Surface Structure of Aerobically Oxidized Diamond Nanocrystals
Abstract
Here we investigate the aerobic oxidation of high-pressure, high-temperature nanodiamonds (5–50 nm dimensions) using a combination of carbon and oxygen K-edge X-ray absorption, wavelength-dependent X-ray photoelectron, and vibrational spectroscopies. Oxidation at 575 °C for 2 h eliminates graphitic carbon contamination (>98%) and produces nanocrystals with hydroxyl functionalized surfaces as well as a minor component (<5%) of carboxylic anhydrides. The low graphitic carbon content and the high crystallinity of HPHT are evident from Raman spectra acquired using visible wavelength excitation (λexcit = 633 nm) as well as carbon K-edge X-ray absorption spectra where the signature of a core–hole exciton is observed. Both spectroscopic features are similar to those of chemical vapor deposited (CVD) diamond but differ significantly from the spectra of detonation nanodiamond. Lastly, we discuss the importance of these findings to the functionalization of nanodiamond surfaces for biological labeling applications.
- Authors:
-
- Columbia Univ., New York, NY (United States). Dept. of Chemistry; Columbia Univ., New York, NY (United States). Dept. of Electrical Engineering; Columbia Univ., New York, NY (United States). Dept. of Applied Mathematics and Applied Physics; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Electrical Engineering and Computer Science; Diamond Nanotechnologies Inc., Boston, MA (United States)
- Columbia Univ., New York, NY (United States). Energy Frontier Research Center
- Columbia Univ., New York, NY (United States). Dept. of Electrical Engineering; Columbia Univ., New York, NY (United States). Dept. of Applied Mathematics and Applied Physics; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Electrical Engineering and Computer Science
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Columbia Univ., New York, NY (United States). Dept. of Electrical Engineering; Columbia Univ., New York, NY (United States). Dept. of Applied Mathematics and Applied Physics; Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Electrical Engineering and Computer Science; Diamond Nanotechnologies Inc., Boston, MA (United States)
- Columbia Univ., New York, NY (United States). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Re-Defining Photovoltaic Efficiency Through Molecule Scale Control (RPEMSC); Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1229426
- Report Number(s):
- BNL-111502-2015-JA
Journal ID: ISSN 1932-7447
- Grant/Contract Number:
- SC00112704; W911NF-12-1-0594; SC0001085; AC02-98CH10886; HDTRA1-11-1-0022; HR0011-14-C-0018; D14PC00121; 1R43MH102942-01
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 118; Journal Issue: 46; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Wolcott, Abraham, Schiros, Theanne, Trusheim, Matthew E., Chen, Edward H., Nordlund, Dennis, Diaz, Rosa E., Gaaton, Ophir, Englund, Dirk, and Owen, Jonathan S. Surface Structure of Aerobically Oxidized Diamond Nanocrystals. United States: N. p., 2014.
Web. doi:10.1021/jp506992c.
Wolcott, Abraham, Schiros, Theanne, Trusheim, Matthew E., Chen, Edward H., Nordlund, Dennis, Diaz, Rosa E., Gaaton, Ophir, Englund, Dirk, & Owen, Jonathan S. Surface Structure of Aerobically Oxidized Diamond Nanocrystals. United States. https://doi.org/10.1021/jp506992c
Wolcott, Abraham, Schiros, Theanne, Trusheim, Matthew E., Chen, Edward H., Nordlund, Dennis, Diaz, Rosa E., Gaaton, Ophir, Englund, Dirk, and Owen, Jonathan S. Mon .
"Surface Structure of Aerobically Oxidized Diamond Nanocrystals". United States. https://doi.org/10.1021/jp506992c. https://www.osti.gov/servlets/purl/1229426.
