Criegee intermediates in the indoor environment. New insights
Abstract
Criegee intermediates are formed in the ozonolysis of alkenes and play an important role in indoor chemistry, notably as a source of OH radicals. Recent studies have shown that these Criegee intermediates react very quickly with NO2, SO2, and carbonyls, and in this study, steady-state calculations are used to inspect the potential impact of these data on indoor chemistry. It is shown that these reactions could accelerate NO3 formation and SO2 removal in the indoor environment significantly. In addition, reaction between Criegee intermediates and halogenated carbonyls could provide a significant loss process indoors, where currently one does not exist.
- Authors:
-
- School of Chemistry, Cantock's Close, University of Bristol, Bristol UK
- School of Chemistry, Cantock's Close, University of Bristol, Bristol UK; Combustion Research Facility, Sandia National Laboratories, Livermore CA USA
- The Centre for Atmospheric Science, The School of Earth, Atmospheric and Environmental Science, The University of Manchester, Manchester UK
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1111400
- Report Number(s):
- SAND-2013-5105J
Journal ID: ISSN 1600-0668; 456549
- Grant/Contract Number:
- AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Indoor Air
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 5; Journal ID: ISSN 1600-0668
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
Citation Formats
Shallcross, D. E., Taatjes, C. A., and Percival, C. J. Criegee intermediates in the indoor environment. New insights. United States: N. p., 2014.
Web. doi:10.1111/ina.12102.
Shallcross, D. E., Taatjes, C. A., & Percival, C. J. Criegee intermediates in the indoor environment. New insights. United States. https://doi.org/10.1111/ina.12102
Shallcross, D. E., Taatjes, C. A., and Percival, C. J. Tue .
"Criegee intermediates in the indoor environment. New insights". United States. https://doi.org/10.1111/ina.12102. https://www.osti.gov/servlets/purl/1111400.
@article{osti_1111400,
title = {Criegee intermediates in the indoor environment. New insights},
author = {Shallcross, D. E. and Taatjes, C. A. and Percival, C. J.},
abstractNote = {Criegee intermediates are formed in the ozonolysis of alkenes and play an important role in indoor chemistry, notably as a source of OH radicals. Recent studies have shown that these Criegee intermediates react very quickly with NO2, SO2, and carbonyls, and in this study, steady-state calculations are used to inspect the potential impact of these data on indoor chemistry. It is shown that these reactions could accelerate NO3 formation and SO2 removal in the indoor environment significantly. In addition, reaction between Criegee intermediates and halogenated carbonyls could provide a significant loss process indoors, where currently one does not exist.},
doi = {10.1111/ina.12102},
journal = {Indoor Air},
number = 5,
volume = 24,
place = {United States},
year = {Tue Mar 25 00:00:00 EDT 2014},
month = {Tue Mar 25 00:00:00 EDT 2014}
}
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Works referencing / citing this record:
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