Three-Dimensional Nanostructures Formed by Single Step, Two-Photon Exposures through Elastomeric Penrose Quasicrystal Phase Masks
Abstract
We describe the fabrication of unusual classes of three-dimensional (3D) nanostructures using single step, two-photon exposures of photopolymers through elastomeric phase masks with 5-fold, Penrose quasicrystalline layouts. Confocal imaging, computational studies, and 3D reconstructions reveal the essential aspects of the flow of light through these quasicrystal masks. Here, the resulting nanostructures show interesting features, including quasicrystalline layouts in planes parallel to the sample surfaces, with completely aperiodic variations through their depths, consistent with the optics. Spectroscopic measurements of transmission and reflection provide additional insights.
- Authors:
-
- Univ. of Illinois at Urbana-Champaign, IL (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Publication Date:
- Research Org.:
- Univ. of Illinois at Urbana-Champaign, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1876446
- Grant/Contract Number:
- FG02-07ER46471; FG02-07ER46453; AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nano Letters
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 8; Journal ID: ISSN 1530-6984
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; Chemical structure; Group theory; Mathematical methods; Nanostructures; Optics
Citation Formats
Shir, Daniel, Liao, Hongwei, Jeon, Seokwoo, Xiao, Dong, Johnson, Harley T., Bogart, Gregory R., Bogart, Katherine H. A., and Rogers, John A. Three-Dimensional Nanostructures Formed by Single Step, Two-Photon Exposures through Elastomeric Penrose Quasicrystal Phase Masks. United States: N. p., 2008.
Web. doi:10.1021/nl080841k.
Shir, Daniel, Liao, Hongwei, Jeon, Seokwoo, Xiao, Dong, Johnson, Harley T., Bogart, Gregory R., Bogart, Katherine H. A., & Rogers, John A. Three-Dimensional Nanostructures Formed by Single Step, Two-Photon Exposures through Elastomeric Penrose Quasicrystal Phase Masks. United States. https://doi.org/10.1021/nl080841k
Shir, Daniel, Liao, Hongwei, Jeon, Seokwoo, Xiao, Dong, Johnson, Harley T., Bogart, Gregory R., Bogart, Katherine H. A., and Rogers, John A. Tue .
"Three-Dimensional Nanostructures Formed by Single Step, Two-Photon Exposures through Elastomeric Penrose Quasicrystal Phase Masks". United States. https://doi.org/10.1021/nl080841k. https://www.osti.gov/servlets/purl/1876446.
@article{osti_1876446,
title = {Three-Dimensional Nanostructures Formed by Single Step, Two-Photon Exposures through Elastomeric Penrose Quasicrystal Phase Masks},
author = {Shir, Daniel and Liao, Hongwei and Jeon, Seokwoo and Xiao, Dong and Johnson, Harley T. and Bogart, Gregory R. and Bogart, Katherine H. A. and Rogers, John A.},
abstractNote = {We describe the fabrication of unusual classes of three-dimensional (3D) nanostructures using single step, two-photon exposures of photopolymers through elastomeric phase masks with 5-fold, Penrose quasicrystalline layouts. Confocal imaging, computational studies, and 3D reconstructions reveal the essential aspects of the flow of light through these quasicrystal masks. Here, the resulting nanostructures show interesting features, including quasicrystalline layouts in planes parallel to the sample surfaces, with completely aperiodic variations through their depths, consistent with the optics. Spectroscopic measurements of transmission and reflection provide additional insights.},
doi = {10.1021/nl080841k},
journal = {Nano Letters},
number = 8,
volume = 8,
place = {United States},
year = {Tue Jul 08 00:00:00 EDT 2008},
month = {Tue Jul 08 00:00:00 EDT 2008}
}
Works referenced in this record:
Complete photonic bandgaps in 12-fold symmetric quasicrystals
journal, April 2000
- Zoorob, M. E.; Charlton, M. D. B.; Parker, G. J.
- Nature, Vol. 404, Issue 6779
Symmetries of Quasicrystals
journal, January 1999
- Radin, Charles
- Journal of Statistical Physics, Vol. 95, Issue 5/6, p. 827-833
Three-Dimensional Nanofabrication with Elastomeric Phase Masks
journal, October 2007
- Shir, Daniel J.; Jeon, Seokwoo; Liao, Hongwei
- The Journal of Physical Chemistry B, Vol. 111, Issue 45
Quantum Yields of Photoacid Generation in 193-nm Chemically Amplified Resists by Fluorescence Imaging Spectroscopy
journal, November 2004
- Ray, Krishanu; Mason, Michael D.; Grober, Robert D.
- Chemistry of Materials, Vol. 16, Issue 26
A revolution in optical manipulation
journal, August 2003
- Grier, David G.
