Fabrics coated with lubricated nanostructures display robust omniphobicity
Abstract
The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.
- Authors:
-
- Harvard Univ., Cambridge, MA (United States)
- Publication Date:
- Research Org.:
- Harvard Univ., Cambridge, MA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- Contributing Org.:
- Pennsylvania State Univ., State College, PA (United States)
- OSTI Identifier:
- 1185184
- Grant/Contract Number:
- AR0000326
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nanotechnology
- Additional Journal Information:
- Journal Volume: 25; Journal Issue: 1; Journal ID: ISSN 0957-4484
- Publisher:
- IOP Publishing
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; nanostructured coating; slippery liquid-infused porous surfaces; omniphobicity; self-cleaning; fabrics
Citation Formats
Shillingford, Cicely, MacCallum, Noah, Wong, Tak -Sing, Kim, Philseok, and Aizenberg, Joanna. Fabrics coated with lubricated nanostructures display robust omniphobicity. United States: N. p., 2013.
Web. doi:10.1088/0957-4484/25/1/014019.
Shillingford, Cicely, MacCallum, Noah, Wong, Tak -Sing, Kim, Philseok, & Aizenberg, Joanna. Fabrics coated with lubricated nanostructures display robust omniphobicity. United States. https://doi.org/10.1088/0957-4484/25/1/014019
Shillingford, Cicely, MacCallum, Noah, Wong, Tak -Sing, Kim, Philseok, and Aizenberg, Joanna. Wed .
"Fabrics coated with lubricated nanostructures display robust omniphobicity". United States. https://doi.org/10.1088/0957-4484/25/1/014019. https://www.osti.gov/servlets/purl/1185184.
@article{osti_1185184,
title = {Fabrics coated with lubricated nanostructures display robust omniphobicity},
author = {Shillingford, Cicely and MacCallum, Noah and Wong, Tak -Sing and Kim, Philseok and Aizenberg, Joanna},
abstractNote = {The development of a stain-resistant and pressure-stable textile is desirable for consumer and industrial applications alike, yet it remains a challenge that current technologies have been unable to fully address. Traditional superhydrophobic surfaces, inspired by the lotus plant, are characterized by two main components: hydrophobic chemical functionalization and surface roughness. While this approach produces water-resistant surfaces, these materials have critical weaknesses that hinder their practical utility, in particular as robust stain-free fabrics. For example, traditional superhydrophobic surfaces fail (i.e., become stained) when exposed to low-surface-tension liquids, under pressure when impacted by a high-velocity stream of water (e.g., rain), and when exposed to physical forces such as abrasion and twisting. We have recently introduced slippery lubricant-infused porous surfaces (SLIPS), a self-healing, pressure-tolerant and omniphobic surface, to address these issues. However we present the rational design and optimization of nanostructured lubricant-infused fabrics and demonstrate markedly improved performance over traditional superhydrophobic textile treatments: SLIPS-functionalized cotton and polyester fabrics exhibit decreased contact angle hysteresis and sliding angles, omni-repellent properties against various fluids including polar and nonpolar liquids, pressure tolerance and mechanical robustness, all of which are not readily achievable with the state-of-the-art superhydrophobic coatings.},
doi = {10.1088/0957-4484/25/1/014019},
journal = {Nanotechnology},
number = 1,
volume = 25,
place = {United States},
year = {Wed Dec 11 00:00:00 EST 2013},
month = {Wed Dec 11 00:00:00 EST 2013}
}
Web of Science
Works referenced in this record:
Bioinspired self-repairing slippery surfaces with pressure-stable omniphobicity
journal, September 2011
- Wong, Tak-Sing; Kang, Sung Hoon; Tang, Sindy K. Y.
- Nature, Vol. 477, Issue 7365, p. 443-447
Slippery pre-suffused surfaces
journal, November 2011
- Lafuma, A.; Quéré, D.
- EPL (Europhysics Letters), Vol. 96, Issue 5
Purity of the sacred lotus, or escape from contamination in biological surfaces
journal, April 1997
- Barthlott, W.; Neinhuis, C.
