Modified Calcium Manganites for Thermochemical Energy Storage Applications

Miller, James E.; Babiniec, Sean M.; Coker, Eric N.; Loutzenhiser, Peter G.; Stechel, Ellen B.; Ambrosini, Andrea

doi:10.3389/fenrg.2022.774099

Title: Modified Calcium Manganites for Thermochemical Energy Storage Applications

Abstract

CaAl _0.2 Mn _0.8 O _3-δ (CAM28) and CaTi _0.2 Mn _0.8 O _3-δ (CTM28) are perovskite metal oxides developed for high-temperature thermochemical energy storage (TCES) applications, e.g., in support of air Brayton power generation. Previous reports for these compounds focus on the equilibrium non-stoichiometry (δ) as a function of temperature and oxygen partial pressure (pO ₂ ) and the endotherm (or exotherm) accompanying changes in δ resulting from thermal reduction (or re-oxidation). Herein, we report results for elemental substitution and doping (Al, Co, Fe, La, Sr, Ti, Y, Zn, and Zr) of calcium manganites (CM) that establish the preference for CAM28 and CTM28. Techniques employed include conventional (screening and equilibrium) and ballistically heated multi-cycle thermogravimetric analysis (TGA), conventional and high temperature ( in-situ ) X-ray diffraction (XRD), and differential scanning calorimetry (DSC). Forward-looking results for A-site Y-doped materials, e.g., Ca _0.9 Y _0.1 MnO _3-δ (CYM910), establish a route to increasing the reduction enthalpy relative to CAM28 and CTM28, albeit at the expense of increased reduction temperatures and raw materials costs. A thermodynamic model presented for CAM28, but extendable to related materials, provides values for the reaction enthalpy and extent of reduction as a function of temperature and oxygenmore »« less

Authors:: Miller, James E.; Babiniec, Sean M.; Coker, Eric N.; Loutzenhiser, Peter G.; Stechel, Ellen B.; Ambrosini, Andrea

Publication Date:: Thu Apr 14 00:00:00 EDT 2022

Sponsoring Org.:: USDOE

OSTI Identifier:: 1863143

Grant/Contract Number:: FOA-0000805-1541

Resource Type:: Published Article

Journal Name:: Frontiers in Energy Research

Additional Journal Information:: Journal Name: Frontiers in Energy Research Journal Volume: 10; Journal ID: ISSN 2296-598X

Publisher:: Frontiers Media SA

Country of Publication:: Switzerland

Language:: English

Citation Formats


                    Miller, James E., Babiniec, Sean M., Coker, Eric N., Loutzenhiser, Peter G., Stechel, Ellen B., and Ambrosini, Andrea. Modified Calcium Manganites for Thermochemical Energy Storage Applications.  Switzerland: N. p., 2022. 
Web.  doi:10.3389/fenrg.2022.774099.

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                    Miller, James E., Babiniec, Sean M., Coker, Eric N., Loutzenhiser, Peter G., Stechel, Ellen B., & Ambrosini, Andrea. Modified Calcium Manganites for Thermochemical Energy Storage Applications.  Switzerland.  https://doi.org/10.3389/fenrg.2022.774099

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                    Miller, James E., Babiniec, Sean M., Coker, Eric N., Loutzenhiser, Peter G., Stechel, Ellen B., and Ambrosini, Andrea. Thu .  
"Modified Calcium Manganites for Thermochemical Energy Storage Applications".  Switzerland.  https://doi.org/10.3389/fenrg.2022.774099.

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@article{osti_1863143,

  title        = {Modified Calcium Manganites for Thermochemical Energy Storage Applications},

  author       = {Miller, James E. and Babiniec, Sean M. and Coker, Eric N. and Loutzenhiser, Peter G. and Stechel, Ellen B. and Ambrosini, Andrea},

  abstractNote = {CaAl 0.2 Mn 0.8 O 3-δ (CAM28) and CaTi 0.2 Mn 0.8 O 3-δ (CTM28) are perovskite metal oxides developed for high-temperature thermochemical energy storage (TCES) applications, e.g., in support of air Brayton power generation. Previous reports for these compounds focus on the equilibrium non-stoichiometry (δ) as a function of temperature and oxygen partial pressure (pO 2 ) and the endotherm (or exotherm) accompanying changes in δ resulting from thermal reduction (or re-oxidation). Herein, we report results for elemental substitution and doping (Al, Co, Fe, La, Sr, Ti, Y, Zn, and Zr) of calcium manganites (CM) that establish the preference for CAM28 and CTM28. Techniques employed include conventional (screening and equilibrium) and ballistically heated multi-cycle thermogravimetric analysis (TGA), conventional and high temperature ( in-situ ) X-ray diffraction (XRD), and differential scanning calorimetry (DSC). Forward-looking results for A-site Y-doped materials, e.g., Ca 0.9 Y 0.1 MnO 3-δ (CYM910), establish a route to increasing the reduction enthalpy relative to CAM28 and CTM28, albeit at the expense of increased reduction temperatures and raw materials costs. A thermodynamic model presented for CAM28, but extendable to related materials, provides values for the reaction enthalpy and extent of reduction as a function of temperature and oxygen partial pressure for use in design efforts. Taken as a whole, the results support the choice of Al-doped CaMnO 3-δ as a low-cost material for TCES in a high temperature air Brayton application, but point the way to achieving higher stored energy densities that could lead to overall cost savings.},

