer by layer polymer/graphene oxide hybrid system has been demonstrated. The conversion degree of the polarity is well controlled and reversible by trapping the opposite carriers. Basically, an electron device is switched to be a hole only device or vice versa. Finally, a hybrid layer ambipolar inverter is demonstrated in which almost no leakage of opposite carrier is found. This hybrid material has wide range of applications in planar p-n junctions and logic circuits for high-throughput manufacturing of printed electronic circuits.

Authors:
 [1];  [1];  [2];  [3];  [4];  [3];  [5]
  1. City Univ. of Hong Kong, Hong Kong (China)
  2. Queensland Univ. of Technology, Brisbane (Australia)
  3. The Hong Kong Polytechnic Univ., Hong Kong (China)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  5. City Univ. of Hong Kong, Hong Kong (China); City Univ. of Hong Kong, Shenzhen (China)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1259695
Alternate Identifier(s):
OSTI ID: 1286902
Grant/Contract Number:  
7004012; AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 5; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; electronic devices; electronic properties and materials

Citation Formats

Zhou, Ye, Han, Su -Ting, Sonar, Prashant, Ma, Xinlei, Chen, Jihua, Zheng, Zijian, and Roy, V. A. L. Reversible conversion of dominant polarity in ambipolar polymer/graphene oxide hybrids. United States: N. p., 2015. Web. doi:10.1038/srep09446.
Zhou, Ye, Han, Su -Ting, Sonar, Prashant, Ma, Xinlei, Chen, Jihua, Zheng, Zijian, & Roy, V. A. L. Reversible conversion of dominant polarity in ambipolar polymer/graphene oxide hybrids. United States. https://doi.org/10.1038/srep09446
Zhou, Ye, Han, Su -Ting, Sonar, Prashant, Ma, Xinlei, Chen, Jihua, Zheng, Zijian, and Roy, V. A. L. Tue . "Reversible conversion of dominant polarity in ambipolar polymer/graphene oxide hybrids". United States. https://doi.org/10.1038/srep09446. https://www.osti.gov/servlets/purl/1259695.
@article{osti_1259695,
title = {Reversible conversion of dominant polarity in ambipolar polymer/graphene oxide hybrids},
author = {Zhou, Ye and Han, Su -Ting and Sonar, Prashant and Ma, Xinlei and Chen, Jihua and Zheng, Zijian and Roy, V. A. L.},
abstractNote = {The possibility to selectively modulate the charge carrier transport in semiconducting materials is extremely challenging for the development of high performance and low-power consuming logic circuits. Systematical control over the polarity (electrons and holes) in transistor based on solution processed layer by layer polymer/graphene oxide hybrid system has been demonstrated. The conversion degree of the polarity is well controlled and reversible by trapping the opposite carriers. Basically, an electron device is switched to be a hole only device or vice versa. Finally, a hybrid layer ambipolar inverter is demonstrated in which almost no leakage of opposite carrier is found. This hybrid material has wide range of applications in planar p-n junctions and logic circuits for high-throughput manufacturing of printed electronic circuits.},
doi = {10.1038/srep09446},
journal = {Scientific Reports},
number = ,
volume = 5,
place = {United States},
year = {Tue Mar 24 00:00:00 EDT 2015},
month = {Tue Mar 24 00:00:00 EDT 2015}
}

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Cited by: 16 works
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journal, January 2012

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Controlled charge trapping by molybdenum disulphide and graphene in ultrathin heterostructured memory devices
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Highly stable organic polymer field-effect transistor sensor for selective detection in the marine environment
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Large-scale complementary macroelectronics using hybrid integration of carbon nanotubes and IGZO thin-film transistors
journal, June 2014

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  • DOI: 10.1038/ncomms5097

Fully-printed high-performance organic thin-film transistors and circuitry on one-micron-thick polymer films
journal, June 2014

  • Fukuda, Kenjiro; Takeda, Yasunori; Yoshimura, Yudai
  • Nature Communications, Vol. 5, Issue 1
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Organic light-emitting transistors with an efficiency that outperforms the equivalent light-emitting diodes
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  • Capelli, Raffaella; Toffanin, Stefano; Generali, Gianluca
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Synthesis of monolithic graphene–graphite integrated electronics
journal, November 2011

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  • Nature Materials, Vol. 11, Issue 2
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Vertically stacked multi-heterostructures of layered materials for logic transistors and complementary inverters
journal, December 2012

  • Yu, Woo Jong; Li, Zheng; Zhou, Hailong
  • Nature Materials, Vol. 12, Issue 3
  • DOI: 10.1038/nmat3518

Solution-processed ambipolar organic field-effect transistors and inverters
journal, September 2003

  • Meijer, E. J.; de Leeuw, D. M.; Setayesh, S.
  • Nature Materials, Vol. 2, Issue 10
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Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material
journal, April 2008

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Ambipolar field effect in the ternary topological insulator (BixSb1–x)2Te3 by composition tuning
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Detecting the translocation of DNA through a nanopore using graphene nanoribbons
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Nonvolatile multilevel data storage memory device from controlled ambipolar charge trapping mechanism
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Works referencing / citing this record:

Recent Advances in Ambipolar Transistors for Functional Applications
journal, July 2019

  • Ren, Yi; Yang, Xiaoyang; Zhou, Li
  • Advanced Functional Materials, Vol. 29, Issue 40
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Recent Advances of Flexible Data Storage Devices Based on Organic Nanoscaled Materials
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Physical properties and device applications of graphene oxide
journal, January 2020


Ultralow bandgap molecular semiconductors for ambient-stable and solution-processable ambipolar organic field-effect transistors and inverters
journal, January 2017

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Physical properties and device applications of graphene oxide
text, January 2019