Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries
Abstract
The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.
- Authors:
-
[2];
[1];
[4];
[1];
- Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Seoul National Univ. (Korea, Republic of)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1177000
- Report Number(s):
- BNL-107669-2015-JA; BNL-107669-2015-JAAM
Journal ID: ISSN 2041-1723; R&D Project: MA453MAEA; VT1201000
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Wang, Yuesheng, Liu, Jue, Lee, Byungju, Qiao, Ruimin, Yang, Zhenzhong, Xu, Shuyin, Yu, Xiqian, Gu, Lin, Hu, Yong-Sheng, Yang, Wanli, Kang, Kisuk, Li, Hong, Yang, Xiao-Qing, Chen, Liquan, and Huang, Xuejie. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries. United States: N. p., 2015.
Web. doi:10.1038/ncomms7401.
Wang, Yuesheng, Liu, Jue, Lee, Byungju, Qiao, Ruimin, Yang, Zhenzhong, Xu, Shuyin, Yu, Xiqian, Gu, Lin, Hu, Yong-Sheng, Yang, Wanli, Kang, Kisuk, Li, Hong, Yang, Xiao-Qing, Chen, Liquan, & Huang, Xuejie. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries. United States. https://doi.org/10.1038/ncomms7401
Wang, Yuesheng, Liu, Jue, Lee, Byungju, Qiao, Ruimin, Yang, Zhenzhong, Xu, Shuyin, Yu, Xiqian, Gu, Lin, Hu, Yong-Sheng, Yang, Wanli, Kang, Kisuk, Li, Hong, Yang, Xiao-Qing, Chen, Liquan, and Huang, Xuejie. Wed .
"Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries". United States. https://doi.org/10.1038/ncomms7401. https://www.osti.gov/servlets/purl/1177000.
@article{osti_1177000,
title = {Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries},
author = {Wang, Yuesheng and Liu, Jue and Lee, Byungju and Qiao, Ruimin and Yang, Zhenzhong and Xu, Shuyin and Yu, Xiqian and Gu, Lin and Hu, Yong-Sheng and Yang, Wanli and Kang, Kisuk and Li, Hong and Yang, Xiao-Qing and Chen, Liquan and Huang, Xuejie},
abstractNote = {The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.},
doi = {10.1038/ncomms7401},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {Wed Mar 25 00:00:00 EDT 2015},
month = {Wed Mar 25 00:00:00 EDT 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 244 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Understanding the Rate Capability of High-Energy-Density Li-Rich Layered Li 1.2 Ni 0.15 Co 0.1 Mn 0.55 O 2 Cathode Materials
journal, December 2013
- Yu, Xiqian; Lyu, Yingchun; Gu, Lin
- Advanced Energy Materials, Vol. 4, Issue 5
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Lithium Insertion Processes of Orthorhombic Na[sub x]MnO[sub 2]-Based Electrode Materials
journal, January 1996
- Doeff, Marca M.
- Journal of The Electrochemical Society, Vol. 143, Issue 8
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011
- Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
- Advanced Functional Materials, Vol. 21, Issue 20
Electrochemical and structural characterization of titanium-substituted manganese oxides based on Na0.44MnO2
journal, September 2004
- Doeff, Marca M.; Richardson, Thomas J.; Hwang, Kwang-Taek
- Journal of Power Sources, Vol. 135, Issue 1-2, p. 240-248
Study of the Insertion/Deinsertion Mechanism of Sodium into Na 0.44 MnO 2
journal, April 2007
- Sauvage, F.; Laffont, L.; Tarascon, J. -M.
- Inorganic Chemistry, Vol. 46, Issue 8
First experimental results from IBM/TENN/TULANE/LLNL/LBL undulator beamline at the advanced light source
journal, February 1995
- Jia, J. J.; Callcott, T. A.; Yurkas, J.
- Review of Scientific Instruments, Vol. 66, Issue 2
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011
- Dunn, B.; Kamath, H.; Tarascon, J. -M.
- Science, Vol. 334, Issue 6058
An advanced cathode for Na-ion batteries with high rate and excellent structural stability
journal, January 2013
- Lee, Dae Hoe; Xu, Jing; Meng, Ying Shirley
- Physical Chemistry Chemical Physics, Vol. 15, Issue 9
A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage
journal, January 2012
- Pasta, Mauro; Wessells, Colin D.; Huggins, Robert A.
