Glass-water interactions: Effect of high-valence cations on glass structure and chemical durability
Abstract
Spectroscopic measurements, dissolution experiments, and Monte Carlo simulations were performed to investigate the effect of high valence cations (HVC) on the mechanisms of glass dissolution under dilute and near-saturated conditions. Raman and NMR spectroscopy were used to determine the structural changes that occur in glass, specifically network formers (e.g., Al, Si, and B), with the addition of the HVC element hafnium in the Na2O Al2O3 B2O3 HfO2 SiO2 system (e.g., Na/(Al+B) = 1.0 and HfO2/SiO2 from 0.0 to 0.42). Spectroscopic measurements revealed that increasing hafnium content decreases N4 and increases the amount of Si–O–Hf moieties in the glass. Results from flow through experiments conducted under dilute and near saturated conditions show a decrease of approximately 100 or more in the dissolution rate over the series from 0 to 20 mol% HfO2. Comparing the average steady-state rates obtained under dilute conditions to the rates obtained for near-saturated conditions reveal a divergence in the magnitude between the average steady state rates measured in these different conditions. The reason for this divergence was investigated more thoroughly using Monte Carlo simulations. Simulations indicate that the divergence in glass dissolution behavior under dilute and near-saturated conditions result from the formation of a low coordination Simore »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Univ. Paris-Saclay, Saclay (France)
- CEA DEN Lab., d'Etude du Comportement a Long Terme (France)
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Environmental Management (EM)
- OSTI Identifier:
- 1241457
- Alternate Identifier(s):
- OSTI ID: 1359155
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Geochimica et Cosmochimica Acta
- Additional Journal Information:
- Journal Volume: 181; Journal Issue: C; Journal ID: ISSN 0016-7037
- Publisher:
- Elsevier; The Geochemical Society; The Meteoritical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES
Citation Formats
Pierce, Eric M., Kerisit, Sebastien N., Charpentier, Thibault, Angeli, Frederic, Icenhower, J. P., McGrail, B. Pete, Charles F. Windisch, Burton, Sarah D., and Hopf, Juliane. Glass-water interactions: Effect of high-valence cations on glass structure and chemical durability. United States: N. p., 2016.
Web. doi:10.1016/j.gca.2016.02.023.
Pierce, Eric M., Kerisit, Sebastien N., Charpentier, Thibault, Angeli, Frederic, Icenhower, J. P., McGrail, B. Pete, Charles F. Windisch, Burton, Sarah D., & Hopf, Juliane. Glass-water interactions: Effect of high-valence cations on glass structure and chemical durability. United States. https://doi.org/10.1016/j.gca.2016.02.023
Pierce, Eric M., Kerisit, Sebastien N., Charpentier, Thibault, Angeli, Frederic, Icenhower, J. P., McGrail, B. Pete, Charles F. Windisch, Burton, Sarah D., and Hopf, Juliane. Sat .
"Glass-water interactions: Effect of high-valence cations on glass structure and chemical durability". United States. https://doi.org/10.1016/j.gca.2016.02.023. https://www.osti.gov/servlets/purl/1241457.
