Expanding iClick to group 9 metals
Abstract
In this study, the iClick (inorganic click) reactions between gold-acetylides and group 9 transition metal-azide complexes are presented. Complexes [Rh(CO)(PPh3)2][PPh3Au](μ-N3C2C6H4NO2) (3), {[Rh(CO)(PPh3)][PPh3Au](μ-N3C2C6H4NO2)}2 (4), and [(CO)(PPh3)2IrAuPPh3](μ-N3C2C6H4NO2) (6) have been synthesized via M-azide/M-acetylide cycloaddition reactions between PPh3Au(Ctriple bond; length of mdashCC6H4NO2) (2) and either Rh(CO)(PPh3)2N3 (1), or Ir(CO)(PPh3)2N3 (5). Complexes 3, 4, and 6 have been characterized by a combination of NMR spectroscopies, crystallography and combustion analysis.
- Authors:
-
- Univ. of Florida, Gainesville, FL (United States)
- Publication Date:
- Research Org.:
- Univ. of Florida, Gainesville, FL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1225602
- Alternate Identifier(s):
- OSTI ID: 1373338
- Grant/Contract Number:
- SC0010510
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Polyhedron
- Additional Journal Information:
- Journal Name: Polyhedron; Journal ID: ISSN 0277-5387
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; iClick; azide-alkyne cycloaddition; rhodium; iridium; heterobimetallic
Citation Formats
Beto, Christopher C., Yang, Xi, Powers, Andrew R., Ghiviriga, Ion, Abboud, Khalil A., and Veige, Adam S. Expanding iClick to group 9 metals. United States: N. p., 2015.
Web. doi:10.1016/j.poly.2015.08.032.
Beto, Christopher C., Yang, Xi, Powers, Andrew R., Ghiviriga, Ion, Abboud, Khalil A., & Veige, Adam S. Expanding iClick to group 9 metals. United States. https://doi.org/10.1016/j.poly.2015.08.032
Beto, Christopher C., Yang, Xi, Powers, Andrew R., Ghiviriga, Ion, Abboud, Khalil A., and Veige, Adam S. Tue .
"Expanding iClick to group 9 metals". United States. https://doi.org/10.1016/j.poly.2015.08.032. https://www.osti.gov/servlets/purl/1225602.
@article{osti_1225602,
title = {Expanding iClick to group 9 metals},
author = {Beto, Christopher C. and Yang, Xi and Powers, Andrew R. and Ghiviriga, Ion and Abboud, Khalil A. and Veige, Adam S.},
abstractNote = {In this study, the iClick (inorganic click) reactions between gold-acetylides and group 9 transition metal-azide complexes are presented. Complexes [Rh(CO)(PPh3)2][PPh3Au](μ-N3C2C6H4NO2) (3), {[Rh(CO)(PPh3)][PPh3Au](μ-N3C2C6H4NO2)}2 (4), and [(CO)(PPh3)2IrAuPPh3](μ-N3C2C6H4NO2) (6) have been synthesized via M-azide/M-acetylide cycloaddition reactions between PPh3Au(Ctriple bond; length of mdashCC6H4NO2) (2) and either Rh(CO)(PPh3)2N3 (1), or Ir(CO)(PPh3)2N3 (5). Complexes 3, 4, and 6 have been characterized by a combination of NMR spectroscopies, crystallography and combustion analysis.},
doi = {10.1016/j.poly.2015.08.032},
journal = {Polyhedron},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 01 00:00:00 EDT 2015},
month = {Tue Sep 01 00:00:00 EDT 2015}
}
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