- Nature Communications, Vol. 3, Issue 1, Article No. 1149
Copper hexacyanoferrate battery electrodes with long cycle life and high power
journal, November 2011
- Wessells, Colin D.; Huggins, Robert A.; Cui, Yi
- Nature Communications, Vol. 2, Article No. 550
Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2
journal, March 2010
- Komaba, Shinichi; Takei, Chikara; Nakayama, Tetsuri
- Electrochemistry Communications, Vol. 12, Issue 3
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Update on Na-based battery materials. A growing research path
journal, January 2013
- Palomares, Verónica; Casas-Cabanas, Montse; Castillo-Martínez, Elizabeth
- Energy & Environmental Science, Vol. 6, Issue 8
Electrochemical Properties of NaTi2(PO4)3 Anode for Rechargeable Aqueous Sodium-Ion Batteries
journal, January 2011
- Park, Sun Il; Gocheva, Irina; Okada, Shigeto
- Journal of The Electrochemical Society, Vol. 158, Issue 10
P2-NaxVO2 system as electrodes for batteries and electron-correlated materials
journal, November 2012
- Guignard, Marie; Didier, Christophe; Darriet, Jacques
- Nature Materials, Vol. 12, Issue 1
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
Orthorhombic Na[sub x]MnO[sub 2] as a Cathode Material for Secondary Sodium and Lithium Polymer Batteries
journal, January 1994
- Doeff, Marca M.
- Journal of The Electrochemical Society, Vol. 141, Issue 11
The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery
journal, January 2011
- Carlier, D.; Cheng, J. H.; Berthelot, R.
- Dalton Transactions, Vol. 40, Issue 36
Single-Crystal Synthesis and Structure Refinement of Na<sub>0.44</sub>MnO<sub>2</sub>
journal, April 2011
- Akimoto, Junji; Hayakawa, Hiroshi; Kijima, Norihito
- Solid State Phenomena, Vol. 170
Band theory and Mott insulators: Hubbard U instead of Stoner I
journal, July 1991
- Anisimov, Vladimir I.; Zaanen, Jan; Andersen, Ole K.
- Physical Review B, Vol. 44, Issue 3, p. 943-954
Sodium-Ion Batteries
journal, May 2012
- Slater, Michael D.; Kim, Donghan; Lee, Eungje
- Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
Study of the Insertion/Deinsertion Mechanism of Sodium into Na0.44MnO2.
journal, July 2007
- Sauvage, F.; Laffont, L.; Tarascon, J. -M.
- ChemInform, Vol. 38, Issue 28
Sodium-Ion Batteries
journal, June 2018
- Rojo, Teofilo; Hu, Yong-Sheng; Forsyth, Maria
- Advanced Energy Materials, Vol. 8, Issue 17
Electrical Conductivities of Na[sub 0.44]Mn[sub 1−x]Ti[sub x]O[sub 2]
journal, January 2009
- Funabiki, Fuji; Hayakawa, Hiroshi; Kijima, Norihito
- Electrochemical and Solid-State Letters, Vol. 12, Issue 11
Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte
journal, August 2010
- Luo, Jia-Yan; Cui, Wang-Jun; He, Ping
- Nature Chemistry, Vol. 2, Issue 9
Diffusion behavior of sodium ions in Na0.44MnO2 in aqueous and non-aqueous electrolytes
journal, December 2013
- Kim, Dong Jun; Ponraj, Rubha; Kannan, Aravindaraj G.
- Journal of Power Sources, Vol. 244
Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010
- Berthelot, R.; Carlier, D.; Delmas, C.
- Nature Materials, Vol. 10, Issue 1
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
journal, May 2013
- Qiao, Ruimin; Chin, Timothy; Harris, Stephen J.
