Hypercrosslinked phenolic polymers with well developed mesoporous frameworks
Abstract
A soft chemistry synthetic strategy based on a Friedel Crafts alkylation reaction is developed for the textural engineering of phenolic resin (PR) with a robust mesoporous framework to avoid serious framework shrinkage and maximize retention of organic functional moieties. By taking advantage of the structural benefits of molecular bridges, the resultant sample maintains a bimodal micro-mesoporous architecture with well-preserved organic functional groups, which is effective for carbon capture. Furthermore, this soft chemistry synthetic protocol can be further extended to nanotexture other aromatic-based polymers with robust frameworks.
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1185912
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 54; Journal Issue: 15; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; phenolic polymer; Friedel-Crafts alkylation reaction; hypercross-linking; mesoporous frameworks; CO2 capture
Citation Formats
Zhang, Jinshui, Qiao, Zhenan -An, Mahurin, Shannon Mark, Jiang, Xueguang, Chai, Song -Hai, Lu, Hanfeng, Nelson, Kimberly M., and Dai, Sheng. Hypercrosslinked phenolic polymers with well developed mesoporous frameworks. United States: N. p., 2015.
Web. doi:10.1002/anie.201500305.
Zhang, Jinshui, Qiao, Zhenan -An, Mahurin, Shannon Mark, Jiang, Xueguang, Chai, Song -Hai, Lu, Hanfeng, Nelson, Kimberly M., & Dai, Sheng. Hypercrosslinked phenolic polymers with well developed mesoporous frameworks. United States. https://doi.org/10.1002/anie.201500305
Zhang, Jinshui, Qiao, Zhenan -An, Mahurin, Shannon Mark, Jiang, Xueguang, Chai, Song -Hai, Lu, Hanfeng, Nelson, Kimberly M., and Dai, Sheng. Thu .
"Hypercrosslinked phenolic polymers with well developed mesoporous frameworks". United States. https://doi.org/10.1002/anie.201500305. https://www.osti.gov/servlets/purl/1185912.
@article{osti_1185912,
title = {Hypercrosslinked phenolic polymers with well developed mesoporous frameworks},
author = {Zhang, Jinshui and Qiao, Zhenan -An and Mahurin, Shannon Mark and Jiang, Xueguang and Chai, Song -Hai and Lu, Hanfeng and Nelson, Kimberly M. and Dai, Sheng},
abstractNote = {A soft chemistry synthetic strategy based on a Friedel Crafts alkylation reaction is developed for the textural engineering of phenolic resin (PR) with a robust mesoporous framework to avoid serious framework shrinkage and maximize retention of organic functional moieties. By taking advantage of the structural benefits of molecular bridges, the resultant sample maintains a bimodal micro-mesoporous architecture with well-preserved organic functional groups, which is effective for carbon capture. Furthermore, this soft chemistry synthetic protocol can be further extended to nanotexture other aromatic-based polymers with robust frameworks.},
doi = {10.1002/anie.201500305},
journal = {Angewandte Chemie (International Edition)},
number = 15,
volume = 54,
place = {United States},
year = {Thu Feb 12 00:00:00 EST 2015},
month = {Thu Feb 12 00:00:00 EST 2015}
}
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