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Title: Boosting the cycling stability of Ni-rich layered oxide cathode by dry coating of ultrastable Li3V2(PO4)3 nanoparticles

Abstract

Nickel (Ni)-rich layered oxides such as LiNi0.6Co0.2Mn0.2O2 (NCM622) represent one of the most promising candidates for next-generation high-energy lithium-ion batteries (LIBs). However, the pristine Ni-rich cathode materials usually suffer from poor structural stability during cycling. In this work, we demonstrate a simple but effective approach to improve the cycling stability of the NCM622 cathode by dry coating of ultrastable Li3V2(PO4)3-carbon (LVP-C) nanoparticles, which leads to a robust composite cathode (NCM622/LVP-C) without sacrificing the specific energy density compared with pristine NCM622. The optimal NCM622/LVP-C composite presents a high specific capacity of 162 mA h g-1 at 0.5 C and excellent cycling performance with 85.0% capacity retention after 200 cycles at 2 C, higher than that of the pristine NCM622 (67.6%). Systematic characterization confirms that the LVP-C protective layer can effectively reduce the side reactions, restrict the cation mixing of NCM622 and improve its structural stability. Moreover, the NCM622/LVP-C||graphite full cells also show a commercial-level capacity of 3.2 mA h cm-2 and much improved cycling stability compared with NCM622/LVP-C||graphite full cells, indicating the great promise for low-cost, high-capacity and long-life LIBs.

Authors:
 [1];  [2];  [3];  [2]; ORCiD logo [4]; ORCiD logo [4];  [5];  [2]; ORCiD logo [6]; ORCiD logo [2]
+ Show Author Affiliations
  1. Univ. of California, San Diego, CA (United States); Tianjin Univ. (China)
  2. Univ. of California, San Diego, CA (United States)
  3. Department of NanoEngineering; University of California San Diego; La Jolla; USA; Program of Chemical Engineering
  4. Tianjin Univ. (China)
  5. Univ. of California, San Diego, CA (United States); Hebei Normal Univ., Shijiazhuang (China)
  6. New Mexico State Univ., Las Cruces, NM (United States)
Publication Date:
Research Org.:
Univ. of California, Los Angeles, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); China Scholarship Council; China Postdoctoral Science Foundation
OSTI Identifier:
1853161
Alternate Identifier(s):
OSTI ID: 1765409
Grant/Contract Number:  
SC0019381; 201706250088; 2020TQ0183; DESC0019381
Resource Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 13; Journal Issue: 5; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Ni-rich cathode; Li3V2(PO4)3; dry coating; high stability; lithium-ion batteries