@article{osti_1241457,
title = {Glass-water interactions: Effect of high-valence cations on glass structure and chemical durability},
author = {Pierce, Eric M. and Kerisit, Sebastien N. and Charpentier, Thibault and Angeli, Frederic and Icenhower, J. P. and McGrail, B. Pete and Charles F. Windisch and Burton, Sarah D. and Hopf, Juliane},
abstractNote = {Spectroscopic measurements, dissolution experiments, and Monte Carlo simulations were performed to investigate the effect of high valence cations (HVC) on the mechanisms of glass dissolution under dilute and near-saturated conditions. Raman and NMR spectroscopy were used to determine the structural changes that occur in glass, specifically network formers (e.g., Al, Si, and B), with the addition of the HVC element hafnium in the Na2O Al2O3 B2O3 HfO2 SiO2 system (e.g., Na/(Al+B) = 1.0 and HfO2/SiO2 from 0.0 to 0.42). Spectroscopic measurements revealed that increasing hafnium content decreases N4 and increases the amount of Si–O–Hf moieties in the glass. Results from flow through experiments conducted under dilute and near saturated conditions show a decrease of approximately 100 or more in the dissolution rate over the series from 0 to 20 mol% HfO2. Comparing the average steady-state rates obtained under dilute conditions to the rates obtained for near-saturated conditions reveal a divergence in the magnitude between the average steady state rates measured in these different conditions. The reason for this divergence was investigated more thoroughly using Monte Carlo simulations. Simulations indicate that the divergence in glass dissolution behavior under dilute and near-saturated conditions result from the formation of a low coordination Si sites when Si from the saturated solution adsorbs to Hf on the glass surface. The residence time of the newly formed low coordination Si sites is longer at the glass surface and increases the density of anchor sites from which altered layers with higher Si densities can form than in the absence of Hf. These results illustrate the importance of understanding solid water/solid-fluid interactions by linking macroscopic reaction kinetics to nanometer scale interfacial processes.},
doi = {10.1016/j.gca.2016.02.023},
journal = {Geochimica et Cosmochimica Acta},
number = C,
volume = 181,
place = {United States},
year = {Sat Feb 27 00:00:00 EST 2016},
month = {Sat Feb 27 00:00:00 EST 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 31 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Testing the Grambow Glass Dissolution Model by Comparing it With Monte Carlo Simulation Results
journal, January 1999
- Aertsens, Marc
- MRS Proceedings, Vol. 556
Contribution of 43Ca MAS NMR for probing the structural configuration of calcium in glass
journal, June 2007
- Angeli, Frédéric; Gaillard, Marina; Jollivet, Patrick
- Chemical Physics Letters, Vol. 440, Issue 4-6
Influence of zirconium on the structure of pristine and leached soda-lime borosilicate glasses: Towards a quantitative approach by 17O MQMAS NMR
journal, August 2008
- Angeli, Frédéric; Charpentier, Thibault; Gaillard, Marina
- Journal of Non-Crystalline Solids, Vol. 354, Issue 31
Boron Speciation in Soda-Lime Borosilicate Glasses Containing Zirconium: Boron Speciation in Soda-Lime Borosilicate Glasses
journal, April 2010
- Angeli, Frédéric; Charpentier, Thibault; De Ligny, Dominique
- Journal of the American Ceramic Society, Vol. 93, Issue 9
Effect of temperature and thermal history on borosilicate glass structure
journal, February 2012
- Angeli, Frédéric; Villain, Olivier; Schuller, Sophie
- Physical Review B, Vol. 85, Issue 5
Aqueous alteration of five-oxide silicate glasses: Experimental approach and Monte Carlo modeling
journal, January 2008
- Arab, M.; Cailleteau, C.; Angeli, F.
- Journal of Non-Crystalline Solids, Vol. 354, Issue 2-9
Adsorption of Gases in Multimolecular Layers
journal, February 1938
- Brunauer, Stephen; Emmett, P. H.; Teller, Edward
- Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319
The effect of molecular structure on borosilicate glass leaching
journal, October 1986
- Bunker, B. C.; Arnold, G. W.; Day, D. E.
- Journal of Non-Crystalline Solids, Vol. 87, Issue 1-2
Waste Glass Corrosion Modeling: Comparison with Experimental Results
journal, January 1993
- Bourcier, William. L.
- MRS Proceedings, Vol. 333
First investigations of the influence of IVB elements (Ti, Zr, and Hf) on the chemical durability of soda-lime borosilicate glasses
journal, October 2010
- Bergeron, Boris; Galoisy, Laurence; Jollivet, Patrick
- Journal of Non-Crystalline Solids, Vol. 356, Issue 44-49
The Relationship Between Reaction Layer Thickness and Leach Rate For Nuclear Waste Glasses
journal, January 1983
- Chick, L. A.; Pederson, L. R.
- MRS Proceedings, Vol. 26
Competition for charge compensation in borosilicate glasses: Wide-angle x-ray scattering and molecular dynamics calculations
journal, June 2000
- Cormier, L.; Ghaleb, D.; Delaye, J. -M.