- Planta, Vol. 202, Issue 1, p. 1-8
Superhydrophobic surfaces and emerging applications: Non-adhesion, energy, green engineering
journal, August 2009
- Nosonovsky, Michael; Bhushan, Bharat
- Current Opinion in Colloid & Interface Science, Vol. 14, Issue 4
Wetting transitions on biomimetic surfaces
journal, October 2010
- Bormashenko, Edward
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 368, Issue 1929
Non-sticking drops
journal, September 2005
- Quéré, David
- Reports on Progress in Physics, Vol. 68, Issue 11, p. 2495-2532
Biomimetic Superhydrophobic and Highly Oleophobic Cotton Textiles
journal, December 2007
- Hoefnagels, H. F.; Wu, D.; de With, G.
- Langmuir, Vol. 23, Issue 26
The “Lotus Effect” Explained: Two Reasons Why Two Length Scales of Topography Are Important
journal, March 2006
- Gao, Lichao; McCarthy, Thomas J.
- Langmuir, Vol. 22, Issue 7
Superoleophobic Cotton Textiles
journal, February 2009
- Leng, Boxun; Shao, Zhengzhong; de With, Gijsbertus
- Langmuir, Vol. 25, Issue 4
Preparation of highly hydrophobic and oleophobic textile surfaces using microwave-promoted silane coupling
journal, December 2010
- Hayn, Ryan A.; Owens, Jeffery R.; Boyer, Stephanie A.
- Journal of Materials Science, Vol. 46, Issue 8
Cotton Fabrics with Single-Faced Superhydrophobicity
journal, December 2012
- Liu, Yuyang; Xin, J. H.; Choi, Chang-Hwan
- Langmuir, Vol. 28, Issue 50
Robust omniphobic surfaces
journal, November 2008
- Tuteja, A.; Choi, W.; Mabry, J. M.
- Proceedings of the National Academy of Sciences, Vol. 105, Issue 47, p. 18200-18205
Mimicking Both Petal and Lotus Effects on a Single Silicon Substrate by Tuning the Wettability of Nanostructured Surfaces
journal, April 2011
- Dawood, M. K.; Zheng, H.; Liew, T. H.
- Langmuir, Vol. 27, Issue 7
The Role of Multiscale Roughness in the Lotus Effect: Is It Essential for Super-Hydrophobicity?
journal, September 2012
- Bittoun, Eyal; Marmur, Abraham
- Langmuir, Vol. 28, Issue 39
Wettability of porous surfaces
journal, January 1944
- Cassie, A. B. D.; Baxter, S.
- Transactions of the Faraday Society, Vol. 40, p. 546-551
Wetting and Roughness
journal, August 2008
- Quéré, David
- Annual Review of Materials Research, Vol. 38, Issue 1, p. 71-99
Superhydrophobic states
journal, June 2003
- Lafuma, Aurélie; Quéré, David
- Nature Materials, Vol. 2, Issue 7
Pearl drops
journal, July 1999
- Bico, J; Marzolin, C; Quéré, D
- Europhysics Letters (EPL), Vol. 47, Issue 2, p. 220-226
Fabrics with Tunable Oleophobicity
journal, June 2009
- Choi, Wonjae; Tuteja, Anish; Chhatre, Shreerang
- Advanced Materials, Vol. 21, Issue 21
Liquid-infused structured surfaces with exceptional anti-biofouling performance
journal, July 2012
- Epstein, A. K.; Wong, T. -S.; Belisle, R. A.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 33
Liquid-Infused Nanostructured Surfaces with Extreme Anti-Ice and Anti-Frost Performance
journal, June 2012
- Kim, Philseok; Wong, Tak-Sing; Alvarenga, Jack
- ACS Nano, Vol. 6, Issue 8
Enhanced Condensation on Lubricant-Impregnated Nanotextured Surfaces
journal, October 2012
- Anand, Sushant; Paxson, Adam T.; Dhiman, Rajeev
- ACS Nano, Vol. 6, Issue 11, p. 10122-10129
Mechanism of Frost Formation on Lubricant-Impregnated Surfaces
journal, April 2013
- Rykaczewski, Konrad; Anand, Sushant; Subramanyam, Srinivas Bengaluru
- Langmuir, Vol. 29, Issue 17, p. 5230-5238
Droplet mobility on lubricant-impregnated surfaces
journal, December 2012
- Smith, J. David; Dhiman, Rajeev; Anand, Sushant
- Soft Matter, Vol. 9, Issue 6, p. 1772-1780
Hierarchical or Not? Effect of the Length Scale and Hierarchy of the Surface Roughness on Omniphobicity of Lubricant-Infused Substrates
journal, March 2013
- Kim, Philseok; Kreder, Michael J.; Alvarenga, Jack
- Nano Letters, Vol. 13, Issue 4, p. 1793-1799
Adaptive fluid-infused porous films with tunable transparency and wettability
journal, April 2013
- Yao, Xi; Hu, Yuhang; Grinthal, Alison
- Nature Materials, Vol. 12, Issue 6
Lubricant-infused micro/nano-structured surfaces with tunable dynamic omniphobicity at high temperatures
journal, June 2013
- Daniel, Daniel; Mankin, Max N.; Belisle, Rebecca A.
