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Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide
Abstract
We present a comprehensive study of the synthesis, structure, and magnetic properties of the honeycomb oxide Na3Mn2SbO6 supported by neutron diffraction, heat capacity, and magnetization measurements. The refinements of the neutron diffraction patterns (150, 50, and 45 K) using the Rietveld method confirm the monoclinic (S. G. C2/m) structure. Temperature-dependent magnetic susceptibilities measured at varying fields along with the heat capacity measurements demonstrate the coexistence of long-range ordering (∼42 K) and short-range ordering (∼65 K). The field-dependent isothermal magnetization measurements at 5 K indicate a spin-flop transition around 5 T. Rietveld refinements of the low-temperature (below 45 K) neutron diffraction data further confirm the long-range magnetic ordering. In addition, the temperature variation of the lattice parameters obtained from the neutron powder diffraction analysis exhibited a distinct anomaly near the antiferromagnetic transition temperature. The appearance of the concomitant broadened backgrounds in the neutron powder diffraction data collected at 80, 50, and 45 K supports the short-range ordering. The resultant magnetic structure consists of spins that are aligned antiparallel with the nearest neighbors and also with the spins of the adjacent honeycomb layers. The occurrence of a fully ordered magnetic ground state (Neel antiferromagnetic (AFM)) in Na3Mn2SbO6 consolidates the significance of fabricatingmore »
- Authors:
-
[2];
[3];
[4];
[1]
- Univ. of Delhi, New Delhi (India)
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Idaho National Laboratory (INL), Idaho Falls, ID (United States)
- Univ. of Texas at El Paso, TX (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); SERB (Govt. of India); University of Delhi
- OSTI Identifier:
- 2000319
- Grant/Contract Number:
- AC05-00OR22725; CRG/2021/003714; IoE/2021/12/FRP
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 62; Journal Issue: 19; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Layers; Neutron diffraction; Oxides; Quantum mechanics; Transition metals
Citation Formats
Yadav, Dileep Kumar, Zhang, Qiang, Gofryk, Krzysztof, Nair, Harikrishnan S., and Uma, Sitharaman. Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide. United States: N. p., 2023.
Web. doi:10.1021/acs.inorgchem.3c00666.
Yadav, Dileep Kumar, Zhang, Qiang, Gofryk, Krzysztof, Nair, Harikrishnan S., & Uma, Sitharaman. Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide. United States. https://doi.org/10.1021/acs.inorgchem.3c00666
Yadav, Dileep Kumar, Zhang, Qiang, Gofryk, Krzysztof, Nair, Harikrishnan S., and Uma, Sitharaman. Thu .
"Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide". United States. https://doi.org/10.1021/acs.inorgchem.3c00666.
@article{osti_2000319,
title = {Evidence of Long-Range and Short-Range Magnetic Ordering in the Honeycomb Na3Mn2SbO6 Oxide},
author = {Yadav, Dileep Kumar and Zhang, Qiang and Gofryk, Krzysztof and Nair, Harikrishnan S. and Uma, Sitharaman},
abstractNote = {We present a comprehensive study of the synthesis, structure, and magnetic properties of the honeycomb oxide Na3Mn2SbO6 supported by neutron diffraction, heat capacity, and magnetization measurements. The refinements of the neutron diffraction patterns (150, 50, and 45 K) using the Rietveld method confirm the monoclinic (S. G. C2/m) structure. Temperature-dependent magnetic susceptibilities measured at varying fields along with the heat capacity measurements demonstrate the coexistence of long-range ordering (∼42 K) and short-range ordering (∼65 K). The field-dependent isothermal magnetization measurements at 5 K indicate a spin-flop transition around 5 T. Rietveld refinements of the low-temperature (below 45 K) neutron diffraction data further confirm the long-range magnetic ordering. In addition, the temperature variation of the lattice parameters obtained from the neutron powder diffraction analysis exhibited a distinct anomaly near the antiferromagnetic transition temperature. The appearance of the concomitant broadened backgrounds in the neutron powder diffraction data collected at 80, 50, and 45 K supports the short-range ordering. The resultant magnetic structure consists of spins that are aligned antiparallel with the nearest neighbors and also with the spins of the adjacent honeycomb layers. The occurrence of a fully ordered magnetic ground state (Neel antiferromagnetic (AFM)) in Na3Mn2SbO6 consolidates the significance of fabricating new honeycomb oxides.},
doi = {10.1021/acs.inorgchem.3c00666},
journal = {Inorganic Chemistry},
number = 19,
volume = 62,
place = {United States},
year = {Thu May 04 00:00:00 EDT 2023},
month = {Thu May 04 00:00:00 EDT 2023}
}
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