Transparent Conducting Properties of SrSnO3 and ZnSnO3
Abstract
We report optical properties of doped n-type SrSnO3 and ZnSnO3 in relation to potential application as transparent conductors. We find that the orthorhombic distortion of the perovskite structure in SrSnO3 leads to absorption in the visible as the doping level is increased. This arises from interband transitions. We find that strain tuning could modify this absorption, but does not eliminate it. On the other hand, we find that ZnSnO3 although also having a non-cubic structure, can retain excellent transparency when doped, making it a good candidate transparent conductor.
- Authors:
-
- Inst. of High Performance Computing (Singapore)
- Jilin Univ., Changchun (China)
- Max Planck Inst. for the Structure and Dynamics of Matter (MPSD), Hamburg (Germany)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1185952
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- APL Materials
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 6; Journal ID: ISSN 2166-532X
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Ong, Khuong P., Fan, Xiaofeng, Subedi, Alaska, Sullivan, Michael B., and Singh, David J. Transparent Conducting Properties of SrSnO3 and ZnSnO3. United States: N. p., 2015.
Web. doi:10.1063/1.4919564.
Ong, Khuong P., Fan, Xiaofeng, Subedi, Alaska, Sullivan, Michael B., & Singh, David J. Transparent Conducting Properties of SrSnO3 and ZnSnO3. United States. https://doi.org/10.1063/1.4919564
Ong, Khuong P., Fan, Xiaofeng, Subedi, Alaska, Sullivan, Michael B., and Singh, David J. Wed .
"Transparent Conducting Properties of SrSnO3 and ZnSnO3". United States. https://doi.org/10.1063/1.4919564. https://www.osti.gov/servlets/purl/1185952.
@article{osti_1185952,
title = {Transparent Conducting Properties of SrSnO3 and ZnSnO3},
author = {Ong, Khuong P. and Fan, Xiaofeng and Subedi, Alaska and Sullivan, Michael B. and Singh, David J.},
abstractNote = {We report optical properties of doped n-type SrSnO3 and ZnSnO3 in relation to potential application as transparent conductors. We find that the orthorhombic distortion of the perovskite structure in SrSnO3 leads to absorption in the visible as the doping level is increased. This arises from interband transitions. We find that strain tuning could modify this absorption, but does not eliminate it. On the other hand, we find that ZnSnO3 although also having a non-cubic structure, can retain excellent transparency when doped, making it a good candidate transparent conductor.},
doi = {10.1063/1.4919564},
journal = {APL Materials},
number = 6,
volume = 3,
place = {United States},
year = {Wed Apr 29 00:00:00 EDT 2015},
month = {Wed Apr 29 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 52 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
La-doped BaSnO 3 âDegenerate perovskite transparent conducting oxide: Evidence from synchrotron x-ray spectroscopy
journal, July 2013
- Sallis, S.; Scanlon, D. O.; Chae, S. C.
- Applied Physics Letters, Vol. 103, Issue 4
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Preparation of crystalline ZnSnO3 from Li2SnO3 by low-temperature ion exchange
journal, June 1998
- Kovacheva, D.
- Solid State Ionics, Vol. 109, Issue 3-4
Dielectric-Constant-Enhanced Hall Mobility in Complex Oxides
journal, June 2012
- Siemons, Wolter; McGuire, Michael A.; Cooper, Valentino R.
- Advanced Materials, Vol. 24, Issue 29
Nonsuperconducting : The 5 s -orbital analog of
journal, September 1990
- Cava, R. J.; Gammel, P.; Batlogg, B.
- Physical Review B, Vol. 42, Issue 7
Merits and limits of the modified Becke-Johnson exchange potential
journal, May 2011
- Koller, David; Tran, Fabien; Blaha, Peter
- Physical Review B, Vol. 83, Issue 19
Electrical and Optical Properties of Sb-Doped BaSnO 3
journal, September 2013
- Mizoguchi, Hiroshi; Chen, Ping; Boolchand, Punit
- Chemistry of Materials, Vol. 25, Issue 19
Empirical electron-phonon values from resistivity of cubic metallic elements
journal, August 1987
- Allen, Philip B.