@article{osti_1229426,
title = {Surface Structure of Aerobically Oxidized Diamond Nanocrystals},
author = {Wolcott, Abraham and Schiros, Theanne and Trusheim, Matthew E. and Chen, Edward H. and Nordlund, Dennis and Diaz, Rosa E. and Gaaton, Ophir and Englund, Dirk and Owen, Jonathan S.},
abstractNote = {Here we investigate the aerobic oxidation of high-pressure, high-temperature nanodiamonds (5–50 nm dimensions) using a combination of carbon and oxygen K-edge X-ray absorption, wavelength-dependent X-ray photoelectron, and vibrational spectroscopies. Oxidation at 575 °C for 2 h eliminates graphitic carbon contamination (>98%) and produces nanocrystals with hydroxyl functionalized surfaces as well as a minor component (<5%) of carboxylic anhydrides. The low graphitic carbon content and the high crystallinity of HPHT are evident from Raman spectra acquired using visible wavelength excitation (λexcit = 633 nm) as well as carbon K-edge X-ray absorption spectra where the signature of a core–hole exciton is observed. Both spectroscopic features are similar to those of chemical vapor deposited (CVD) diamond but differ significantly from the spectra of detonation nanodiamond. Lastly, we discuss the importance of these findings to the functionalization of nanodiamond surfaces for biological labeling applications.},
doi = {10.1021/jp506992c},
journal = {Journal of Physical Chemistry. C},
number = 46,
volume = 118,
place = {United States},
year = {Mon Oct 27 00:00:00 EDT 2014},
month = {Mon Oct 27 00:00:00 EDT 2014}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 50 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Inner-shell excitation of formaldehyde, acetaldehyde and acetone studied by electron impact
journal, January 1980
- Hitchcock, A. P.; Brion, C. E.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 19, Issue 2
Fluorescent PLLA-nanodiamond composites for bone tissue engineering
journal, January 2011
- Zhang, Qingwei; Mochalin, Vadym N.; Neitzel, Ioannis
- Biomaterials, Vol. 32, Issue 1
High yield fabrication of fluorescent nanodiamonds
journal, May 2009
- Boudou, Jean-Paul; Curmi, Patrick A.; Jelezko, Fedor
- Nanotechnology, Vol. 20, Issue 23
Oxidative etching of cleaved synthetic diamond {111} surfaces
journal, October 2001
- de Theije, F. K.; van Veenendaal, E.; van Enckevort, W. J. P.
- Surface Science, Vol. 492, Issue 1-2
NEXAFS studies of complex alcohols and carboxylic acids on the Si(111)(7×7) surface
journal, June 1987
- Outka, D. A.; Stöhr, J.; Madix, R. J.
- Surface Science, Vol. 185, Issue 1-2
Calculated X-ray Diffraction Data for Diamond Polytypes
journal, July 1992
- Ownby, P. Darrell; Yang, Xi; Liu, Jenq
- Journal of the American Ceramic Society, Vol. 75, Issue 7
Electric-field sensing using single diamond spins
journal, April 2011
- Dolde, F.; Fedder, H.; Doherty, M. W.
- Nature Physics, Vol. 7, Issue 6
Quantum register based on coupled electron spins in a room-temperature solid
journal, February 2010
- Neumann, P.; Kolesov, R.; Naydenov, B.
- Nature Physics, Vol. 6, Issue 4
Enormously High Concentrations of Fluorescent Nitrogen-Vacancy Centers Fabricated by Sintering of Detonation Nanodiamonds
journal, April 2011
- Baranov, Pavel G.; Soltamova, Alexandra A.; Tolmachev, Daniel O.
- Small, Vol. 7, Issue 11
Nanoscale magnetic imaging of a single electron spin under ambient conditions
journal, February 2013
- Grinolds, M. S.; Hong, S.; Maletinsky, P.
- Nature Physics, Vol. 9, Issue 4
Theoretical Strength and Cleavage of Diamond
journal, May 2000
- Telling, R. H.; Pickard, C. J.; Payne, M. C.
- Physical Review Letters, Vol. 84, Issue 22
Silica Encapsulation of Fluorescent Nanodiamonds for Colloidal Stability and Facile Surface Functionalization
journal, April 2013
- Bumb, Ambika; Sarkar, Susanta K.; Billington, Neil
- Journal of the American Chemical Society, Vol. 135, Issue 21
Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000
- Ferrari, A. C.; Robertson, J.
