Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries

Pezeshki, Alan M.; Fujimoto, Cy; Sun, Che -Nan; Mench, Matthew M.; Zawodzinski, Thomas A.; Tang, Z. J.

doi:10.1149/2.0201601jes

Title: Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries

Abstract

In this paper, we report on the performance of Diels Alder poly(phenylene) membranes in vanadium redox flow batteries. The membranes were functionalized with quaternary ammonium groups to form an anion exchange membrane (QDAPP) and with sulfonic acid groups to form a cation exchange membrane (SDAPP). Both membrane classes showed similar conductivities in the battery environment, suggesting that the ion conduction mechanism in the material is not strongly affected by the moieties along the polymer backbone. The resistance to vanadium permeation in QDAPP was not improved relative to SDAPP, further suggesting that the polarity of the functional groups do not play a significant role in the membrane materials tested. Both QDAPP and SDAPP outperformed Nafion membranes in cycling tests, with both achieving voltage efficiencies above 85% while maintaining 95% coulombic efficiency while at a current density of 200 mA/cm₂.

Authors:

Pezeshki, Alan M. ^[1]; Fujimoto, Cy ^[2]; Sun, Che -Nan ^[3]; Mench, Matthew M. ^[4]; Zawodzinski, Thomas A. ^[1]; Tang, Z. J. ^[1]

Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States)

Publication Date:: Sat Nov 14 00:00:00 EST 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1244190

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 163; Journal Issue: 1; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; flow batteries; membranes; vanadium

Citation Formats


                    Pezeshki, Alan M., Fujimoto, Cy, Sun, Che -Nan, Mench, Matthew M., Zawodzinski, Thomas A., and Tang, Z. J. Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries.  United States: N. p., 2015. 
Web.  doi:10.1149/2.0201601jes.

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                    Pezeshki, Alan M., Fujimoto, Cy, Sun, Che -Nan, Mench, Matthew M., Zawodzinski, Thomas A., & Tang, Z. J. Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries.  United States.  https://doi.org/10.1149/2.0201601jes

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                    Pezeshki, Alan M., Fujimoto, Cy, Sun, Che -Nan, Mench, Matthew M., Zawodzinski, Thomas A., and Tang, Z. J. Sat .  
"Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries".  United States.  https://doi.org/10.1149/2.0201601jes.  https://www.osti.gov/servlets/purl/1244190.

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@article{osti_1244190,

  title        = {Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries},

  author       = {Pezeshki, Alan M. and Fujimoto, Cy and Sun, Che -Nan and Mench, Matthew M. and Zawodzinski, Thomas A. and Tang, Z. J.},

  abstractNote = {In this paper, we report on the performance of Diels Alder poly(phenylene) membranes in vanadium redox flow batteries. The membranes were functionalized with quaternary ammonium groups to form an anion exchange membrane (QDAPP) and with sulfonic acid groups to form a cation exchange membrane (SDAPP). Both membrane classes showed similar conductivities in the battery environment, suggesting that the ion conduction mechanism in the material is not strongly affected by the moieties along the polymer backbone. The resistance to vanadium permeation in QDAPP was not improved relative to SDAPP, further suggesting that the polarity of the functional groups do not play a significant role in the membrane materials tested. Both QDAPP and SDAPP outperformed Nafion membranes in cycling tests, with both achieving voltage efficiencies above 85% while maintaining 95% coulombic efficiency while at a current density of 200 mA/cm2.},

  doi          = {10.1149/2.0201601jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 1,

  volume       = 163,

  place        = {United States},

  year         = {Sat Nov 14 00:00:00 EST 2015},

  month        = {Sat Nov 14 00:00:00 EST 2015}

}

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Title: Full cell study of Diels Alder poly(phenylene) anion and cation exchange membranes in vanadium redox flow batteries

Abstract

Citation Formats

Electrochemical Energy Storage for Green Grid journal, May 2011

Redox flow batteries a review journal, September 2011

Review of material research and development for vanadium redox flow battery applications journal, July 2013

Progress in Flow Battery Research and Development journal, June 2011

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Review of material research and development for vanadium redox flow battery applications
journal, July 2013

Progress in Flow Battery Research and Development
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Self-assembled polyelectrolyte multilayer modified Nafion membrane with suppressed vanadium ion crossover for vanadium redox flow batteries
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Nafion/organically modified silicate hybrids membrane for vanadium redox flow battery
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Composition and Conductivity of Membranes Equilibrated with Solutions of Sulfuric Acid and Vanadyl Sulfate
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journal, May 2012

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Transport Properties of Hydroxide and Proton Conducting Membranes
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Influence of cations on the proton leakage through anion-exchange membranes
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Transport mechanism of sulfuric acid through an anion exchange membrane
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Polymer Electrolyte Fuel Cell Model
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Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes
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Monitoring the State of Charge of Operating Vanadium Redox Flow Batteries
conference, January 2012

Investigations on transfer of water and vanadium ions across Nafion membrane in an operating vanadium redox flow battery
journal, February 2010

A Transient Vanadium Flow Battery Model Incorporating Vanadium Crossover and Water Transport through the Membrane
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