- Physical Review B, Vol. 36, Issue 5
Theoretical and experimental study of the structural, dynamical and dielectric properties of perovskite BaSnO 3
journal, March 2008
- BĂ©villon, Ămile; Chesnaud, Anthony; Wang, Yanzhong
- Journal of Physics: Condensed Matter, Vol. 20, Issue 14
First-principles study of the ferroelectric and nonlinear optical properties of the LiNbO3-type ZnSnO3
journal, January 2010
- Zhang, J.; Yao, K. L.; Liu, Z. L.
- Physical Chemistry Chemical Physics, Vol. 12, Issue 32
Room-temperature fabrication of transparent flexible thin-film transistors using amorphous oxide semiconductors
journal, November 2004
- Nomura, Kenji; Ohta, Hiromichi; Takagi, Akihiro
- Nature, Vol. 432, Issue 7016, p. 488-492
Probing the Electronic Structures of Ternary Perovskite and Pyrochlore Oxides Containing Sn 4+ or Sb 5+
journal, March 2004
- Mizoguchi, Hiroshi; Eng, Hank W.; Woodward, Patrick M.
- Inorganic Chemistry, Vol. 43, Issue 5
Electronic structure of Ba(Sn,Sb) : Absence of superconductivity
journal, November 1991
- Singh, D. J.; Papaconstantopoulos, D. A.; Julien, J. P.
- Physical Review B, Vol. 44, Issue 17
Towards efficient band structure and effective mass calculations for III-V direct band-gap semiconductors
journal, November 2010
- Kim, Yoon-Suk; Marsman, Martijn; Kresse, Georg
- Physical Review B, Vol. 82, Issue 20
Improved electrical mobility in highly epitaxial La:BaSnO 3 films on SmScO 3 (110) substrates
journal, August 2014
- Wadekar, P. V.; Alaria, J.; O'Sullivan, M.
- Applied Physics Letters, Vol. 105, Issue 5
Solution-Processed Metal Nanowire Mesh Transparent Electrodes
journal, February 2008
- Lee, Jung-Yong; Connor, Stephen T.; Cui, Yi
- Nano Letters, Vol. 8, Issue 2, p. 689-692
Structure and optical properties of high light output halide scintillators
journal, October 2010
- Singh, David J.
- Physical Review B, Vol. 82, Issue 15
Heteroepitaxial Ferroelectric ZnSnO 3 Thin Film
journal, June 2009
- Son, Jong Yeog; Lee, Geunhee; Jo, Moon-Ho
- Journal of the American Chemical Society, Vol. 131, Issue 24
Present status of amorphous InâGaâZnâO thin-film transistors
journal, February 2010
- Kamiya, Toshio; Nomura, Kenji; Hosono, Hideo
- Science and Technology of Advanced Materials, Vol. 11, Issue 4
Accurate Band Gaps of Semiconductors and Insulators with a Semilocal Exchange-Correlation Potential
journal, June 2009
- Tran, Fabien; Blaha, Peter
- Physical Review Letters, Vol. 102, Issue 22
Electronic band structure and optical phonons of BaSnO 3 and Ba 0.97 La 0.03 SnO 3 single crystals: Theory and experiment
journal, August 2012
- Stanislavchuk, T. N.; Sirenko, A. A.; Litvinchuk, A. P.
- Journal of Applied Physics, Vol. 112, Issue 4
Strain effects on the band gap and optical properties of perovskite SrSnO 3 and BaSnO 3
journal, January 2014
- Singh, David J.; Xu, Qiang; Ong, Khuong P.
- Applied Physics Letters, Vol. 104, Issue 1
Structural Instability of Epitaxial (001) BiFeO3 Thin Films under Tensile Strain
journal, April 2014
- Fan, Zhen; Wang, John; Sullivan, Michael B.
- Scientific Reports, Vol. 4, Issue 1
Hybrid functional calculation of electronic and phonon structure of BaSnO3
journal, January 2013
- Kim, Bog G.; Jo, J. Y.; Cheong, S. W.
- Journal of Solid State Chemistry, Vol. 197
Properties of transparent zincâstannate conducting films prepared by radio frequency magnetron sputtering
journal, May 1995
- Minami, T.; Takata, S.; Sato, H.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 13, Issue 3
Electronic structure calculations with the Tran-Blaha modified Becke-Johnson density functional
journal, November 2010
- Singh, David J.