- Physical Review B, Vol. 61, Issue 20, p. 14095-14107
Real-Time Background-Free Selective Imaging of Fluorescent Nanodiamonds in Vivo
journal, October 2012
- Igarashi, Ryuji; Yoshinari, Yohsuke; Yokota, Hiroaki
- Nano Letters, Vol. 12, Issue 11
Interaction of hydrogen and water with diamond (100): Infrared spectroscopy
journal, July 1993
- Struck, Lisa M.; D’Evelyn, Mark P.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 11, Issue 4
Size-reduction of nanodiamonds via air oxidation
journal, January 2012
- Gaebel, T.; Bradac, C.; Chen, J.
- Diamond and Related Materials, Vol. 21
The oscillator strengths for C1s and O1s excitation of some saturated and unsaturated organic alcohols, acids and esters
journal, January 1988
- Ishii, I.; Hitchcook, A. P.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 46, Issue 1
Bonding and hardness in nonhydrogenated carbon films with moderate sp3 content
journal, June 2000
- Gago, R.; Jiménez, I.; Albella, J. M.
- Journal of Applied Physics, Vol. 87, Issue 11
Thermal hydrogenation of diamond surfaces studied by diffuse reflectance Fourier-transform infrared, temperature-programmed desorption and laser Raman spectroscopy
journal, January 1993
- Ando, Toshihiro; Ishii, Motohiko; Kamo, Mutsukazu
- Journal of the Chemical Society, Faraday Transactions, Vol. 89, Issue 11
Wet Chemistry Route to Hydrophobic Blue Fluorescent Nanodiamond
journal, April 2009
- Mochalin, Vadym N.; Gogotsi, Yury
- Journal of the American Chemical Society, Vol. 131, Issue 13
Biotinylated Nanodiamond: Simple and Efficient Functionalization of Detonation Diamond
journal, April 2008
- Krueger, Anke; Stegk, Jochen; Liang, Yuejiang
- Langmuir, Vol. 24, Issue 8
Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond
journal, September 2004
- Ferrari, Andrea Carlo; Robertson, John
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 362, Issue 1824
The NIST quantitative infrared database
journal, January 1999
- Chu, P. M.; Guenther, F. R.; Rhoderick, G. C.
- Journal of Research of the National Institute of Standards and Technology, Vol. 104, Issue 1
Summary Abstract: Structural analysis of the diamond C(111)‐(2×1) reconstructed surface by low‐energy electron diffraction
journal, May 1988
- Sowa, Erik C.; Kubiak, Glenn D.; Stulen, Richard H.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 6, Issue 3
content of mass-selected ion-beam-deposited carbon films determined by inelastic and elastic electron scattering
journal, December 1995
- Kulik, J.; Lempert, G. D.; Grossman, E.
- Physical Review B, Vol. 52, Issue 22
Study of Oxygen on the Three Low Index Diamond Surfaces by XPS
journal, April 2003
- Makau, N. W.; Derry, T. E.
- Surface Review and Letters, Vol. 10, Issue 02n03
Nuclear Magnetic Resonance Spectroscopy on a (5-Nanometer) 3 Sample Volume
journal, January 2013
- Staudacher, T.; Shi, F.; Pezzagna, S.
- Science, Vol. 339, Issue 6119
Quantum measurement and orientation tracking of fluorescent nanodiamonds inside living cells
journal, May 2011
- McGuinness, L. P.; Yan, Y.; Stacey, A.
- Nature Nanotechnology, Vol. 6, Issue 6
The properties and applications of nanodiamonds
journal, December 2011
- Mochalin, Vadym N.; Shenderova, Olga; Ho, Dean
- Nature Nanotechnology, Vol. 7, Issue 1
Oxidation of the hydrogenated diamond (100) surface
journal, July 2000
- Pehrsson, Pehr E.; Mercer, Thomas W.
- Surface Science, Vol. 460, Issue 1-3
Observation of a C- Core Exciton in Diamond
journal, April 1985
- Morar, J. F.; Himpsel, F. J.; Hollinger, G.
- Physical Review Letters, Vol. 54, Issue 17
Raman spectroscopy in graphene
journal, April 2009
- Malard, L. M.; Pimenta, M. A.; Dresselhaus, G.