Citation Formats

Wang, Dongdong, Yan, Qizhang, Li, Mingqian, Gao, Hongpeng, Tian, Jianhua, Shan, Zhongqiang, Wang, Ning, Luo, Jian, Zhou, Meng, and Chen, Zheng. Boosting the cycling stability of Ni-rich layered oxide cathode by dry coating of ultrastable Li3V2(PO4)3 nanoparticles. United States: N. p., 2021. Web. doi:10.1039/d0nr08305d.
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Wang, Dongdong, Yan, Qizhang, Li, Mingqian, Gao, Hongpeng, Tian, Jianhua, Shan, Zhongqiang, Wang, Ning, Luo, Jian, Zhou, Meng, & Chen, Zheng. Boosting the cycling stability of Ni-rich layered oxide cathode by dry coating of ultrastable Li3V2(PO4)3 nanoparticles. United States. https://doi.org/10.1039/d0nr08305d
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Wang, Dongdong, Yan, Qizhang, Li, Mingqian, Gao, Hongpeng, Tian, Jianhua, Shan, Zhongqiang, Wang, Ning, Luo, Jian, Zhou, Meng, and Chen, Zheng. Thu . "Boosting the cycling stability of Ni-rich layered oxide cathode by dry coating of ultrastable Li3V2(PO4)3 nanoparticles". United States. https://doi.org/10.1039/d0nr08305d. https://www.osti.gov/servlets/purl/1853161.
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@article{osti_1853161,
title = {Boosting the cycling stability of Ni-rich layered oxide cathode by dry coating of ultrastable Li3V2(PO4)3 nanoparticles},
author = {Wang, Dongdong and Yan, Qizhang and Li, Mingqian and Gao, Hongpeng and Tian, Jianhua and Shan, Zhongqiang and Wang, Ning and Luo, Jian and Zhou, Meng and Chen, Zheng},
abstractNote = {Nickel (Ni)-rich layered oxides such as LiNi0.6Co0.2Mn0.2O2 (NCM622) represent one of the most promising candidates for next-generation high-energy lithium-ion batteries (LIBs). However, the pristine Ni-rich cathode materials usually suffer from poor structural stability during cycling. In this work, we demonstrate a simple but effective approach to improve the cycling stability of the NCM622 cathode by dry coating of ultrastable Li3V2(PO4)3-carbon (LVP-C) nanoparticles, which leads to a robust composite cathode (NCM622/LVP-C) without sacrificing the specific energy density compared with pristine NCM622. The optimal NCM622/LVP-C composite presents a high specific capacity of 162 mA h g-1 at 0.5 C and excellent cycling performance with 85.0% capacity retention after 200 cycles at 2 C, higher than that of the pristine NCM622 (67.6%). Systematic characterization confirms that the LVP-C protective layer can effectively reduce the side reactions, restrict the cation mixing of NCM622 and improve its structural stability. Moreover, the NCM622/LVP-C||graphite full cells also show a commercial-level capacity of 3.2 mA h cm-2 and much improved cycling stability compared with NCM622/LVP-C||graphite full cells, indicating the great promise for low-cost, high-capacity and long-life LIBs.},
doi = {10.1039/d0nr08305d},
journal = {Nanoscale},
number = 5,
volume = 13,
place = {United States},
year = {Thu Jan 07 00:00:00 EST 2021},
month = {Thu Jan 07 00:00:00 EST 2021}
}
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https://doi.org/10.1039/d0nr08305d
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Works referenced in this record:

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries
journal, March 2015

  • Liu, Wen; Oh, Pilgun; Liu, Xien
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201409262

Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes: I. Nickel-Rich, LiNi
journal, December 2016

  • Schipper, Florian; Erickson, Evan M.; Erk, Christoph
  • Journal of The Electrochemical Society, Vol. 164, Issue 1
  • DOI: 10.1149/2.0351701jes

Preparation and Performance of the Heterostructured Material with a Ni-Rich Layered Oxide Core and a LiNi 0.5 Mn 1.5 O 4 -like Spinel Shell
journal, April 2019

  • Huang, Yan; Zhang, Xiaohui; Yu, Ruizhi
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 18
  • DOI: 10.1021/acsami.9b01957

LiFePO 4 -Coated LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Materials with Improved High Voltage Electrochemical Performance and Enhanced Safety for Lithium Ion Pouch Cells
journal, January 2019

  • Zhu, Lei; Yan, Ting-Fang; Jia, Di
  • Journal of The Electrochemical Society, Vol. 166, Issue 3
  • DOI: 10.1149/2.0651903jes

Solvothermal synthesis of hedgehog-like mesoporous rutile TiO 2 with improved lithium storage properties
journal, January 2017

High-rate capability of Li3V2(PO4)3/C composites prepared via a polyvinylpyrrolidone-assisted sol–gel method
journal, June 2012

Interfacial Film Li 1.3 Al 0.3 Ti 1.7 PO 4 -Coated LiNi 0.6 Co 0.2 Mn 0.2 O 2 for the Long Cycle Stability of Lithium-Ion Batteries
journal, October 2019

  • Song, Guowen; Zhong, Hui; Wang, Zhen
  • ACS Applied Energy Materials, Vol. 2, Issue 11
  • DOI: 10.1021/acsaem.9b01412

Suppressing H2–H3 phase transition in high Ni–low Co layered oxide cathode material by dual modification
journal, January 2020

  • Jamil, Sidra; Wang, Gang; Yang, Li
  • Journal of Materials Chemistry A, Vol. 8, Issue 40
  • DOI: 10.1039/D0TA07965K

Novel layered Li 3 V 2 (PO 4 ) 3 /rGO&C sheets as high-rate and long-life lithium ion battery cathodes
journal, January 2016