- Physical Review B, Vol. 82, Issue 20
Origin of the superior conductivity of perovskite Ba(Sr)SnO 3
journal, March 2013
- Liu, Heng-Rui; Yang, Ji-Hui; Xiang, H. J.
- Applied Physics Letters, Vol. 102, Issue 11
Transparent, Conductive Graphene Electrodes for Dye-Sensitized Solar Cells
journal, January 2008
- Wang, Xuan; Zhi, Linjie; MĂŒllen, Klaus
- Nano Letters, Vol. 8, Issue 1, p. 323-327
Chemical and Thin-Film Strategies for New Transparent Conducting Oxides
journal, August 2000
- Freeman, A. J.; Poeppelmeier, K. R.; Mason, T. O.
- MRS Bulletin, Vol. 25, Issue 8
First-Principles Studies on Novel Polar Oxide ZnSnO3; Pressure-Induced Phase Transition and Electric Properties
journal, May 2010
- Nakayama, Masanobu; Nogami, Masayuki; Yoshida, Masashi
- Advanced Materials, Vol. 22, Issue 23
Structural properties of A2SnO4(A = Ba,Sr). A neutron diffraction study
journal, January 1996
- Green, Mark A.; Prassides, Kosmas; Day, Peter
- Journal of the Chemical Society, Faraday Transactions, Vol. 92, Issue 12
A Polar Oxide ZnSnO 3 with a LiNbO 3 -Type Structure
journal, May 2008
- Inaguma, Yoshiyuki; Yoshida, Masashi; Katsumata, Tetsuhiro
- Journal of the American Chemical Society, Vol. 130, Issue 21
High mobility transparent thin-film transistors with amorphous zinc tin oxide channel layer
journal, January 2005
- Chiang, H. Q.; Wager, J. F.; Hoffman, R. L.
- Applied Physics Letters, Vol. 86, Issue 1
First-principles study of structural, electronic, and optical properties of
journal, November 2009
- Wang, Hai; Huang, Haitao; Wang, Biao
- Solid State Communications, Vol. 149, Issue 41-42
Highly Transparent and Conductive Zinc-Stannate Thin Films Prepared by RF Magnetron Sputtering
journal, December 1994
- Minami, Tadatsugu; Sonohara, Hideo; Takata, Shinzo
- Japanese Journal of Applied Physics, Vol. 33, Issue Part 2, No. 12A
Transparent p -Type Conducting Oxides: Design and Fabrication of p-n Heterojunctions
journal, August 2000
- Kawazoe, Hiroshi; Yanagi, Hiroshi; Ueda, Kazushige
- MRS Bulletin, Vol. 25, Issue 8
Evaporated Snâdoped In 2 O 3 films: Basic optical properties and applications to energyâefficient windows
journal, December 1986
- Hamberg, I.; Granqvist, C. G.
- Journal of Applied Physics, Vol. 60, Issue 11
Growth and characterization of radio frequency magnetron sputter-deposited zinc stannate, Zn2SnO4, thin films
journal, July 2002
- Young, David L.; Moutinho, Helio; Yan, Yanfa
- Journal of Applied Physics, Vol. 92, Issue 1
Enhanced Born charge and proximity to ferroelectricity in thallium halides
journal, April 2010
- Du, Mao-Hua; Singh, David J.
- Physical Review B, Vol. 81, Issue 14
High Mobility in a Stable Transparent Perovskite Oxide
journal, May 2012
- Kim, Hyung Joon; Kim, Useong; Kim, Hoon Min
- Applied Physics Express, Vol. 5, Issue 6
Large effects of dislocations on high mobility of epitaxial perovskite Ba 0.96 La 0.04 SnO 3 films
journal, June 2013
- Mun, Hyosik; Kim, Useong; Min Kim, Hoon
- Applied Physics Letters, Vol. 102, Issue 25
Tuning optical properties of transparent conducting barium stannate by dimensional reduction
journal, January 2015
- Li, Yuwei; Zhang, Lijun; Ma, Yanming
- APL Materials, Vol. 3, Issue 1
Synthesis, structure and electrical behaviour of lanthanum-doped barium stannate
journal, April 2004
- Upadhyay, Shail; Parkash, Om; Kumar, Devendra
- Journal of Physics D: Applied Physics, Vol. 37, Issue 10
Restoring the Density-Gradient Expansion for Exchange in Solids and Surfaces
journal, April 2008
- Perdew, John P.; Ruzsinszky, Adrienn; Csonka, GĂĄbor I.
