Identifying the role of N-heteroatom location in the activity of metal catalysts for alcohol oxidation
Abstract
Here, this work focuses on understanding how the bonding of nitrogen heteroatoms contained on/in a activated carbon support influence the stability and reactivity of a supported Pd catalyst for the oxidation of alcohols in solution. The results show that simply adding N groups via solution chemistry is insufficient to improve catalytic properties. Instead a strongly bound N moiety is required to activate the catalyst and stabilize the metal particles.
- Authors:
-
- Univ. degli Studi di Milano via Golgi, Milano (Italy)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1185380
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemCatChem
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 8; Journal ID: ISSN 1867-3880
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; nitrogen functionalization; activated carbon; Pd nanoparticles; alcohol oxidation
Citation Formats
Chan-Thaw, Carine E., Veith, Gabriel M., Villa, Alberto, and Prati, Laura. Identifying the role of N-heteroatom location in the activity of metal catalysts for alcohol oxidation. United States: N. p., 2015.
Web. doi:10.1002/cctc.201402951.
Chan-Thaw, Carine E., Veith, Gabriel M., Villa, Alberto, & Prati, Laura. Identifying the role of N-heteroatom location in the activity of metal catalysts for alcohol oxidation. United States. https://doi.org/10.1002/cctc.201402951
Chan-Thaw, Carine E., Veith, Gabriel M., Villa, Alberto, and Prati, Laura. Thu .
"Identifying the role of N-heteroatom location in the activity of metal catalysts for alcohol oxidation". United States. https://doi.org/10.1002/cctc.201402951. https://www.osti.gov/servlets/purl/1185380.
@article{osti_1185380,
title = {Identifying the role of N-heteroatom location in the activity of metal catalysts for alcohol oxidation},
author = {Chan-Thaw, Carine E. and Veith, Gabriel M. and Villa, Alberto and Prati, Laura},
abstractNote = {Here, this work focuses on understanding how the bonding of nitrogen heteroatoms contained on/in a activated carbon support influence the stability and reactivity of a supported Pd catalyst for the oxidation of alcohols in solution. The results show that simply adding N groups via solution chemistry is insufficient to improve catalytic properties. Instead a strongly bound N moiety is required to activate the catalyst and stabilize the metal particles.},
doi = {10.1002/cctc.201402951},
journal = {ChemCatChem},
number = 8,
volume = 7,
place = {United States},
year = {Thu Apr 02 00:00:00 EDT 2015},
month = {Thu Apr 02 00:00:00 EDT 2015}
}
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