- Applied Physics Letters, Vol. 102, Issue 23
Recent Studies on Super-Hydrophobic Films
journal, January 2001
- Nakajima, Akira; Hashimoto, Kazuhito; Watanabe, Toshiya
- Monatshefte fuer Chemie/Chemical Monthly, Vol. 132, Issue 1
Effects of the Surface Roughness on Sliding Angles of Water Droplets on Superhydrophobic Surfaces
journal, June 2000
- Miwa, Masashi; Nakajima, Akira; Fujishima, Akira
- Langmuir, Vol. 16, Issue 13
Effects of Surface Structure on the Hydrophobicity and Sliding Behavior of Water Droplets
journal, July 2002
- Yoshimitsu, Zen; Nakajima, Akira; Watanabe, Toshiya
- Langmuir, Vol. 18, Issue 15
Design of a Superhydrophobic Surface Using Woven Structures
journal, May 2007
- Michielsen, Stephen; Lee, Hoon J.
- Langmuir, Vol. 23, Issue 11
Controlled growth of monodisperse silica spheres in the micron size range
journal, January 1968
- Stöber, Werner; Fink, Arthur; Bohn, Ernst
- Journal of Colloid and Interface Science, Vol. 26, Issue 1, p. 62-69
Surface Modification of Poly(ethylene terephthalate) To Prepare Surfaces with Silica-Like Reactivity
journal, September 1998
- Fadeev, Alexander Y.; McCarthy, Thomas J.
- Langmuir, Vol. 14, Issue 19, p. 5586-5593
Formation of superhydrophobic boehmite film on glass substrate by sol-gel method
journal, February 2009
- Fang, Xinhui; Yu, Zhijia; Sun, Xiangyu
- Frontiers of Chemical Engineering in China, Vol. 3, Issue 1
Fabrication of superhydrophobic surface by hierarchical growth of lotus-leaf-like boehmite on aluminum foil
journal, June 2011
- Liu, Lijun; Zhao, Jiashou; Zhang, Yi
- Journal of Colloid and Interface Science, Vol. 358, Issue 1
Fabrication of superhydrophobic nanostructured surface on aluminum alloy
journal, November 2010
- Jafari, R.; Farzaneh, M.
- Applied Physics A, Vol. 102, Issue 1
Analysis of roughness parameters to specify superhydrophobic antireflective boehmite films made by the sol–gel process
journal, January 2008
- Zhang, Xiaoxue; Järn, Mikael; Peltonen, Jouko
- Journal of the European Ceramic Society, Vol. 28, Issue 11
Quantitative Testing of Robustness on Superomniphobic Surfaces by Drop Impact
journal, December 2010
- Nhung Nguyen, Thi Phuong; Brunet, Philippe; Coffinier, Yannick
- Langmuir, Vol. 26, Issue 23, p. 18369-18373
Density and surface tension of 83 organic liquids
journal, July 1981
- Korosi, Gabor; Kovats, E. S.
- Journal of Chemical & Engineering Data, Vol. 26, Issue 3
Pearl drops
journal, September 1999
- Bico, J.; Marzolin, C.; Quéré, D.