- Physical Review Letters, Vol. 100, Issue 13
Electromagnetic absorption in transparent conducting films
journal, May 2004
- Porch, Adrian; Morgan, D. Vernon; Perks, Richard M.
- Journal of Applied Physics, Vol. 95, Issue 9
Optical properties of ferroelectric
journal, November 2010
- Singh, David J.; Seo, Sung Seok A.; Lee, Ho Nyung
- Physical Review B, Vol. 82, Issue 18
2DEGs at Perovskite Interfaces between KTaO3 or KNbO3 and Stannates
journal, March 2014
- Fan, Xiaofeng; Zheng, Weitao; Chen, Xin
- PLoS ONE, Vol. 9, Issue 3
Physical properties of transparent perovskite oxides (Ba,La)SnO with high electrical mobility at room temperature
journal, October 2012
- Kim, Hyung Joon; Kim, Useong; Kim, Tai Hoon
- Physical Review B, Vol. 86, Issue 16
The A SnO 3 ( A =Ca,Sr) perovskites
journal, April 1986
- Vegas, A.; Vallet-RegĂ, M.; GonzĂĄlez-Calbet, J. M.
- Acta Crystallographica Section B Structural Science, Vol. 42, Issue 2
Transparent Conducting Oxides
journal, August 2000
- Ginley, David S.; Bright, Clark
- MRS Bulletin, Vol. 25, Issue 8
Free-carrier absorption in nitrides from first principles
journal, June 2010
- Kioupakis, Emmanouil; Rinke, Patrick; Schleife, André
- Physical Review B, Vol. 81, Issue 24
Works referencing / citing this record:
Wide Bandgap Perovskite Oxides with High RoomâTemperature Electron Mobility
journal, June 2019
- Prakash, Abhinav; Jalan, Bharat
- Advanced Materials Interfaces, Vol. 6, Issue 15
Trapped Carrier Scattering and Charge Transport in HighâMobility Amorphous Metal Oxide ThinâFilm Transistors
journal, November 2018
- Wang, Xiao; Dodabalapur, Ananth
- Annalen der Physik, Vol. 530, Issue 12
Low Temperature Fabrication of Transparent Conductive Electrode With High Ultraviolet Transmittance Down to Wavelength of 250ânm
journal, September 2018
- Safaei, Javad; Rosli, Nurul Nazli; Mohamad Noh, Mohamad Firdaus
- physica status solidi (RRL) â Rapid Research Letters, Vol. 12, Issue 12
Thermopower Modulation Clarification of the Operating Mechanism in Wide Bandgap BaSnO 3 -SrSnO 3 Solid-Solution Based Thin Film Transistors
journal, January 2019
- Sanchela, Anup V.; Wei, Mian; Cho, Hai Jun
- Small, Vol. 15, Issue 8
New p-type Al-substituted SrSnO 3 perovskites for TCO applications?
journal, January 2020
- Ben Amor, Leila; Belgacem, Besma; Filhol, Jean-SĂ©bastien
- Chemical Communications, Vol. 56, Issue 17
Dopant solubility and charge compensation in La-doped SrSnO 3 films
journal, October 2019
- Truttmann, Tristan; Prakash, Abhinav; Yue, Jin
- Applied Physics Letters, Vol. 115, Issue 15
Defect and Optical Properties of Sb doped and hydrogenated BaSnO 3
journal, February 2018
- Sarkar, Ankita; De, S. K.
- Semiconductor Science and Technology, Vol. 33, Issue 3
Redefining the Mobility Edge in Thin-Film Transistors
journal, June 2019
- Wang, Xiao; Register, Leonard F.; Dodabalapur, Ananth
- Physical Review Applied, Vol. 11, Issue 6
Dopant Solubility, and Charge Compensation in La-doped SrSnO3 Films
text, January 2019
- Truttmann, Tristan; Prakash, Abhinav; Yue, Jin
- arXiv