- Current Applied Physics, Vol. 13, Issue 3
The structure of Na4Mn4Ti5O18
journal, August 1968
- Mumme, W. G.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 24, Issue 8, p. 1114-1120
Direct evidence of gradient Mn(II) evolution at charged states in LiNi0.5Mn1.5O4 electrodes with capacity fading
journal, January 2015
- Qiao, Ruimin; Wang, Yuesheng; Olalde-Velasco, Paul
- Journal of Power Sources, Vol. 273
Full open-framework batteries for stationary energy storage
journal, January 2014
- Pasta, Mauro; Wessells, Colin D.; Liu, Nian
- Nature Communications, Vol. 5, Issue 1
Coupled Commensurate Cation and Charge Modulation in the Tunneled Structure, Na 0.40(2) MnO 2
journal, September 2011
- Kruk, Izabela; Zajdel, Pawel; van Beek, Wouter
- Journal of the American Chemical Society, Vol. 133, Issue 35
Towards High Power High Energy Aqueous Sodium-Ion Batteries: The NaTi 2 (PO 4 ) 3 /Na 0.44 MnO 2 System
journal, October 2012
- Li, Zheng; Young, David; Xiang, Kai
- Advanced Energy Materials, Vol. 3, Issue 3
Energetic Aqueous Rechargeable Sodium-Ion Battery Based on Na 2 CuFe(CN) 6 -NaTi 2 (PO 4 ) 3 Intercalation Chemistry
journal, January 2014
- Wu, Xian-yong; Sun, Meng-ying; Shen, Yi-fei
- ChemSusChem, Vol. 7, Issue 2
Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life
journal, June 2011
- Cao, Yuliang; Xiao, Lifen; Wang, Wei
- Advanced Materials, Vol. 23, Issue 28, p. 3155-3160
First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method
journal, January 1997
- Anisimov, Vladimir I.; Aryasetiawan, F.; Lichtenstein, A. I.
- Journal of Physics: Condensed Matter, Vol. 9, Issue 4, p. 767-808
High-resolution X-ray luminescence extension imaging
journal, February 2021
- Ou, Xiangyu; Qin, Xian; Huang, Bolong
- Nature, Vol. 590, Issue 7846
Recent Progress in Aqueous Lithium-Ion Batteries
journal, June 2012
- Wang, Yonggang; Yi, Jin; Xia, Yongyao
- Advanced Energy Materials, Vol. 2, Issue 7
The role of vacancies and defects in Na0.44MnO2 nanowire catalysts for lithium–oxygen batteries
journal, January 2012
- Lee, Jin-Hyon; Black, Robert; Popov, Guerman
- Energy & Environmental Science, Vol. 5, Issue 11
Na4Mn9O18 as a positive electrode material for an aqueous electrolyte sodium-ion energy storage device
journal, March 2010
- Whitacre, J. F.; Tevar, A.; Sharma, S.
- Electrochemistry Communications, Vol. 12, Issue 3, p. 463-466
High power Na-ion rechargeable battery with single-crystalline Na0.44MnO2 nanowire electrode
journal, November 2012
- Hosono, Eiji; Saito, Tatsuya; Hoshino, Junichi
- Journal of Power Sources, Vol. 217
Sodium Storage and Transport Properties in Layered Na 2 Ti 3 O 7 for Room-Temperature Sodium-Ion Batteries
journal, May 2013
- Pan, Huilin; Lu, Xia; Yu, Xiqian
- Advanced Energy Materials, Vol. 3, Issue 9
Electrochemical Energy Storage for Green Grid
journal, May 2011
- Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
- Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
Aqueous Rechargeable Li and Na Ion Batteries
journal, September 2014
- Kim, Haegyeom; Hong, Jihyun; Park, Kyu-Young
- Chemical Reviews, Vol. 114, Issue 23
STEM characterization for lithium-ion battery cathode materials
journal, February 2012
- Huang, Rong; Ikuhara, Yuichi
- Current Opinion in Solid State and Materials Science, Vol. 16, Issue 1
A 3.8-V earth-abundant sodium battery electrode
journal, July 2014
- Barpanda, Prabeer; Oyama, Gosuke; Nishimura, Shin-ichi
- Nature Communications, Vol. 5, Issue 1
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Thermodynamic analysis on energy densities of batteries
journal, January 2011
- Zu, Chen-Xi; Li, Hong
- Energy & Environmental Science, Vol. 4, Issue 8
Superior Electrochemical Performance and Storage Mechanism of Na 3 V 2 (PO 4 ) 3 Cathode for Room-Temperature Sodium-Ion Batteries
journal, October 2012
- Jian, Zelang; Han, Wenze; Lu, Xia
- Advanced Energy Materials, Vol. 3, Issue 2
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012
- Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
- Nature Materials, Vol. 11, Issue 6
Electrochemical intercalation and deintercalation of NaxMnO2 bronzes
journal, May 1985
- Mendiboure, A.; Delmas, C.; Hagenmuller, P.