- Physics Reports, Vol. 473, Issue 5-6, p. 51-87
Functionality is Key: Recent Progress in the Surface Modification of Nanodiamond
journal, January 2012
- Krueger, Anke; Lang, Daniel
- Advanced Functional Materials, Vol. 22, Issue 5
Thermal oxidation of the hydrogenated diamond () surface
journal, January 2002
- Pehrsson, Pehr E.; Mercer, Thomas W.; Chaney, John A.
- Surface Science, Vol. 497, Issue 1-3
Ultralong spin coherence time in isotopically engineered diamond
journal, April 2009
- Balasubramanian, Gopalakrishnan; Neumann, Philipp; Twitchen, Daniel
- Nature Materials, Vol. 8, Issue 5
Mass production and dynamic imaging of fluorescent nanodiamonds
journal, April 2008
- Chang, Yi-Ren; Lee, Hsu-Yang; Chen, Kowa
- Nature Nanotechnology, Vol. 3, Issue 5
Contribution of Functional Groups to the Raman Spectrum of Nanodiamond Powders
journal, January 2009
- Mochalin, Vadym; Osswald, Sebastian; Gogotsi, Yury
- Chemistry of Materials, Vol. 21, Issue 2
Fluorescent Nanodiamonds Embedded in Biocompatible Translucent Shells
journal, February 2014
- Rehor, Ivan; Slegerova, Jitka; Kucka, Jan
- Small, Vol. 10, Issue 6
First-principle study on reactions of diamond (100) surfaces with hydrogen and methyl radicals
journal, December 2000
- Tamura, Hiroyuki; Zhou, Hui; Hirano, Yoshihisa
- Physical Review B, Vol. 62, Issue 24
High-sensitivity diamond magnetometer with nanoscale resolution
journal, September 2008
- Taylor, J. M.; Cappellaro, P.; Childress, L.
- Nature Physics, Vol. 4, Issue 10
Quantum Confinement and Fullerenelike Surface Reconstructions in Nanodiamonds
journal, January 2003
- Raty, Jean-Yves; Galli, Giulia; Bostedt, C.
- Physical Review Letters, Vol. 90, Issue 3
An extension of the mean free path approach to X-ray absorption spectroscopy
journal, June 2002
- Zharnikov, M.; Frey, S.; Heister, K.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 124, Issue 1
Nanoscale imaging magnetometry with diamond spins under ambient conditions
journal, October 2008
- Balasubramanian, Gopalakrishnan; Chan, I. Y.; Kolesov, Roman
- Nature, Vol. 455, Issue 7213
Nanoscale magnetic sensing with an individual electronic spin in diamond
journal, October 2008
- Maze, J. R.; Stanwix, P. L.; Hodges, J. S.
- Nature, Vol. 455, Issue 7213
Control of sp2/sp3 Carbon Ratio and Surface Chemistry of Nanodiamond Powders by Selective Oxidation in Air
journal, September 2006
- Osswald, Sebastian; Yushin, Gleb; Mochalin, Vadym
- Journal of the American Chemical Society, Vol. 128, Issue 35, p. 11635-11642
Fluorescence and Spin Properties of Defects in Single Digit Nanodiamonds
journal, June 2009
- Tisler, Julia; Balasubramanian, Gopalakrishnan; Naydenov, Boris
- ACS Nano, Vol. 3, Issue 7
Diffuse reflectance Fourier-transform infrared study of the plasma-fluorination of diamond surfaces using a microwave discharge in CF4
journal, January 1993
- Ando, Toshihiro; Tanaka, Junzo; Ishii, Motohiko
- Journal of the Chemical Society, Faraday Transactions, Vol. 89, Issue 16
Wide-Field Multispectral Super-Resolution Imaging Using Spin-Dependent Fluorescence in Nanodiamonds
journal, April 2013
- Chen, Edward H.; Gaathon, Ophir; Trusheim, Matthew E.
- Nano Letters, Vol. 13, Issue 5
Nanoscale Nuclear Magnetic Resonance with a Nitrogen-Vacancy Spin Sensor
journal, January 2013
- Mamin, H. J.; Kim, M.; Sherwood, M. H.
- Science, Vol. 339, Issue 6119
Characterization of nanocrystalline diamond films by core‐level photoabsorption
journal, March 1996
- Gruen, D. M.; Krauss, A. R.; Zuiker, C. D.
