In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures
Abstract
In this study, the use of maltodextrin supramolecular structures (MD SMS) as a reducing agent and colloidal stabilizing agent for the synthesis of Ag nanoparticles (Ag NPs) identified three key points. First, the maltodextrin (MD) solutions are effective in the formation of well-dispersed Ag NPs utilizing alkaline solution conditions, with the resulting Ag NPs ranging in size from 5 to 50 nm diameter. Second, in situ characterization by Raman spectroscopy and small angle X-ray scattering (SAXS) are consistent with initial nucleation of Ag NPs within the MD SMS up to a critical size of ca. 1 nm, followed by a transition to more rapid growth by aggregation and fusion between MD SMS, similar to micelle aggregation reactions. Third, the stabilization of larger Ag NPs by adsorbed MD SMS is similar to hemi-micelle stabilization, and monomodal size distributions are proposed to relate to integer surface coverage of the Ag NPs. Conditions were identified for preparing Ag NPs with monomodal distributions centered at 30–35 nm Ag NPs.
- Authors:
-
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Univ. of New Mexico, Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1236240
- Alternate Identifier(s):
- OSTI ID: 1358968
- Report Number(s):
- SAND-2015-1001J
Journal ID: ISSN 0927-7765; 566969
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Colloids and Surfaces. B, Biointerfaces
- Additional Journal Information:
- Journal Volume: 134; Journal Issue: C; Journal ID: ISSN 0927-7765
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; silver; nanoparticles; maltodextrin; synthesis; in situ
Citation Formats
Bell, Nelson S., Dunphy, Darren R., Lambert, Timothy N., Lu, Ping, and Boyle, Timothy J. In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures. United States: N. p., 2015.
Web. doi:10.1016/j.colsurfb.2015.06.030.
Bell, Nelson S., Dunphy, Darren R., Lambert, Timothy N., Lu, Ping, & Boyle, Timothy J. In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures. United States. https://doi.org/10.1016/j.colsurfb.2015.06.030
Bell, Nelson S., Dunphy, Darren R., Lambert, Timothy N., Lu, Ping, and Boyle, Timothy J. Fri .
"In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures". United States. https://doi.org/10.1016/j.colsurfb.2015.06.030. https://www.osti.gov/servlets/purl/1236240.
@article{osti_1236240,
title = {In situ characterization of silver nanoparticle synthesis in maltodextrin supramolecular structures},
author = {Bell, Nelson S. and Dunphy, Darren R. and Lambert, Timothy N. and Lu, Ping and Boyle, Timothy J.},
abstractNote = {In this study, the use of maltodextrin supramolecular structures (MD SMS) as a reducing agent and colloidal stabilizing agent for the synthesis of Ag nanoparticles (Ag NPs) identified three key points. First, the maltodextrin (MD) solutions are effective in the formation of well-dispersed Ag NPs utilizing alkaline solution conditions, with the resulting Ag NPs ranging in size from 5 to 50 nm diameter. Second, in situ characterization by Raman spectroscopy and small angle X-ray scattering (SAXS) are consistent with initial nucleation of Ag NPs within the MD SMS up to a critical size of ca. 1 nm, followed by a transition to more rapid growth by aggregation and fusion between MD SMS, similar to micelle aggregation reactions. Third, the stabilization of larger Ag NPs by adsorbed MD SMS is similar to hemi-micelle stabilization, and monomodal size distributions are proposed to relate to integer surface coverage of the Ag NPs. Conditions were identified for preparing Ag NPs with monomodal distributions centered at 30–35 nm Ag NPs.},
doi = {10.1016/j.colsurfb.2015.06.030},
journal = {Colloids and Surfaces. B, Biointerfaces},
number = C,
volume = 134,
place = {United States},
year = {Fri Jun 26 00:00:00 EDT 2015},
month = {Fri Jun 26 00:00:00 EDT 2015}
}
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