- Journal of Solid State Chemistry, Vol. 57, Issue 3
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries
journal, February 2013
- Suo, Liumin; Hu, Yong-Sheng; Li, Hong
- Nature Communications, Vol. 4, Issue 1
Direct atomic-scale confirmation of three-phase storage mechanism in Li4Ti5O12 anodes for room-temperature sodium-ion batteries
journal, May 2013
- Sun, Yang; Zhao, Liang; Pan, Huilin
- Nature Communications, Vol. 4, Issue 1
Identifying the Critical Role of Li Substitution in P2–Na x [Li y Ni z Mn 1– y – z ]O 2 (0 < x , y , z < 1) Intercalation Cathode Materials for High-Energy Na-Ion Batteries
journal, December 2013
- Xu, Jing; Lee, Dae Hoe; Clément, Raphaële J.
- Chemistry of Materials, Vol. 26, Issue 2
Ab Initio Study of the Sodium Intercalation and Intermediate Phases in Na 0.44 MnO 2 for Sodium-Ion Battery
journal, March 2012
- Kim, Heejin; Kim, Dong Jun; Seo, Dong-Hwa
- Chemistry of Materials, Vol. 24, Issue 6
A low-cost and environmentally benign aqueous rechargeable sodium-ion battery based on NaTi2(PO4)3–Na2NiFe(CN)6 intercalation chemistry
journal, June 2013
- Wu, Xianyong; Cao, Yuliang; Ai, Xinping
- Electrochemistry Communications, Vol. 31
Spectroscopic fingerprints of valence and spin states in manganese oxides and fluorides
text, January 2012
- Qiao, Ruimin; Chin, Timothy; Harris, Stephen J.
- arXiv
Layered Transition Metal Oxides as Cathodes for Sodium Secondary Battery
journal, June 2006
- Okada, Shigeto; Takahashi, Yusuke; Kiyabu, Toshiyasu
- ECS Meeting Abstracts, Vol. MA2006-02, Issue 4
Works referencing / citing this record:
Water-mediated cation intercalation of open-framework indium hexacyanoferrate with high voltage and fast kinetics
journal, June 2016
- Chen, Liang; Shao, Hezhu; Zhou, Xufeng
- Nature Communications, Vol. 7, Issue 1
Rechargeable Aqueous Electrochromic Batteries Utilizing Ti‐Substituted Tungsten Molybdenum Oxide Based Zn 2+ Ion Intercalation Cathodes
journal, February 2019
- Li, Haizeng; McRae, Liam; Firby, Curtis J.
- Advanced Materials, Vol. 31, Issue 15
A novel aqueous ammonium dual-ion battery based on organic polymers
journal, January 2019
- Zhang, Yadi; An, Yufeng; Yin, Bo
- Journal of Materials Chemistry A, Vol. 7, Issue 18
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy
journal, July 2019
- Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
- Batteries & Supercaps, Vol. 2, Issue 10
NASICON-Structured NaTi2(PO4)3 for Sustainable Energy Storage
journal, May 2019
- Wu, Mingguang; Ni, Wei; Hu, Jin
- Nano-Micro Letters, Vol. 11, Issue 1
Aqueous Batteries Operated at −50 °C
journal, November 2019
- Nian, Qingshun; Wang, Jiayue; Liu, Shuang
- Angewandte Chemie International Edition, Vol. 58, Issue 47
Na–Mn–O@C yolk–shell nanorods as an ultrahigh electrochemical performance anode for lithium ion batteries
journal, January 2017
- Li, Jiannian; Yu, Jun; Amiinu, Ibrahim Saana
- Journal of Materials Chemistry A, Vol. 5, Issue 35
Ultrasmall MoS 3 Loaded GO Nanocomposites as High‐Rate and Long‐Cycle‐Life Anode Materials for Lithium‐ and Sodium‐Ion Batteries
journal, May 2019
- Zhou, Yanli; Li, Yanyan; Wang, Qianqian
- ChemElectroChem, Vol. 6, Issue 12
Understanding hydrothermal transformation from Mn2O3 particles to Na0.55Mn2O4·1.5H2O nanosheets, nanobelts and single crystalline ultra-long Na4Mn9O18 nanowires
journal, December 2015
- Park, Yohan; Woo Lee, Sung; Kim, Ki Hyeon
- Scientific Reports, Vol. 5, Issue 1
Unexpectedly high electrochemical performances of a monoclinic Na 2.4 V 2 (PO 4 ) 3 /conductive polymer composite for Na-ion batteries
journal, January 2018
- Lee, Yongseok; Yoo, Jung-Keun; Oh, Youngseok
- Journal of Materials Chemistry A, Vol. 6, Issue 36
An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na 3 MnTi(PO 4 ) 3
journal, September 2016
- Gao, Hongcai; Goodenough, John B.