- Applied Physics Letters, Vol. 68, Issue 12
Oxygen Adsorption on (111)-Oriented Diamond: A Study with Ultraviolet Photoelectron Spectroscopy, Temperature-Programmed Desorption, and Periodic Density Functional Theory
journal, May 2002
- Loh, Kian Ping; Xie, X. N.; Yang, S. W.
- The Journal of Physical Chemistry B, Vol. 106, Issue 20
C 1s excitation studies of diamond (111). II. Unoccupied surface states
journal, January 1986
- Morar, J. F.; Himpsel, F. J.; Hollinger, G.
- Physical Review B, Vol. 33, Issue 2
Raman Spectrum of Graphene and Graphene Layers
journal, October 2006
- Ferrari, A. C.; Meyer, J. C.; Scardaci, V.
- Physical Review Letters, Vol. 97, Issue 18, Article No. 187401
New dimerized-chain model for the reconstruction of the diamond (111)-(2 × 1) surface
journal, March 1982
- Pandey, K. C.
- Physical Review B, Vol. 25, Issue 6
The Oxidation of Diamond: The Geometry and Stretching Frequency of Carbonyl on the (100) Surface
journal, May 2003
- John, Phillip; Polwart, Neil; Troupe, Clare E.
- Journal of the American Chemical Society, Vol. 125, Issue 22
A robust scanning diamond sensor for nanoscale imaging with single nitrogen-vacancy centres
journal, April 2012
- Maletinsky, P.; Hong, S.; Grinolds, M. S.
- Nature Nanotechnology, Vol. 7, Issue 5
High yield fabrication of fluorescent nanodiamonds
journal, August 2009
- Boudou, Jean-Paul; Curmi, Patrick A.; Jelezko, Fedor
- Nanotechnology, Vol. 20, Issue 35
Enormously High Concentrations of Fluorescent Nitrogen-Vacancy Centers Fabricated by Sintering of Detonation Nanodiamonds
journal, April 2011
- Baranov, Pavel G.; Soltamova, Alexandra A.; Tolmachev, Daniel O.
- Small, Vol. 7, Issue 11
Fluorescent Nanodiamonds Embedded in Biocompatible Translucent Shells
journal, February 2014
- Rehor, Ivan; Slegerova, Jitka; Kucka, Jan
- Small, Vol. 10, Issue 6
Fluorescent PLLA-nanodiamond composites for bone tissue engineering
journal, January 2011
- Zhang, Qingwei; Mochalin, Vadym N.; Neitzel, Ioannis
- Biomaterials, Vol. 32, Issue 1
The Oxidation of Diamond: The Geometry and Stretching Frequency of Carbonyl on the (100) Surface
journal, May 2003
- John, Phillip; Polwart, Neil; Troupe, Clare E.
- Journal of the American Chemical Society, Vol. 125, Issue 22
Wet Chemistry Route to Hydrophobic Blue Fluorescent Nanodiamond
journal, April 2009
- Mochalin, Vadym N.; Gogotsi, Yury
- Journal of the American Chemical Society, Vol. 131, Issue 13
Biotinylated Nanodiamond: Simple and Efficient Functionalization of Detonation Diamond
journal, April 2008
- Krueger, Anke; Stegk, Jochen; Liang, Yuejiang
- Langmuir, Vol. 24, Issue 8
Wide-Field Multispectral Super-Resolution Imaging Using Spin-Dependent Fluorescence in Nanodiamonds
journal, April 2013
- Chen, Edward H.; Gaathon, Ophir; Trusheim, Matthew E.
- Nano Letters, Vol. 13, Issue 5
Fluorescence and Spin Properties of Defects in Single Digit Nanodiamonds
journal, June 2009
- Tisler, Julia; Balasubramanian, Gopalakrishnan; Naydenov, Boris
- ACS Nano, Vol. 3, Issue 7
The properties and applications of nanodiamonds
journal, December 2011
- Mochalin, Vadym N.; Shenderova, Olga; Ho, Dean
- Nature Nanotechnology, Vol. 7, Issue 1
Quantum measurement and orientation tracking of fluorescent nanodiamonds inside living cells
journal, May 2011
- McGuinness, L. P.; Yan, Y.; Stacey, A.