- Nature, Vol. 424, Issue 6950
Unconventional Methods for Fabricating and Patterning Nanostructures
journal, May 1999
- Xia, Younan; Rogers, John A.; Paul, Kateri E.
- Chemical Reviews, Vol. 99, Issue 7, p. 1823-1848
Photonic crystals through holographic lithography: Simple cubic, diamond-like, and gyroid-like structures
journal, June 2004
- Ullal, Chaitanya K.; Maldovan, Martin; Thomas, Edwin L.
- Applied Physics Letters, Vol. 84, Issue 26
Fabricating three-dimensional nanostructures using two photon lithography in a single exposure step
journal, January 2006
- Jeon, Seokwoo; Malyarchuk, Viktor; Rogers, John A.
- Optics Express, Vol. 14, Issue 6
Creating Periodic Three-Dimensional Structures by Multibeam Interference of Visible Laser
journal, June 2002
- Yang, Shu; Megens, Mischa; Aizenberg, Joanna
- Chemistry of Materials, Vol. 14, Issue 7, p. 2831-2833
Soft Lithography
journal, March 1998
- Xia, Younan; Whitesides, George M.
- Angewandte Chemie International Edition, Vol. 37, Issue 5, p. 550-575
Improved Pattern Transfer in Soft Lithography Using Composite Stamps
journal, June 2002
- Odom, Teri W.; Love, J. Christopher; Wolfe, Daniel B.
- Langmuir, Vol. 18, Issue 13, p. 5314-5320
Siloxane Polymers for High-Resolution, High-Accuracy Soft Lithography
journal, April 2000
- Schmid, H.; Michel, B.
- Macromolecules, Vol. 33, Issue 8, p. 3042-3049
Fabrication of photonic crystals for the visible spectrum by holographic lithography
journal, March 2000
- Campbell, M.; Sharp, D. N.; Harrison, M. T.
- Nature, Vol. 404, Issue 6773, p. 53-56
Large-Area 3D Nanostructures with Octagonal Quasicrystalline Symmetry via Phase-Mask Lithography
journal, May 2007
- Bita, I.; Choi, T.; Walsh, M. E.
- Advanced Materials, Vol. 19, Issue 10
Fabrication of three-dimensional polymer photonic crystal structures using single diffraction element interference lithography
journal, March 2003
- Divliansky, Ivan; Mayer, Theresa S.; Holliday, Kito S.
- Applied Physics Letters, Vol. 82, Issue 11, p. 1667-1669
Fabricating complex three-dimensional nanostructures with high-resolution conformable phase masks
journal, August 2004
- Jeon, S.; Park, J.-U.; Cirelli, R.
- Proceedings of the National Academy of Sciences, Vol. 101, Issue 34, p. 12428-12433
Molded transparent photopolymers and phase shift optics for fabricating three dimensional nanostructures
journal, January 2007
- Jeon, Seokwoo; Shir, Daniel J.; Nam, Yun Suk
- Optics Express, Vol. 15, Issue 10
Femtosecond laser interference technique with diffractive beam splitter for fabrication of three-dimensional photonic crystals
journal, August 2001
- Kondo, Toshiaki; Matsuo, Shigeki; Juodkazis, Saulius
- Applied Physics Letters, Vol. 79, Issue 6
Works referencing / citing this record:
Synthesis of Periodically Structured Titania Nanotube Films and Their Potential for Photonic Applications
journal, May 2011
- Lin, Jia; Liu, Kun; Chen, Xianfeng
- Small, Vol. 7, Issue 13
Rapid, High-Resolution 3D Interference Printing of Multilevel Ultralong Nanochannel Arrays for High-Throughput Nanofluidic Transport
journal, November 2015
- Park, Junyong; Kim, Kyung-Il; Kim, Kisun
- Advanced Materials, Vol. 27, Issue 48
Three-dimensional fabrication of heterogeneous microstructures using soft membrane deformation and optofluidic maskless lithography
journal, January 2009
- Lee, Seung Ah; Chung, Su Eun; Park, Wook
- Lab on a Chip, Vol. 9, Issue 12
25th Anniversary Article: Ordered Polymer Structures for the Engineering of Photons and Phonons
journal, December 2013
- Lee, Jae-Hwang; Koh, Cheong Yang; Singer, Jonathan P.
- Advanced Materials, Vol. 26, Issue 4
Optics of photonic quasicrystals
journal, February 2013
- Vardeny, Z. Valy; Nahata, Ajay; Agrawal, Amit
- Nature Photonics, Vol. 7, Issue 3
25th Anniversary Article: Ordered Polymer Structures for the Engineering of Photons and Phonons
journal, December 2013
- Lee, Jae-Hwang; Koh, Cheong Yang; Singer, Jonathan P.
- Advanced Materials, Vol. 26, Issue 4