- Angewandte Chemie, Vol. 128, Issue 41
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, January 2020
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie International Edition, Vol. 59, Issue 4
Different crystallographic sodium manganese oxides for capacitive deionization: performance comparison and the associated mechanism
journal, January 2019
- Zhao, Yubo; Liang, Bolong; Zong, Mingzhu
- Environmental Science: Nano, Vol. 6, Issue 10
A 3D Lithium/Carbon Fiber Anode with Sustained Electrolyte Contact for Solid‐State Batteries
journal, December 2019
- Zhang, Ying; Shi, Yang; Hu, Xin‐Cheng
- Advanced Energy Materials, Vol. 10, Issue 3
Impact of Na 2 MoO 4 nanolayers autogenously formed on tunnel-type Na 0.44 MnO 2
journal, January 2019
- Choi, Ji Ung; Jo, Jae Hyeon; Jo, Chang-Heum
- Journal of Materials Chemistry A, Vol. 7, Issue 22
Electrolytes and Electrolyte/Electrode Interfaces in Sodium‐Ion Batteries: From Scientific Research to Practical Application
journal, March 2019
- Huang, Yongxin; Zhao, Luzi; Li, Li
- Advanced Materials, Vol. 31, Issue 21
A Synergistic Na-Mn-O Composite Cathodes for High-Capacity Na-Ion Storage
journal, October 2018
- Wang, Xuanpeng; Wang, Chenyang; Han, Kang
- Advanced Energy Materials, Vol. 8, Issue 33
The influence of large cations on the electrochemical properties of tunnel-structured metal oxides
journal, November 2016
- Yuan, Yifei; Zhan, Chun; He, Kun
- Nature Communications, Vol. 7, Issue 1
Composite‐Structure Materials for Na‐Ion Batteries
journal, October 2018
- Su, Heng; Yu, Haijun
- Small Methods, Vol. 3, Issue 4
Reversible Oxygen Redox Chemistry in Aqueous Zinc‐Ion Batteries
journal, April 2019
- Wan, Fang; Zhang, Yan; Zhang, Linlin
- Angewandte Chemie, Vol. 131, Issue 21
Native Vacancy Enhanced Oxygen Redox Reversibility and Structural Robustness
journal, December 2018
- Li, Yejing; Wang, Xuefeng; Gao, Yurui
- Advanced Energy Materials, Vol. 9, Issue 4
Tailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries
journal, June 2018
- Yan, Pengfei; Zheng, Jianming; Liu, Jian
- Nature Energy, Vol. 3, Issue 7
A durable VO 2 (M)/Zn battery with ultrahigh rate capability enabled by pseudocapacitive proton insertion
journal, January 2020
- Zhang, Lishang; Miao, Ling; Zhang, Bao
- Journal of Materials Chemistry A, Vol. 8, Issue 4
A Novel High Capacity Positive Electrode Material with Tunnel-Type Structure for Aqueous Sodium-Ion Batteries
journal, August 2015
- Wang, Yuesheng; Mu, Linqin; Liu, Jue
- Advanced Energy Materials, Vol. 5, Issue 22
Sodium Ion Stabilized Vanadium Oxide Nanowire Cathode for High-Performance Zinc-Ion Batteries
journal, January 2018
- He, Pan; Zhang, Guobin; Liao, Xiaobin
- Advanced Energy Materials, Vol. 8, Issue 10
Rechargeable aqueous zinc-manganese dioxide batteries with high energy and power densities
journal, September 2017
- Zhang, Ning; Cheng, Fangyi; Liu, Junxiang
- Nature Communications, Vol. 8, Issue 1
Faradaic reactions in capacitive deionization for desalination and ion separation
journal, January 2019
- Yu, Fei; Wang, Lei; Wang, Ying
- Journal of Materials Chemistry A, Vol. 7, Issue 27
High valence Mo-doped Na 3 V 2 (PO 4 ) 3 /C as a high rate and stable cycle-life cathode for sodium battery
journal, January 2018