- Physical Review B, Vol. 61, Issue 21
Insight into silicate-glass corrosion mechanisms
journal, October 2008
- Cailleteau, Céline; Angeli, Frédéric; Devreux, François
- Nature Materials, Vol. 7, Issue 12
Why Do Certain Glasses with a High Dissolution Rate Undergo a Low Degree of Corrosion?
journal, March 2011
- Cailleteau, Céline; Devreux, François; Spalla, Olivier
- The Journal of Physical Chemistry C, Vol. 115, Issue 13
The structural role of Zr within alkali borosilicate glasses for nuclear waste immobilisation
journal, April 2011
- Connelly, A. J.; Hyatt, N. C.; Travis, K. P.
- Journal of Non-Crystalline Solids, Vol. 357, Issue 7
The Structural Properties of Cations in Nuclear Glasses
journal, January 2014
- Calas, Georges; Galoisy, Laurence; Cormier, Laurent
- Procedia Materials Science, Vol. 7
Hafnium in peralkaline and peraluminous boro-aluminosilicate glass and glass sub-components: a solubility study
journal, October 2003
- Davis, L. L.; Darab, J. G.; Qian, M.
- Journal of Non-Crystalline Solids, Vol. 328, Issue 1-3
Leaching of borosilicate glasses. II. Model and Monte-Carlo simulations
journal, September 2004
- Devreux, F.; Ledieu, A.; Barboux, P.
- Journal of Non-Crystalline Solids, Vol. 343, Issue 1-3
Site Preference and Si/B Mixing in Mixed-Alkali Borosilicate Glasses: A High-Resolution 11 B and 17 O NMR Study
journal, October 2003
- Du, Lin-Shu; Stebbins, Jonathan F.
- Chemistry of Materials, Vol. 15, Issue 20
Solid-state NMR study of metastable immiscibility in alkali borosilicate glasses
journal, January 2003
- Du, Lin-Shu; Stebbins, Jonathan F.
- Journal of Non-Crystalline Solids, Vol. 315, Issue 3
Network connectivity in aluminoborosilicate glasses: A high-resolution 11B, 27Al and 17O NMR study
journal, November 2005
- Du, Lin-Shu; Stebbins, Jonathan F.
- Journal of Non-Crystalline Solids, Vol. 351, Issue 43-45
Raman study of potassium silicate glasses containing Rb+, Sr2+, Y3+ and Zr4+: Implications for cation solution mechanisms in multicomponent silicate liquids
journal, April 1994
- Ellison, Adam J. G.; Hess, Paul C.
- Geochimica et Cosmochimica Acta, Vol. 58, Issue 8
Structural environments of incompatible elements in silicate glass/melt systems: I. Zirconium at trace levels
journal, June 1991
- Farges, François; Ponader, Carl W.; Brown, Gordon E.
- Geochimica et Cosmochimica Acta, Vol. 55, Issue 6
The effect of composition on the leaching of three nuclear waste glasses: R7T7, AVM and VRZ
journal, November 2005
- Frugier, Pierre; Martin, Christelle; Ribet, Isabelle
- Journal of Nuclear Materials, Vol. 346, Issue 2-3
First-order dissolution rate law and the role of surface layers in glass performance assessment
journal, September 2001
- Grambow, B.; Müller, R.
- Journal of Nuclear Materials, Vol. 298, Issue 1-2
Evidence for 6-Coordinated Zirconium in Inactive Nuclear Waste Glasses
journal, August 1999
- Galoisy, Laurence; Pélegrin, Emmanuèle; Arrio, Marie-Anne
- Journal of the American Ceramic Society, Vol. 82, Issue 8
Open Scientific Questions about Nuclear Glass Corrosion
journal, January 2014
- Gin, S.
- Procedia Materials Science, Vol. 7
Role and properties of the gel formed during nuclear glass alteration: importance of gel formation conditions
journal, September 2001
- Gin, S.; Ribet, I.; Couillard, M.
- Journal of Nuclear Materials, Vol. 298, Issue 1-2
An international initiative on long-term behavior of high-level nuclear waste glass
journal, June 2013
- Gin, S.; Abdelouas, A.; Criscenti, L. J.