- Europhysics Letters (EPL), Vol. 47, Issue 6
Wetting transitions on biomimetic surfaces
journal, April 2011
- Bormashenko, Edward
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 369, Issue 1941
Recent Studies on Super-Hydrophobic Films
book, January 2001
- Nakajima, Akira; Hashimoto, Kazuhito; Watanabe, Toshiya
- Molecular Materials and Functional Polymers
Works referencing / citing this record:
Designing Liquid‐Infused Surfaces for Medical Applications: A Review
journal, August 2018
- Howell, Caitlin; Grinthal, Alison; Sunny, Steffi
- Advanced Materials, Vol. 30, Issue 50
Recent Progress in Durable and Self-Healing Super-Nonwettable Fabrics
journal, June 2018
- Zhou, Hua; Wang, Hongxia; Niu, Haitao
- Advanced Materials Interfaces, Vol. 5, Issue 16
One-Step Modification of Fabrics with Bioinspired Polydopamine@Octadecylamine Nanocapsules for Robust and Healable Self-Cleaning Performance
journal, September 2014
- Liu, Yanhua; Liu, Zhilu; Liu, Yupeng
- Small, Vol. 11, Issue 4
Robust superhydrophobic surface on Al substrate with durability, corrosion resistance and ice-phobicity
journal, February 2016
- Wang, Guoyong; Liu, Shuai; Wei, Sufeng
- Scientific Reports, Vol. 6, Issue 1
Accelerating the healing of superhydrophobicity through photothermogenesis
journal, January 2015
- Liu, Yanhua; Pei, Xiaowei; Liu, Zhilu
- Journal of Materials Chemistry A, Vol. 3, Issue 33
The nanotipped hairs of gecko skin and biotemplated replicas impair and/or kill pathogenic bacteria with high efficiency
journal, January 2016
- Li, X.; Cheung, G. S.; Watson, G. S.
- Nanoscale, Vol. 8, Issue 45
A review on special wettability textiles: theoretical models, fabrication technologies and multifunctional applications
journal, January 2017
- Li, Shuhui; Huang, Jianying; Chen, Zhong
- Journal of Materials Chemistry A, Vol. 5, Issue 1
Superhydrophobic and slippery cotton fabrics with robust nanolayers for stable wettability, anti-fouling and anti-icing properties
journal, January 2019
- Gao, Xiaoyu; Wen, Gang; Guo, Zhiguang
- New Journal of Chemistry, Vol. 43, Issue 42
Low voltage reversible electrowetting exploiting lubricated polymer honeycomb substrates
journal, April 2014
- Bormashenko, Edward; Pogreb, Roman; Bormashenko, Yelena
- Applied Physics Letters, Vol. 104, Issue 17
Air-stable droplet interface bilayers on oil-infused surfaces
journal, May 2014
- Boreyko, J. B.; Polizos, G.; Datskos, P. G.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 21
Omniphobic Coatings Based on Vinyl Pivalate–Perfluorohexylethyl Methacrylate Copolymers Formed in Supercritical Carbon Dioxide
journal, March 2019
- Kazaryan, P. S.; Zefirov, V. V.; El’manovich, I. V.
- Polymer Science, Series A, Vol. 61, Issue 2
Immobilized liquid layers: A new approach to anti-adhesion surfaces for medical applications
journal, March 2016
- Sotiri, Irini; Overton, Jonathan C.; Waterhouse, Anna
- Experimental Biology and Medicine, Vol. 241, Issue 9
Recent Progress in Fabrication and Applications of Superhydrophobic Coating on Cellulose-Based Substrates
journal, February 2016
- Liu, Hui; Gao, Shou-Wei; Cai, Jing-Sheng
- Materials, Vol. 9, Issue 3
Polymeric Slippery Coatings: Nature and Applications
journal, April 2014
- Samaha, Mohamed; Gad-el-Hak, Mohamed
- Polymers, Vol. 6, Issue 5
Low Voltage Reversible Electrowetting Exploiting Lubricated Polymer Honeycomb Substrates
text, January 2014
- Bormashenko, Edward; Pogreb, Roman; Bormashenko, Yelena
- arXiv
Robust superhydrophobic surface on Al substrate with durability, corrosion resistance and ice-phobicity
journal, February 2016
- Wang, Guoyong; Liu, Shuai; Wei, Sufeng
- Scientific Reports, Vol. 6, Issue 1
Uniting Superhydrophobic, Superoleophobic and Lubricant Infused Slippery Behavior on Copper Oxide Nano-structured Substrates
journal, October 2016
- Ujjain, Sanjeev Kumar; Roy, Pritam Kumar; Kumar, Sumana
- Scientific Reports, Vol. 6, Issue 1
Recent Progress in Fabrication and Applications of Superhydrophobic Coating on Cellulose-Based Substrates
journal, February 2016
- Liu, Hui; Gao, Shou-Wei; Cai, Jing-Sheng
- Materials, Vol. 9, Issue 3