- Li, Xiang; Huang, Yangyang; Wang, Jingsong
- Journal of Materials Chemistry A, Vol. 6, Issue 4
Preparation and electrochemical performance of VO 2 (A) hollow spheres as a cathode for aqueous zinc ion batteries
journal, January 2019
- Li, Runxia; Yu, Xin; Bian, Xiaofei
- RSC Advances, Vol. 9, Issue 60
Reversible Oxygen Redox Chemistry in Aqueous Zinc‐Ion Batteries
journal, May 2019
- Wan, Fang; Zhang, Yan; Zhang, Linlin
- Angewandte Chemie International Edition, Vol. 58, Issue 21
A Layered-Tunnel Intergrowth Structure for High-Performance Sodium-Ion Oxide Cathode
journal, May 2018
- Xiao, Yao; Wang, Peng-Fei; Yin, Ya-Xia
- Advanced Energy Materials, Vol. 8, Issue 22
Realization of Ti Doping by Electrostatic Assembly to Improve the Stability of LiCoO 2 Cycled to 4.5 V
journal, January 2019
- Sun, Liwei; Zhang, Zeshu; Hu, Xuefeng
- Journal of The Electrochemical Society, Vol. 166, Issue 10
An Environmentally Friendly and Flexible Aqueous Zinc Battery Using an Organic Cathode
journal, August 2018
- Guo, Zhaowei; Ma, Yuanyuan; Dong, Xiaoli
- Angewandte Chemie International Edition, Vol. 57, Issue 36
Environmentally-friendly aqueous Li (or Na)-ion battery with fast electrode kinetics and super-long life
journal, January 2016
- Dong, Xiaoli; Chen, Long; Liu, Jingyuan
- Science Advances, Vol. 2, Issue 1
Highly durable organic electrode for sodium-ion batteries via a stabilized α-C radical intermediate
journal, November 2016
- Wu, Shaofei; Wang, Wenxi; Li, Minchan
- Nature Communications, Vol. 7, Issue 1
Na-Mn-O Nanocrystals as a High Capacity and Long Life Anode Material for Li-Ion Batteries
journal, November 2016
- Zhang, Jie; He, Ting; Zhang, Wei
- Advanced Energy Materials, Vol. 7, Issue 5
Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery
journal, July 2018
- Huang, Jianhang; Wang, Zhuo; Hou, Mengyan
- Nature Communications, Vol. 9, Issue 1
Effects of Different Atmosphere on Electrochemical Performance of Hard Carbon Electrode in Sodium Ion Battery
journal, April 2019
- Xu, Ziqiang; Chen, Jinchen; Wu, Mengqiang
- Electronic Materials Letters, Vol. 15, Issue 4
An Aqueous Symmetric Sodium-Ion Battery with NASICON-Structured Na 3 MnTi(PO 4 ) 3
journal, September 2016
- Gao, Hongcai; Goodenough, John B.
- Angewandte Chemie International Edition, Vol. 55, Issue 41
Stabilized Molybdenum Trioxide Nanowires as Novel Ultrahigh‐Capacity Cathode for Rechargeable Zinc Ion Battery
journal, May 2019
- He, Xinjun; Zhang, Haozhe; Zhao, Xingyu
- Advanced Science, Vol. 6, Issue 14
Battery-Supercapacitor Hybrid Devices: Recent Progress and Future Prospects
journal, February 2017
- Zuo, Wenhua; Li, Ruizhi; Zhou, Cheng
- Advanced Science, Vol. 4, Issue 7
A New Strategy to Build a High‐Performance P′2‐Type Cathode Material through Titanium Doping for Sodium‐Ion Batteries
journal, May 2019
- Park, Yun Ji; Choi, Ji Ung; Jo, Jae Hyeon
- Advanced Functional Materials, Vol. 29, Issue 28
An Environmentally Friendly and Flexible Aqueous Zinc Battery Using an Organic Cathode
journal, August 2018
- Guo, Zhaowei; Ma, Yuanyuan; Dong, Xiaoli
- Angewandte Chemie, Vol. 130, Issue 36
Sodium-Ion Battery Materials and Electrochemical Properties Reviewed
journal, April 2018
- Chayambuka, Kudakwashe; Mulder, Grietus; Danilov, Dmitri L.