  doi          = {10.3389/fenrg.2022.774099},

  journal      = {Frontiers in Energy Research},

  number       = ,

  volume       = 10,

  place        = {Switzerland},

  year         = {Thu Apr 14 00:00:00 EDT 2022},

  month        = {Thu Apr 14 00:00:00 EDT 2022}

}

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Title: Modified Calcium Manganites for Thermochemical Energy Storage Applications

Abstract

Citation Formats

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Design and Characterization of a Novel Upward Flow Reactor for the Study of High-Temperature Thermal Reduction for Solar-Driven Processes journal, July 2017

Chemical Structures and Performance of Perovskite Oxides journal, July 2001

Oxygen non-stoichiometry, high-temperature properties, and phase diagram of CaMnO3–δ journal, February 2011

A review on high-temperature thermochemical energy storage based on metal oxides redox cycle journal, July 2018

Thermochemical oxygen pumping for improved hydrogen production in solar redox cycles journal, April 2019

Doped calcium manganites for advanced high-temperature thermochemical energy storage: Doped calcium manganites for thermochemical energy storage journal, December 2015

Analytical Model of CeO 2 Oxidation and Reduction journal, November 2013

Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C journal, November 2018

Solar electricity via an Air Brayton cycle with an integrated two-step thermochemical cycle for heat storage based on Co3O4/CoO redox reactions II: Kinetic analyses journal, December 2015

Nonstoichiometry and reductive decomposition of CaMnO journal, January 2005

Vacuum pumping options for application in solar thermochemical redox cycles – Assessment of mechanical-, jet- and thermochemical pumping systems journal, January 2017

Thermochemical behavior of perovskite oxides based on LaxSr1-x(Mn, Fe, Co)O3-δ and BaySr1-yCoO3-δ redox system for thermochemical energy storage at high temperatures journal, March 2019

Considerations in the Design of Materials for Solar-Driven Fuel Production Using Metal-Oxide Thermochemical Cycles journal, October 2013

Thermodynamic modelling of the cerium–oxygen system journal, April 2006

Thermochemical energy storage at high temperature via redox cycles of Mn and Co oxides: Pure oxides versus mixed ones journal, April 2014

Impact of La doping on the thermochemical heat storage properties of CaMnO3-δ journal, August 2021

Exploitation of thermochemical cycles based on solid oxide redox systems for thermochemical storage of solar heat. Part 1: Testing of cobalt oxide-based powders journal, April 2014

Evaluating thermodynamic performance limits of thermochemical energy storage subsystems using reactive perovskite oxide particles for concentrating solar power journal, June 2018

State of the art on the high-temperature thermochemical energy storage systems journal, December 2018

Investigation of La Sr1−Co M1−O3− (M = Mn, Fe) perovskite materials as thermochemical energy storage media journal, August 2015

Kinetic and thermodynamic considerations for oxygen absorption/desorption using cobalt oxide journal, January 2006

Demonstration of thermochemical oxygen pumping for atmosphere control in reduction reactions journal, August 2018

The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting journal, January 2018

The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants journal, October 2019