- Materials Today, Vol. 16, Issue 6
Origin and consequences of silicate glass passivation by surface layers
journal, February 2015
- Gin, Stéphane; Jollivet, Patrick; Fournier, Maxime
- Nature Communications, Vol. 6, Issue 1
Coordination of boron in nominally boron-free rock forming silicates: Evidence for incorporation of BO3 groups in clinopyroxene
journal, October 2010
- Hålenius, Ulf; Skogby, Henrik; Edén, Mattias
- Geochimica et Cosmochimica Acta, Vol. 74, Issue 19
Movement of manganese contamination through the Critical Zone
journal, June 2011
- Herndon, Elizabeth M.; Brantley, Susan L.
- Applied Geochemistry, Vol. 26
Soils Reveal Widespread Manganese Enrichment from Industrial Inputs
journal, January 2011
- Herndon, Elizabeth M.; Jin, Lixin; Brantley, Susan L.
- Environmental Science & Technology, Vol. 45, Issue 1
Topography and Mechanical Property Mapping of International Simple Glass Surfaces with Atomic Force Microscopy
journal, January 2014
- Hopf, Juliane; Pierce, E. M.
- Procedia Materials Science, Vol. 7
Nanometre-scale evidence for interfacial dissolution–reprecipitation control of silicate glass corrosion
journal, January 2015
- Hellmann, Roland; Cotte, Stéphane; Cadel, Emmanuel
- Nature Materials, Vol. 14, Issue 3
Dissolution kinetics of pyrochlore ceramics for the disposition of plutonium
journal, January 2006
- Icenhower, Jonathan P.; Strachan, Denis M.; McGrail, B. Pete
- American Mineralogist, Vol. 91, Issue 1
Experimentally determined dissolution kinetics of Na-rich borosilicate glass at far from equilibrium conditions: Implications for Transition State Theory
journal, June 2008
- Icenhower, Jonathan P.; McGrail, B. Peter; Shaw, Wendy J.
- Geochimica et Cosmochimica Acta, Vol. 72, Issue 12
SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species, and reactions from 1 to 5000 bar and 0 to 1000°C
journal, August 1992
- Johnson, James W.; Oelkers, Eric H.; Helgeson, Harold C.
- Computers & Geosciences, Vol. 18, Issue 7
Alteration kinetics of a simplified nuclear glass in an aqueous medium: effects of solution chemistry and of protective gel properties on diminishing the alteration rate
journal, July 2000
- Jégou, C.; Gin, S.; Larché, F.
- Journal of Nuclear Materials, Vol. 280, Issue 2
Investigation of gel porosity clogging during glass leaching
journal, November 2008
- Jollivet, Patrick; Angeli, Frédéric; Cailleteau, Céline
- Journal of Non-Crystalline Solids, Vol. 354, Issue 45-46
An enhanced resolution of the structural environment of zirconium in borosilicate glasses
journal, December 2013
- Jollivet, P.; Calas, G.; Galoisy, L.
- Journal of Non-Crystalline Solids, Vol. 381
Monte Carlo simulations of the dissolution of borosilicate and aluminoborosilicate glasses in dilute aqueous solutions
journal, September 2011
- Kerisit, Sebastien; Pierce, Eric M.
- Geochimica et Cosmochimica Acta, Vol. 75, Issue 18
Monte Carlo simulations of the dissolution of borosilicate glasses in near-equilibrium conditions
journal, May 2012
- Kerisit, Sebastien; Pierce, Eric M.
- Journal of Non-Crystalline Solids, Vol. 358, Issue 10
Monte Carlo simulations of the corrosion of aluminoborosilicate glasses
journal, October 2013
- Kerisit, Sebastien; Ryan, Joseph V.; Pierce, Eric M.
- Journal of Non-Crystalline Solids, Vol. 378
Monte Carlo simulations of coupled diffusion and surface reactions during the aqueous corrosion of borosilicate glasses
journal, January 2015
- Kerisit, Sebastien; Pierce, Eric M.; Ryan, Joseph V.
- Journal of Non-Crystalline Solids, Vol. 408
Structural studies of silicates by solid-state high-resolution silicon-29 NMR
journal, July 1980
- Lippmaa, E.; Maegi, M.; Samoson, A.
- Journal of the American Chemical Society, Vol. 102, Issue 15
Investigation of the structure of zeolites by solid-state high-resolution silicon-29 NMR spectroscopy
journal, August 1981
- Lippmaa, E.; Maegi, M.; Samoson, A.