- Advanced Energy Materials, Vol. 8, Issue 16
A clean and membrane-free chlor-alkali process with decoupled Cl2 and H2/NaOH production
journal, January 2018
- Hou, Mengyan; Chen, Long; Guo, Zhaowei
- Nature Communications, Vol. 9, Issue 1
Universal quinone electrodes for long cycle life aqueous rechargeable batteries
journal, June 2017
- Liang, Yanliang; Jing, Yan; Gheytani, Saman
- Nature Materials, Vol. 16, Issue 8
Ti-based electrode materials for electrochemical sodium ion storage and removal
journal, January 2019
- Zhai, Haifa; Xia, Bao Yu; Park, Ho Seok
- Journal of Materials Chemistry A, Vol. 7, Issue 39
High Capacity and High Efficiency Maple Tree-Biomass-Derived Hard Carbon as an Anode Material for Sodium-Ion Batteries
journal, July 2018
- Wang, Yuesheng; Feng, Zimin; Zhu, Wen
- Materials, Vol. 11, Issue 8
Beyond Li-ion: electrode materials for sodium- and magnesium-ion batteries
journal, September 2015
- Massé, Robert C.; Uchaker, Evan; Cao, Guozhong
- Science China Materials, Vol. 58, Issue 9
Understanding Oxygen Redox in Cu-Doped P2-Na 0.67 Mn 0.8 Fe 0.1 Co 0.1 O 2 Cathode Materials for Na-Ion Batteries
journal, January 2018
- Li, Ling; Wang, Huibo; Han, Wenze
- Journal of The Electrochemical Society, Vol. 165, Issue 16
Zero-strain K 0.6 Mn 1 F 2.7 hollow nanocubes for ultrastable potassium ion storage
journal, January 2018
- Liu, Zhiwei; Li, Ping; Suo, Guoquan
- Energy & Environmental Science, Vol. 11, Issue 10
Ni-based cathode materials for Na-ion batteries
journal, June 2019
- Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan
- Nano Research, Vol. 12, Issue 9
Carbon-Coated Na 2.2 V 1.2 Ti 0.8 (PO 4 ) 3 Cathode with Excellent Cycling Performance for Aqueous Sodium-Ion Batteries
journal, June 2018
- Lei, Ping; Wang, Yao; Zhang, Fang
- ChemElectroChem, Vol. 5, Issue 17
Development of a new alluaudite-based cathode material with high power and long cyclability for application in Na ion batteries in real-life
journal, January 2017
- Kim, Jongsoon; Kim, Hyungsub; Lee, Seongsu
- J. Mater. Chem. A, Vol. 5, Issue 42
Application of Operando X-ray Diffractometry in Various Aspects of the Investigations of Lithium/Sodium-Ion Batteries
journal, November 2018
- Zhu, Wen; Wang, Yuesheng; Liu, Dongqiang
- Energies, Vol. 11, Issue 11
High Energy Density Sodium-Ion Battery with Industrially Feasible and Air-Stable O3-Type Layered Oxide Cathode
journal, October 2017
- Deng, Jianqiu; Luo, Wen-Bin; Lu, Xiao
- Advanced Energy Materials, Vol. 8, Issue 5
Monovalent manganese based anodes and co-solvent electrolyte for stable low-cost high-rate sodium-ion batteries
journal, February 2018
- Firouzi, Ali; Qiao, Ruimin; Motallebi, Shahrokh
- Nature Communications, Vol. 9, Issue 1
Na 2.3 Cu 1.1 Mn 2 O 7−δ nanoflakes as enhanced cathode materials for high-energy sodium-ion batteries achieved by a rapid pyrosynthesis approach
journal, January 2020
- Soundharrajan, Vaiyapuri; Sambandam, Balaji; Alfaruqi, Muhammad H.