Using in-situ techniques to probe high-temperature reactions: thermochemical cycles for the production of synthetic fuels from CO ₂ and water
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Analysis of solid-state reaction in the performance of doped calcium manganites for thermal storage
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Outstanding Properties and Performance of CaTi0.5Mn0.5O3–δ for Solar-Driven Thermochemical Hydrogen Production
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Experimental study on optimized composition of mixed carbonate salt for sensible heat storage in solar thermal power plant
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Aluminum-doped strontium ferrites for a two-step solar thermochemical air separation cycle: Thermodynamic characterization and cycle analysis
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Developments in calcium/chemical looping and metal oxide redox cycles for high-temperature thermochemical energy storage: A review
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The compound energy formalism
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Design Principles of Perovskites for Thermochemical Oxygen Separation
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Exploring Ca–Ce–M–O (M = 3d Transition Metal) Oxide Perovskites for Solar Thermochemical Applications
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Considerations for the Design of a High-Temperature Particle Reoxidation Reactor for Extraction of Heat in Thermochemical Energy Storage Systems
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Techno-economic assessment of solid–gas thermochemical energy storage systems for solar thermal power applications
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Recent Advances in Thermochemical Energy Storage via Solid–Gas Reversible Reactions at High Temperature
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Measuring attrition resistance of oxygen carrier particles for chemical looping combustion with a customized jet cup
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Concentrating Solar Power Best Practices Study
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A critical review of high-temperature reversible thermochemical energy storage systems
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First-principles thermodynamic framework for the evaluation of thermochemical $H_{2} O$ - or ${CO}_{2}$ -splitting materials
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Aluminum-doped calcium manganite particles for solar thermochemical energy storage: Reactor design, particle characterization, and heat and mass transfer modeling
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High Performance Reduction/Oxidation Metal Oxides for Thermochemical Energy Storage (PROMOTES)
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Techno-Economic Analysis of a Concentrating Solar Power Plant Using Redox-Active Metal Oxides as Heat Transfer Fluid and Storage Media
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Algebraic Representation of Thermodynamic Properties and the Classification of Solutions
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A review of solar thermal energy storage in beds of particles: Packed and fluidized beds
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Technical Challenges and Opportunities for Concentrating Solar Power With Thermal Energy Storage
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Development on Thermochemical Energy Storage Based on CaO-Based Materials: A Review
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A review of material screening in pure and mixed-metal oxide thermochemical energy storage (TCES) systems for concentrated solar power (CSP) applications
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Nonstoichiometry and thermochemical stability of the perovskite-type La1−xSrxMnO3−δ
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Experimental, computational and thermodynamic studies in perovskites metal oxides for thermochemical fuel production: A review
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Entropy of oxidation and redox energetics of CaMnO
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ABO3 (A = La, Ba, Sr, K; B = Co, Mn, Fe) perovskites for thermochemical energy storage
conference, January 2016

Structural investigation of oxygen-deficient perovskite CaMnO2.75
journal, September 1991

Design and Characterization of a Novel Upward Flow Reactor for the Study of High-Temperature Thermal Reduction for Solar-Driven Processes
journal, July 2017

Chemical Structures and Performance of Perovskite Oxides
journal, July 2001

Oxygen non-stoichiometry, high-temperature properties, and phase diagram of CaMnO3–δ
journal, February 2011

A review on high-temperature thermochemical energy storage based on metal oxides redox cycle
journal, July 2018

Thermochemical oxygen pumping for improved hydrogen production in solar redox cycles
journal, April 2019

Doped calcium manganites for advanced high-temperature thermochemical energy storage: Doped calcium manganites for thermochemical energy storage
journal, December 2015

Analytical Model of CeO ₂ Oxidation and Reduction
journal, November 2013

Redox cycles with doped calcium manganites for thermochemical energy storage to 1000 °C
journal, November 2018

Solar electricity via an Air Brayton cycle with an integrated two-step thermochemical cycle for heat storage based on Co3O4/CoO redox reactions II: Kinetic analyses
journal, December 2015

Nonstoichiometry and reductive decomposition of CaMnO
journal, January 2005

Vacuum pumping options for application in solar thermochemical redox cycles – Assessment of mechanical-, jet- and thermochemical pumping systems
journal, January 2017

Thermochemical behavior of perovskite oxides based on LaxSr1-x(Mn, Fe, Co)O3-δ and BaySr1-yCoO3-δ redox system for thermochemical energy storage at high temperatures
journal, March 2019

Considerations in the Design of Materials for Solar-Driven Fuel Production Using Metal-Oxide Thermochemical Cycles
journal, October 2013

Thermodynamic modelling of the cerium–oxygen system
journal, April 2006

Thermochemical energy storage at high temperature via redox cycles of Mn and Co oxides: Pure oxides versus mixed ones
journal, April 2014

Impact of La doping on the thermochemical heat storage properties of CaMnO3-δ
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Exploitation of thermochemical cycles based on solid oxide redox systems for thermochemical storage of solar heat. Part 1: Testing of cobalt oxide-based powders
journal, April 2014

Evaluating thermodynamic performance limits of thermochemical energy storage subsystems using reactive perovskite oxide particles for concentrating solar power
journal, June 2018

State of the art on the high-temperature thermochemical energy storage systems
journal, December 2018

Investigation of La Sr1−Co M1−O3− (M = Mn, Fe) perovskite materials as thermochemical energy storage media
journal, August 2015

Kinetic and thermodynamic considerations for oxygen absorption/desorption using cobalt oxide
journal, January 2006

Demonstration of thermochemical oxygen pumping for atmosphere control in reduction reactions
journal, August 2018

The use of poly-cation oxides to lower the temperature of two-step thermochemical water splitting
journal, January 2018

The Calcium-Looping (CaCO3/CaO) process for thermochemical energy storage in Concentrating Solar Power plants
journal, October 2019