Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2
Abstract
We report prominent resonance Raman and photoluminescence spectroscopic differences between AA' and AB stacked bilayer molybdenum disulfide (MoS2) grown by chemical vapor deposition. Bilayer MoS2 islands consisting of the two stacking orders were obtained under identical growth conditions. Resonance Moreover, Raman and photoluminescence spectra of AA' and AB stacked bilayer MoS2 were obtained on Au nanopyramid surfaces under strong plasmon resonance. Both resonance Raman and photoluminescence spectra show distinct features indicating clear differences in interlayer interaction between these two phases. Finally, the implication of these findings on device applications based on spin and valley degrees of freedom will be discussed.
- Authors:
-
- Univ. of California, Los Angeles, CA (United States)
- Rice Univ., Houston, TX (United States)
- Southeast Univ., Nanjing (China). School of Energy and Environment; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Innovations for High Performance (IHP), Frankfurt (Germany)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Univ. of California, Los Angeles, CA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1252727
- Alternate Identifier(s):
- OSTI ID: 1286946
- Grant/Contract Number:
- W-7405-ENG-26; AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Nano
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 1936-0851
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; molybdenum disulfide; bilayer stacking; Au nanopyramids; photoluminescence; resonance Raman; 36 MATERIALS SCIENCE
Citation Formats
Xia, Ming, Li, Bo, Yin, Kuibo, Capellini, Giovanni, Niu, Gang, Gong, Yongji, Zhou, Wu, Ajayan, Pulickel M., and Xie, Ya -Hong. Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2. United States: N. p., 2015.
Web. doi:10.1021/acsnano.5b05474.
Xia, Ming, Li, Bo, Yin, Kuibo, Capellini, Giovanni, Niu, Gang, Gong, Yongji, Zhou, Wu, Ajayan, Pulickel M., & Xie, Ya -Hong. Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2. United States. https://doi.org/10.1021/acsnano.5b05474
Xia, Ming, Li, Bo, Yin, Kuibo, Capellini, Giovanni, Niu, Gang, Gong, Yongji, Zhou, Wu, Ajayan, Pulickel M., and Xie, Ya -Hong. Wed .
"Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2". United States. https://doi.org/10.1021/acsnano.5b05474. https://www.osti.gov/servlets/purl/1252727.
@article{osti_1252727,
title = {Spectroscopic signatures of AA' and AB stacking of chemical vapor deposited bilayer MoS2},
author = {Xia, Ming and Li, Bo and Yin, Kuibo and Capellini, Giovanni and Niu, Gang and Gong, Yongji and Zhou, Wu and Ajayan, Pulickel M. and Xie, Ya -Hong},
abstractNote = {We report prominent resonance Raman and photoluminescence spectroscopic differences between AA' and AB stacked bilayer molybdenum disulfide (MoS2) grown by chemical vapor deposition. Bilayer MoS2 islands consisting of the two stacking orders were obtained under identical growth conditions. Resonance Moreover, Raman and photoluminescence spectra of AA' and AB stacked bilayer MoS2 were obtained on Au nanopyramid surfaces under strong plasmon resonance. Both resonance Raman and photoluminescence spectra show distinct features indicating clear differences in interlayer interaction between these two phases. Finally, the implication of these findings on device applications based on spin and valley degrees of freedom will be discussed.},
doi = {10.1021/acsnano.5b05474},
journal = {ACS Nano},
number = 12,
volume = 9,
place = {United States},
year = {Wed Nov 04 00:00:00 EST 2015},
month = {Wed Nov 04 00:00:00 EST 2015}
}
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