- Journal of the American Chemical Society, Vol. 103, Issue 17
Monte Carlo Modelling of Glass Dissolution: Comparison with Experiments
journal, January 2000
- Lobanova, M.; Maurer, L.; Barboux, P.
- MRS Proceedings, Vol. 663
29Si and 17O (Q)CPMG-MAS solid-state NMR experiments as an optimum approach for half-integer nuclei having long T1 relaxation times
journal, May 2002
- Larsen, Flemming H.; Farnan, Ian
- Chemical Physics Letters, Vol. 357, Issue 5-6
Xray Absorption Studies of Borosilicate Glasses Containing Dissolved Actinides or Surrogates
journal, January 2005
- C. Lopez, .; X. Deschanels, .; Auwer, C. Den
- Physica Scripta
Contribution of Monte Carlo Modeling to Understanding the Alteration of Nuclear Glasses by Water
journal, July 2006
- Ledieu, Aurélien; Devreux, François; Barboux, Philippe
- Nuclear Science and Engineering, Vol. 153, Issue 3
Microscopic reactive diffusion of uranium in the contaminated sediments at Hanford, United States: MICROSCOPIC REACTIVE DIFFUSION
journal, December 2006
- Liu, Chongxuan; Zachara, John M.; Yantasee, Wassana
- Water Resources Research, Vol. 42, Issue 12
Solid-state and solution structures of some lithium salts of tetraphenyldisiloxanediolate(2–) and the lithium-bridged compounds Li 2 [M(OSiPh 2 OSiPh 2 O) 3 ·3py](py = pyridine, M = Zr or Hf)
journal, January 1993
- Motevalli, Majid; Shah, Dipti; Sullivan, Alice C.
- J. Chem. Soc., Dalton Trans., Issue 18
Measurement of kinetic rate law parameters on a NaCaAl borosilicate glass for low-activity waste
journal, October 1997
- McGrail, B. P.; Ebert, W. L.; Bakel, A. J.
- Journal of Nuclear Materials, Vol. 249, Issue 2-3
The structure of Na2O–Al2O3–SiO2 glass: impact on sodium ion exchange in H2O and D2O
journal, December 2001
- McGrail, B. P.; Icenhower, J. P.; Shuh, D. K.
- Journal of Non-Crystalline Solids, Vol. 296, Issue 1-2
X-ray absorption studies of the local environment of Zr in high-zirconia borosilicate glasses
journal, November 1999
- McKeown, David A.; Muller, Isabelle S.; Buechele, Andrew C.
- Journal of Non-Crystalline Solids, Vol. 258, Issue 1-3
Structural characterization of high-zirconia borosilicate glasses using Raman spectroscopy
journal, February 2000
- McKeown, David A.; Muller, Isabelle S.; Buechele, Andrew C.
- Journal of Non-Crystalline Solids, Vol. 262, Issue 1-3
Two-dimensional one pulse MAS of half-integer quadrupolar nuclei
journal, August 2006
- Massiot, Dominique; Hiet, Julian; Pellerin, Nadia
- Journal of Magnetic Resonance, Vol. 181, Issue 2
The Principles Determining the Structure of Complex Ionic Crystals
journal, April 1929
- Pauling, Linus
- Journal of the American Chemical Society, Vol. 51, Issue 4
Combined Experimental and Computational Approach to Predict the Glass-Water Reaction
journal, October 2011
- Pierce, E. M.; Bacon, D. H.
- Nuclear Technology, Vol. 176, Issue 1
Experimental determination of UO2(cr) dissolution kinetics: Effects of solution saturation state and pH
journal, October 2005
- Pierce, E. M.; Icenhower, J. P.; Serne, R. J.
- Journal of Nuclear Materials, Vol. 345, Issue 2-3, p. 206-218
Aluminoborosilicate waste glass dissolution under alkaline conditions at 40°C: implications for a chemical affinity-based rate equation
journal, January 2008
- Pierce, E. M.; Richards, E. L.; Davis, A. M.
