Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries
Abstract
Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. As a result, the Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.
- Authors:
-
- Chinese Academy of Sciences (CAS), Beijing (China)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE)
- OSTI Identifier:
- 1164333
- Report Number(s):
- BNL-107069-2014-JA
Journal ID: ISSN 1998-0124; VT1201000-05450-1005554
- Grant/Contract Number:
- AC02-98CH10886
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Research
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 1998-0124
- Publisher:
- Springer
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; sodium iron hexacyanoferrate; Na rich cathode; sodium-ion batteries; Prussian blue analogues; national synchrotron light source
Citation Formats
You, Ya, Yu, Xi -Qian, Yin, Ya -Xia, Nam, Kyung -Wan, and Guo, Yu -Guo. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries. United States: N. p., 2014.
Web. doi:10.1007/s12274-014-0588-7.
You, Ya, Yu, Xi -Qian, Yin, Ya -Xia, Nam, Kyung -Wan, & Guo, Yu -Guo. Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries. United States. https://doi.org/10.1007/s12274-014-0588-7
You, Ya, Yu, Xi -Qian, Yin, Ya -Xia, Nam, Kyung -Wan, and Guo, Yu -Guo. Mon .
"Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries". United States. https://doi.org/10.1007/s12274-014-0588-7. https://www.osti.gov/servlets/purl/1164333.
@article{osti_1164333,
title = {Sodium iron hexacyanoferrate with high Na content as a Na-rich cathode material for Na-ion batteries},
author = {You, Ya and Yu, Xi -Qian and Yin, Ya -Xia and Nam, Kyung -Wan and Guo, Yu -Guo},
abstractNote = {Owing to the worldwide abundance and low-cost of Na, room-temperature Na-ion batteries are emerging as attractive energy storage systems for large-scale grids. Increasing the Na content in cathode material is one of the effective ways to achieve high energy density. Prussian blue and its analogues (PBAs) are promising Na-rich cathode materials since they can theoretically store two Na ions per formula. However, increasing the Na content in PBAs cathode materials is a big challenge in the current. Here we show that sodium iron hexacyanoferrate with high Na content could be obtained by simply controlling the reducing agent and reaction atmosphere during synthesis. The Na content can reach as high as 1.63 per formula, which is the highest value for sodium iron hexacyanoferrate. This Na-rich sodium iron hexacyanoferrate demonstrates a high specific capacity of 150 mA h g-1 and remarkable cycling performance with 90% capacity retention after 200 cycles. Furthermore, the Na intercalation/de-intercalation mechanism is systematically studied by in situ Raman, X-ray diffraction and X-ray absorption spectroscopy analysis for the first time. As a result, the Na-rich sodium iron hexacyanoferrate could function as a plenteous Na reservoir and has great potential as a cathode material toward practical Na-ion batteries.},
doi = {10.1007/s12274-014-0588-7},
journal = {Nano Research},
number = 1,
volume = 8,
place = {United States},
year = {Mon Oct 27 00:00:00 EDT 2014},
month = {Mon Oct 27 00:00:00 EDT 2014}
}
Web of Science
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- Li, Yucen; Dang, Qi; Shi, Chunjing
- Journal of Materials Chemistry A, Vol. 7, Issue 40
Highly crystalline sodium manganese ferrocyanide microcubes for advanced sodium ion battery cathodes
journal, January 2019
- Peng, Fangwei; Yu, Lei; Gao, Pengyue
- Journal of Materials Chemistry A, Vol. 7, Issue 39
Electrochemical Performance of NaFeFe(CN) 6 Prepared by Solid Reaction for Sodium Ion Batteries
journal, January 2018
- Tang, Wan; Xie, Yingying; Peng, Fangwei
- Journal of The Electrochemical Society, Vol. 165, Issue 16
Prussian Blue Analogue Mesoframes for Enhanced Aqueous Sodium-ion Storage
journal, January 2018
- Sun, Huiyun; Zhang, Wei; Hu, Ming
- Crystals, Vol. 8, Issue 1, p. 23
Tin-Decorated Reduced Graphene Oxide and NaLi0.2Ni0.25Mn0.75O as Electrode Materials for Sodium-Ion Batteries
journal, April 2019
- Prosini, Pier Paolo; Carewska, Maria; Cento, Cinzia
- Materials, Vol. 12, Issue 7
Morphology and Structure of Electrodeposited Prussian Blue and Prussian White Thin Films
journal, April 2019
- Baggio, Bruna; Vicente, Cristiano; Pelegrini, Silvia
- Materials, Vol. 12, Issue 7
A Dual-Insertion Type Sodium-Ion Full Cell Based on High-Quality Ternary-Metal Prussian Blue Analogs
journal, January 2018
- Peng, Jian; Wang, Jinsong; Yi, Haocong
- Advanced Energy Materials, Vol. 8, Issue 11
Suppressing the P2-O2 Phase Transition of Na 0.67 Mn 0.67 Ni 0.33 O 2 by Magnesium Substitution for Improved Sodium-Ion Batteries
journal, May 2016
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Angewandte Chemie, Vol. 128, Issue 26
Size Engineering and Crystallinity Control Enable High‐Capacity Aqueous Potassium‐Ion Storage of Prussian White Analogues
journal, October 2018
- Li, Chang; Wang, Xusheng; Deng, Wenjun
- ChemElectroChem, Vol. 5, Issue 24
Towards K-Ion and Na-Ion Batteries as “Beyond Li-Ion”
journal, February 2018
- Kubota, Kei; Dahbi, Mouad; Hosaka, Tomooki
- The Chemical Record, Vol. 18, Issue 4
Coordinating gallium hexacyanocobaltate: Prussian blue-based nanomaterial for Li-ion storage
journal, January 2019
- Zhang, Kaiqiang; Lee, Tae Hyung; Bubach, Bailey
- RSC Advances, Vol. 9, Issue 46
Constructing a 3D compact sulfur host based on carbon-nanotube threaded defective Prussian blue nanocrystals for high performance lithium–sulfur batteries
journal, January 2020
- Shen, Guohong; Liu, Zhixiao; Liu, Piao
- Journal of Materials Chemistry A, Vol. 8, Issue 3
Cerium Hexacyanocobaltate: A Lanthanide-Compliant Prussian Blue Analogue for Li-Ion Storage
journal, December 2019
- Zhang, Kaiqiang; Lee, Tae Hyung; Cha, Joo Hwan
- ACS Omega, Vol. 4, Issue 25
Reversible structural evolution of sodium-rich rhombohedral Prussian blue for sodium-ion batteries
journal, February 2020
- Wang, Wanlin; Gang, Yong; Hu, Zhe
- Nature Communications, Vol. 11, Issue 1
Tin-Decorated Reduced Graphene Oxide and NaLi0.2Ni0.25Mn0.75O as Electrode Materials for Sodium-Ion Batteries
journal, April 2019
- Prosini, Pier Paolo; Carewska, Maria; Cento, Cinzia
- Materials, Vol. 12, Issue 7
Morphology and Structure of Electrodeposited Prussian Blue and Prussian White Thin Films
journal, April 2019
- Baggio, Bruna; Vicente, Cristiano; Pelegrini, Silvia
- Materials, Vol. 12, Issue 7