Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries
Abstract
Polymerized ionic networks (PINs) with six ion pairs per repeating unit are synthesized by nucleophilic-substitution-mediated polymerization or radical polymerization of monomers bearing six 1-vinylimidazolium cations. PIN-based solid-like electrolytes show good ionic conductivities (up to 5.32 × 10-3 S cm-1 at 22 °C), wide electrochemical stability windows (up to 5.6 V), and good interfacial compatibility with the electrodes.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1234996
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials (Online)
- Additional Journal Information:
- Journal Name: Advanced Materials (Online); Journal Volume: 27; Journal Issue: 48; Journal ID: ISSN 1521-4095
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 25 ENERGY STORAGE
Citation Formats
Zhang, Pengfei, Li, Mingtao, Jiang, Xueguang, Fang, Youxing, Veith, Gabriel M., Sun, Xiao-Guang, and Dai, Sheng. Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries. United States: N. p., 2015.
Web. doi:10.1002/adma.201502855.
Zhang, Pengfei, Li, Mingtao, Jiang, Xueguang, Fang, Youxing, Veith, Gabriel M., Sun, Xiao-Guang, & Dai, Sheng. Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries. United States. https://doi.org/10.1002/adma.201502855
Zhang, Pengfei, Li, Mingtao, Jiang, Xueguang, Fang, Youxing, Veith, Gabriel M., Sun, Xiao-Guang, and Dai, Sheng. Mon .
"Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries". United States. https://doi.org/10.1002/adma.201502855. https://www.osti.gov/servlets/purl/1234996.
@article{osti_1234996,
title = {Polymeric Ionic Networks with High Charge Density: Solid-like Electrolytes in Lithium Metal Batteries},
author = {Zhang, Pengfei and Li, Mingtao and Jiang, Xueguang and Fang, Youxing and Veith, Gabriel M. and Sun, Xiao-Guang and Dai, Sheng},
abstractNote = {Polymerized ionic networks (PINs) with six ion pairs per repeating unit are synthesized by nucleophilic-substitution-mediated polymerization or radical polymerization of monomers bearing six 1-vinylimidazolium cations. PIN-based solid-like electrolytes show good ionic conductivities (up to 5.32 × 10-3 S cm-1 at 22 °C), wide electrochemical stability windows (up to 5.6 V), and good interfacial compatibility with the electrodes.},
doi = {10.1002/adma.201502855},
journal = {Advanced Materials (Online)},
number = 48,
volume = 27,
place = {United States},
year = {Mon Nov 02 00:00:00 EST 2015},
month = {Mon Nov 02 00:00:00 EST 2015}
}
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