- Journal of Materials Chemistry A, Vol. 8, Issue 2
Rechargeable aqueous electrolyte batteries: from univalent to multivalent cation chemistry
journal, January 2019
- Demir-Cakan, Rezan; Palacin, M. Rosa; Croguennec, Laurence
- Journal of Materials Chemistry A, Vol. 7, Issue 36
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, December 2019
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie, Vol. 132, Issue 4
Understanding Fundamentals and Reaction Mechanisms of Electrode Materials for Na-Ion Batteries
journal, January 2018
- Yu, Linghui; Wang, Luyuan Paul; Liao, Hanbin
- Small, Vol. 14, Issue 16
Electrochemical Intercalation of Potassium into Graphite
journal, September 2016
- Zhao, Jin; Zou, Xiaoxi; Zhu, Yujie
- Advanced Functional Materials, Vol. 26, Issue 44
Exploration of Advanced Electrode Materials for Rechargeable Sodium‐Ion Batteries
journal, July 2018
- Sun, Yang; Guo, Shaohua; Zhou, Haoshen
- Advanced Energy Materials, Vol. 9, Issue 23
Caging Na 3 V 2 (PO 4 ) 2 F 3 Microcubes in Cross-Linked Graphene Enabling Ultrafast Sodium Storage and Long-Term Cycling
journal, July 2018
- Cai, Yangsheng; Cao, Xinxin; Luo, Zhigao
- Advanced Science, Vol. 5, Issue 9
Boron Substituted Na 3 V 2 (P 1 −x B x O 4 ) 3 Cathode Materials with Enhanced Performance for Sodium-Ion Batteries
journal, August 2016
- Hu, Pu; Wang, Xiaofang; Wang, Tianshi
- Advanced Science, Vol. 3, Issue 12
Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015
- Kubota, Kei; Komaba, Shinichi
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Progress in Aqueous Rechargeable Sodium-Ion Batteries
journal, March 2018
- Bin, Duan; Wang, Fei; Tamirat, Andebet Gedamu
- Advanced Energy Materials, Vol. 8, Issue 17
Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes
journal, September 2018
- Huang, Jianhang; Guo, Zhaowei; Ma, Yuanyuan
- Small Methods, Vol. 3, Issue 1
Fe-Based Tunnel-Type Na 0.61 [Mn 0.27 Fe 0.34 Ti 0.39 ]O 2 Designed by a New Strategy as a Cathode Material for Sodium-Ion Batteries
journal, August 2015
- Xu, Shuyin; Wang, Yuesheng; Ben, Liubin
- Advanced Energy Materials, Vol. 5, Issue 22
Extremely Small Pyrrhotite Fe 7 S 8 Nanocrystals with Simultaneous Carbon-Encapsulation for High-Performance Na-Ion Batteries
journal, November 2017
- Choi, Min-Jae; Kim, Jongsoon; Yoo, Jung-Keun
- Small, Vol. 14, Issue 2
Boron Substituted Na 3 V 2 (P 1−x B x O 4 ) 3 Cathode Materials with Enhanced Performance for Sodium-Ion Batteries
journal, January 2017
- Hu, Pu; Wang, Xiaofang; Wang, Tianshi
- Advanced Science, Vol. 4, Issue 2
Layered VS 2 Nanosheet-Based Aqueous Zn Ion Battery Cathode
journal, January 2017
- He, Pan; Yan, Mengyu; Zhang, Guobin
- Advanced Energy Materials, Vol. 7, Issue 11
Red blood cell-like hollow carbon sphere anchored ultrathin Na 2 Ti 3 O 7 nanosheets as long cycling and high rate-performance anodes for sodium-ion batteries
journal, January 2018
- Chen, Sheng; Pang, Yuanchao; Liang, Jin
- Journal of Materials Chemistry A, Vol. 6, Issue 27
Aqueous Batteries Operated at −50 °C
journal, November 2019
- Nian, Qingshun; Wang, Jiayue; Liu, Shuang
- Angewandte Chemie, Vol. 131, Issue 47
Porous V 2 O 5 microspheres: a high-capacity cathode material for aqueous zinc–ion batteries
journal, January 2019
- Hu, Ping; Zhu, Ting; Ma, Jingxuan
- Chemical Communications, Vol. 55, Issue 58