- Environmental Chemistry, Vol. 5, Issue 1
Experimental determination of the effect of the ratio of B/Al on glass dissolution along the nepheline (NaAlSiO4)–malinkoite (NaBSiO4) join
journal, May 2010
- Pierce, E. M.; Reed, L. R.; Shaw, W. J.
- Geochimica et Cosmochimica Acta, Vol. 74, Issue 9
Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations
journal, July 2014
- Pierce, Eric M.; Frugier, Pierre; Criscenti, Louise J.
- International Journal of Applied Glass Science, Vol. 5, Issue 4
NMR Study of a Rare-Earth Aluminoborosilicate Glass with Varying CaO-to-Na2O Ratio
journal, December 2007
- Quintas, A.; Charpentier, T.; Majérus, O.
- Applied Magnetic Resonance, Vol. 32, Issue 4
Bond valence in silicate glasses
journal, June 2002
- Rossano, S.; Farges, F.; Ramos, A.
- Journal of Non-Crystalline Solids, Vol. 304, Issue 1-3
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Reactive transport modeling: An essential tool and a new research approach for the Earth sciences
journal, December 2005
- Steefel, C.; Depaolo, D.; Lichtner, P.
- Earth and Planetary Science Letters, Vol. 240, Issue 3-4
Contribution of first-principles calculations to multinuclear NMR analysis of borosilicate glasses
journal, September 2010
- Soleilhavoup, Anne; Delaye, Jean-Marc; Angeli, Frédéric
- Magnetic Resonance in Chemistry, Vol. 48, Issue S1
Effects of pH, temperature, and aqueous organic material on the dissolution kinetics of meta-autunite minerals, (Na, Ca) 2−1 [(UO 2 )(PO 4 )] 2 · 3H 2 O
journal, January 2006
- Wellman, Dawn M.; Icenhower, Jonathan P.; Gamerdinger, Amy P.
- American Mineralogist, Vol. 91, Issue 1
Deep-UV Raman spectroscopic analysis of structure and dissolution rates of silica-rich sodium borosilicate glasses
journal, May 2011
- Windisch, Charles F.; Pierce, Eric M.; Burton, Sarah D.
- Journal of Non-Crystalline Solids, Vol. 357, Issue 10
Chromium speciation and mobility in a high level nuclear waste vadose zone plume
journal, January 2004
- Zachara, John M.; Ainsworth, Calvin C.; Brown, Gordon E.
- Geochimica et Cosmochimica Acta, Vol. 68, Issue 1
Energetics of dissolution of Gd2O3 and HfO2 in sodium alumino-borosilicate glasses
journal, December 2001
- Zhang, Yahong; Navrotsky, Alexandra; Li, Hong
- Journal of Non-Crystalline Solids, Vol. 296, Issue 1-2
Works referencing / citing this record:
Structural study of Na 2 O–B 2 O 3 –SiO 2 glasses from molecular simulations using a polarizable force field
journal, October 2017
- Pacaud, Fabien; Delaye, Jean-Marc; Charpentier, Thibault
- The Journal of Chemical Physics, Vol. 147, Issue 16
Molecular Dynamics Simulation of Water Confinement in Disordered Aluminosilicate Subnanopores
journal, February 2018
- Ohkubo, Takahiro; Gin, Stéphane; Collin, Marie
- Scientific Reports, Vol. 8, Issue 1
Corrosion of the International Simple Glass under acidic to hyperalkaline conditions
journal, September 2018
- Backhouse, Daniel J.; Fisher, Adam J.; Neeway, James J.
- npj Materials Degradation, Vol. 2, Issue 1
Effect of thermally induced structural disorder on the chemical durability of International Simple Glass
journal, September 2018
- Angeli, Frederic; Charpentier, Thibault; Jollivet, Patrick
- npj Materials Degradation, Vol. 2, Issue 1
Dissolution of silica component of glass network at early stage of corrosion in initially silica‐saturated solution
journal, May 2019
- Ngo, Dien; Liu, Hongshen; Kaya, Huseyin
- Journal of the American Ceramic Society, Vol. 102, Issue 11
Molecular Dynamics Simulation of Water Confinement in Disordered Aluminosilicate Subnanopores
journal, February 2018
- Ohkubo, Takahiro; Gin, Stéphane; Collin, Marie
- Scientific Reports, Vol. 8, Issue 1