- Nature Nanotechnology, Vol. 6, Issue 6
Quantum register based on coupled electron spins in a room-temperature solid
journal, February 2010
- Neumann, P.; Kolesov, R.; Naydenov, B.
- Nature Physics, Vol. 6, Issue 4
Bonding and hardness in nonhydrogenated carbon films with moderate sp3 content
journal, June 2000
- Gago, R.; Jiménez, I.; Albella, J. M.
- Journal of Applied Physics, Vol. 87, Issue 11
High yield fabrication of fluorescent nanodiamonds
journal, May 2009
- Boudou, Jean-Paul; Curmi, Patrick A.; Jelezko, Fedor
- Nanotechnology, Vol. 20, Issue 23
Stability, reconstruction, and electronic properties of diamond (100) and (111) surfaces
journal, December 1993
- Frauenheim, Th.; Stephan, U.; Blaudeck, P.
- Physical Review B, Vol. 48, Issue 24
High-resolution electron-energy-loss spectroscopic study of epitaxially grown diamond (111) and (100) surfaces
journal, December 1993
- Aizawa, Takashi; Ando, Toshihiro; Kamo, Mutsukazu
- Physical Review B, Vol. 48, Issue 24
Structural, electronic, and vibrational properties of diamond (100), (111), and (110) surfaces from ab initio calculations
journal, May 1995
- Alfonso, Dominic R.; Drabold, David A.; Ulloa, Sergio E.
- Physical Review B, Vol. 51, Issue 20
Phonon confinement effects in the Raman spectrum of nanodiamond
journal, August 2009
- Osswald, S.; Mochalin, V. N.; Havel, M.
- Physical Review B, Vol. 80, Issue 7
A robust scanning diamond sensor for nanoscale imaging with single nitrogen-vacancy centres
text, January 2012
- Maletinsky, Patrick; Hong, Sungkun; Grinolds, Mike
- Nature Publishing Group
Works referencing / citing this record:
Monitoring spin coherence of single nitrogen-vacancy centers in nanodiamonds during pH changes in aqueous buffer solutions
text, January 2018
- Fujiwara, Masazumi; Tsukahara, Ryuta; Sera, Yoshihiko
- arXiv
Monitoring spin coherence of single nitrogen-vacancy centers in nanodiamonds during pH changes in aqueous buffer solutions
journal, January 2019
- Fujiwara, Masazumi; Tsukahara, Ryuta; Sera, Yoshihiko
- RSC Advances, Vol. 9, Issue 22
Modulation of nitrogen vacancy charge state and fluorescence in nanodiamonds using electrochemical potential
journal, March 2016
- Karaveli, Sinan; Gaathon, Ophir; Wolcott, Abraham
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 15
Polydopamine Encapsulation of Fluorescent Nanodiamonds for Biomedical Applications
journal, June 2018
- Jung, Hak-Sung; Cho, Kyung-Jin; Seol, Yeonee
- Advanced Functional Materials, Vol. 28, Issue 33
High-yield fabrication and properties of 1.4 nm nanodiamonds with narrow size distribution
journal, December 2016
- Stehlik, Stepan; Varga, Marian; Ledinsky, Martin
- Scientific Reports, Vol. 6, Issue 1
Electron spin control of optically levitated nanodiamonds in vacuum
journal, July 2016
- Hoang, Thai M.; Ahn, Jonghoon; Bang, Jaehoon
- Nature Communications, Vol. 7, Issue 1
High-yield fabrication and properties of 1.4 nm nanodiamonds with narrow size distribution
journal, December 2016
- Stehlik, Stepan; Varga, Marian; Ledinsky, Martin
- Scientific Reports, Vol. 6, Issue 1
Monitoring spin coherence of single nitrogen-vacancy centers in nanodiamonds during pH changes in aqueous buffer solutions
text, January 2018
- Fujiwara, Masazumi; Tsukahara, Ryuta; Sera, Yoshihiko
- arXiv
Effect of surface oxidation on electron spin coherence of single nitrogen-vacancy centers in nanodiamonds
text, January 2018
- Tsukahara, Ryuta; Fujiwara, Masazumi; Sera, Yoshihiko
- arXiv