Structure and magnetic properties of Ce₃(Ni/Al/Ga)₁₁—A new phase with the La₃Al₁₁ structure type

Janka, Oliver; Shang, Tian; Baumbach, Ryan E.; Bauer, Eric D.; Thompson, Joe D.; Kauzlarich, Susan M.

doi:10.3390/cryst5010001

Title: Structure and magnetic properties of Ce₃(Ni/Al/Ga)₁₁—A new phase with the La₃Al₁₁ structure type

Abstract

Single crystals of Ce₃(Ni/Al/Ga)₁₁ were obtained from an Al flux reaction. Single crystals of the title compound crystallizing in the orthorhombic space group Immm (No. 71, Z = 2) with a = 436.38(14), b = 1004.5(3) and c = 1293.4(4) pm. This is a standardized unit cell of the previously published La₃Al₁₁ structure type. Wavelength dispersive microprobe provides the composition of Ce₃.₁₁₍₁₎Ni₀.₀₃₍₁₎Al₈.₉₅₍₁₎Ga₁.₉₀₍₁₎. Single crystal refinement provides the composition Ce₃Ni₀.₀₈Al₉.₁₃Ga₁.₇₈ with substitution of the Ni and Ga on the Al1 and Al4 sites with the Al2 and Al3 solely occupied by Al. Magnetic susceptibility measurements reveal antiferromagnetic ordering with T_N = 4.8 K and there is no evidence for a ferromagnetic ordering that has been reported for Ce₃Al₁₁. The effective magnetic moment was found to be μ_eff = 1.9μB/Ce, which is lower than the expected value for trivalent Ce (2.54μB/Ce).

Authors:

Janka, Oliver ^[1]; Shang, Tian ^[2]; Baumbach, Ryan E. ^[3]; Bauer, Eric D. ^[4]; Thompson, Joe D. ^[4]; Kauzlarich, Susan M. ^[5]

Univ. of California, Davis, CA (United States); Westfalische Wilhelms-Universitat, Munster (Germany)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Zhejiang Univ., Zhejiang (China)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Florida State Univ., Tallahassee, FL (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of California, Davis, CA (United States)

Publication Date:: Sun Mar 01 00:00:00 EST 2015

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1190777

Grant/Contract Number:: DMR-1100313

Resource Type:: Accepted Manuscript

Journal Name:: Crystals

Additional Journal Information:: Journal Volume: 5; Journal Issue: 1; Journal ID: ISSN 2073-4352

Publisher:: MDPI

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; cerium; single crystal; magnetism; aluminum

Citation Formats


                    Janka, Oliver, Shang, Tian, Baumbach, Ryan E., Bauer, Eric D., Thompson, Joe D., and Kauzlarich, Susan M. Structure and magnetic properties of Ce₃(Ni/Al/Ga)₁₁—A new phase with the La₃Al₁₁ structure type.  United States: N. p., 2015. 
Web.  doi:10.3390/cryst5010001.

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                    Janka, Oliver, Shang, Tian, Baumbach, Ryan E., Bauer, Eric D., Thompson, Joe D., & Kauzlarich, Susan M. Structure and magnetic properties of Ce₃(Ni/Al/Ga)₁₁—A new phase with the La₃Al₁₁ structure type.  United States.  https://doi.org/10.3390/cryst5010001

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                    Janka, Oliver, Shang, Tian, Baumbach, Ryan E., Bauer, Eric D., Thompson, Joe D., and Kauzlarich, Susan M. Sun .  
"Structure and magnetic properties of Ce₃(Ni/Al/Ga)₁₁—A new phase with the La₃Al₁₁ structure type".  United States.  https://doi.org/10.3390/cryst5010001.  https://www.osti.gov/servlets/purl/1190777.

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@article{osti_1190777,

  title        = {Structure and magnetic properties of Ce₃(Ni/Al/Ga)₁₁—A new phase with the La₃Al₁₁ structure type},

  author       = {Janka, Oliver and Shang, Tian and Baumbach, Ryan E. and Bauer, Eric D. and Thompson, Joe D. and Kauzlarich, Susan M.},

  abstractNote = {Single crystals of Ce₃(Ni/Al/Ga)₁₁ were obtained from an Al flux reaction. Single crystals of the title compound crystallizing in the orthorhombic space group Immm (No. 71, Z = 2) with a = 436.38(14), b = 1004.5(3) and c = 1293.4(4) pm. This is a standardized unit cell of the previously published La₃Al₁₁ structure type. Wavelength dispersive microprobe provides the composition of Ce₃.₁₁₍₁₎Ni₀.₀₃₍₁₎Al₈.₉₅₍₁₎Ga₁.₉₀₍₁₎. Single crystal refinement provides the composition Ce₃Ni₀.₀₈Al₉.₁₃Ga₁.₇₈ with substitution of the Ni and Ga on the Al1 and Al4 sites with the Al2 and Al3 solely occupied by Al. Magnetic susceptibility measurements reveal antiferromagnetic ordering with TN = 4.8 K and there is no evidence for a ferromagnetic ordering that has been reported for Ce₃Al₁₁. The effective magnetic moment was found to be μeff = 1.9μB/Ce, which is lower than the expected value for trivalent Ce (2.54μB/Ce).},

  doi          = {10.3390/cryst5010001},

  journal      = {Crystals},

  number       = 1,

  volume       = 5,

  place        = {United States},

  year         = {Sun Mar 01 00:00:00 EST 2015},

  month        = {Sun Mar 01 00:00:00 EST 2015}

}

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Works referenced in this record:

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Title: Structure and magnetic properties of Ce₃(Ni/Al/Ga)₁₁—A new phase with the La₃Al₁₁ structure type

Abstract

Citation Formats

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