  • Wei, Qiulong; Xu, Yanan; Li, Qidong
  • Chemical Communications, Vol. 52, Issue 56
  • DOI: 10.1039/C6CC03629E

Rational Design and Synthesis of Li 3 V 2 (PO 4 ) 3 /C Nanocomposites As High-Performance Cathodes for Lithium-Ion Batteries
journal, May 2018

Probing Li-Ni Cation Disorder in Li 1− x Ni 1+ x − y Al y O 2 Cathode Materials by Neutron Diffraction
journal, January 2012

  • Cai, Lu; Liu, Zengcai; An, Ke
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.005207jes

Front Cover: Highly Tunable Growth and Etching of Silica Shells on Surfactant‐Free Gold Nanostars (ChemNanoMat 1/2020)
journal, October 2019

Anthracite-Derived Dual-Phase Carbon-Coated Li 3 V 2 (PO 4 ) 3 as High-Performance Cathode Material for Lithium Ion Batteries
journal, December 2017

  • Ding, Xiao-Kai; Zhang, Lu-Lu; Yang, Xue-Lin
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 49
  • DOI: 10.1021/acsami.7b14117

A long-lasting dual-function electrolyte additive for stable lithium metal batteries
journal, September 2020

Li 3 V 2 (PO 4 ) 3 encapsulated flexible free-standing nanofabric cathodes for fast charging and long life-cycle lithium-ion batteries
journal, January 2016

  • Sun, Pingping; Zhao, Xueying; Chen, Renpeng
  • Nanoscale, Vol. 8, Issue 14
  • DOI: 10.1039/C5NR08832A

Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Novel dry deposition of LiNbO3 or Li2ZrO3 on LiNi0.6Co0.2Mn0.2O2 for high performance all-solid-state lithium batteries
journal, April 2020

Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffraction
journal, May 2013

Structural and Electrochemical Study of Al 2 O 3 and TiO 2 Coated Li 1.2 Ni 0.13 Mn 0.54 Co 0.13 O 2 Cathode Material Using ALD
journal, June 2013

  • Zhang, Xiaofeng; Belharouak, Ilias; Li, Li
  • Advanced Energy Materials, Vol. 3, Issue 10
  • DOI: 10.1002/aenm.201300269

Electrochemical Properties of the LiNi 0.6 Co 0.2 Mn 0.2 O 2 Cathode Material Modified by Lithium Tungstate under High Voltage
journal, May 2018

  • Fu, Jiale; Mu, Daobin; Wu, Borong
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 23
  • DOI: 10.1021/acsami.8b04167

Hierarchically Micro-/Nanostructured TiO 2 /Micron Carbon Fibers Composites for Long-Life and Fast-Charging Lithium-Ion Batteries
journal, December 2017

  • Wang, Dongdong; Zhang, Guanghui; Shan, Zhongqiang
  • ChemElectroChem, Vol. 5, Issue 3
  • DOI: 10.1002/celc.201700946

LISICON structured Li 3 V 2 (PO 4 ) 3 with high rate and ultralong life for low-temperature lithium-ion batteries
journal, January 2018

  • Qin, Ruihuan; Wei, Yaqing; Zhai, Tianyou
  • Journal of Materials Chemistry A, Vol. 6, Issue 20
  • DOI: 10.1039/C8TA01124A

A promising cathode for Li-ion batteries: Li3V2(PO4)3
journal, July 2016

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Ultrafast Cathode Characteristics of Nanocrystalline-Li 3 V 2 (PO 4 ) 3 /Carbon Nanofiber Composites
journal, January 2015

  • Naoi, Katsuhiko; Kisu, Kazuaki; Iwama, Etsuro
  • Journal of The Electrochemical Society, Vol. 162, Issue 6
  • DOI: 10.1149/2.0021506jes

High power high safety battery with electrospun Li3V2(PO4)3 cathode and Li4Ti5O12 anode with 95% energy efficiency
journal, October 2016

Enhanced electrochemical properties of the Cd-modified LiNi0.6Co0.2Mn0.2O2 cathode materials at high cut-off voltage
journal, August 2018

Enhanced electrochemical performance and thermal stability of LiNi0.80Co0.15Al0.05O2 via nano-sized LiMnPO4 coating
journal, December 2016

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