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Title: Characterization of Nanoscale Pores in Tight Gas Sandstones Using Complex Techniques: A Case Study of a Linxing Tight Gas Sandstone Reservoir

Abstract

Pore structures with rich nanopores and permeability in tight gas reservoirs are poorly understood up to date. Advanced techniques are needed to be employed to accurately characterize pore structures, especially tiny pores which include micron and nanopores. In this study, various experimental techniques such as scanning electron microscopy (SEM), nuclear magnetic resonance (NMR) T 2 , nitrogen adsorption method, and NMR cryoporometry (NMRC) are combined to interrogate the complex pore systems of the tight gas reservoir in the Linxing formation, Ordos Basin, China. Results show that tight gas sandstones are primarily comprised of residual interparticle and clay-dominated pores. Clay and quartz are two dominate minerals while pyrite occupies a nontrivial amount as well. The permeability of tight gas sandstones is very low, exhibiting an extremely poor positive correlation with porosity. While pore types and relative pore contents are more influential factors on the permeability, accurate characterization of pore size distribution is critical for the permeability of tight gas sandstones. Therefore, complementary characterization methods are carried out, indicating that neither small pores with radii < 100 nm (around peak 1 in NMR T 2 distribution) nor large pores with radii > 5 μ m (around peak 3 in NMR T 2 distribution) control the permeability by analyzing the connectivity of the pores in various size ranges, but rather pores averaging approximately 350 ± X nm (around peak 2 in NMR T 2 distribution) have sufficient connectivity to host and transmit hydrocarbons. The pore size of tight gas sandstones is dominated by the clay-rich mineral assemblage. The study shows that the NMRC technique can be a very promising method, especially when referred to as a promising “roadmap” on how to interrogate tight formations such as the tight gas sands or even shale especially for the nanopore characterization.

Authors:
ORCiD logo [1];  [2];  [2]; ORCiD logo [2];  [3];
  1. China University of Petroleum, Beijing, China, School of Earth Sciences, The Ohio State University, Columbus, Ohio, USA
  2. China University of Petroleum, Beijing, China
  3. School of Earth Sciences, The Ohio State University, Columbus, Ohio, USA
Publication Date:
Research Org.:
The Ohio State University, Columbus, OH (United States)
Sponsoring Org.:
USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division (CSGB); Science Foundation of China University of Petroleum
OSTI Identifier:
1837480
Alternate Identifier(s):
OSTI ID: 1980901
Grant/Contract Number:  
SC0006878; 2462021XKBH007
Resource Type:
Published Article
Journal Name:
Geofluids
Additional Journal Information:
Journal Name: Geofluids Journal Volume: 2021; Journal ID: ISSN 1468-8115
Publisher:
Hindawi Publishing Corporation
Country of Publication:
Canada
Language:
English
Subject:
15 GEOTHERMAL ENERGY

Citation Formats

Lyu, Chaohui, Zhong, Liguo, Ning, Zhengfu, Wang, Qing, Cole, David R., and Fattah, ed., Mohammed. Characterization of Nanoscale Pores in Tight Gas Sandstones Using Complex Techniques: A Case Study of a Linxing Tight Gas Sandstone Reservoir. Canada: N. p., 2021. Web. doi:10.1155/2021/7670556.
Lyu, Chaohui, Zhong, Liguo, Ning, Zhengfu, Wang, Qing, Cole, David R., & Fattah, ed., Mohammed. Characterization of Nanoscale Pores in Tight Gas Sandstones Using Complex Techniques: A Case Study of a Linxing Tight Gas Sandstone Reservoir. Canada. https://doi.org/10.1155/2021/7670556
Lyu, Chaohui, Zhong, Liguo, Ning, Zhengfu, Wang, Qing, Cole, David R., and Fattah, ed., Mohammed. Mon . "Characterization of Nanoscale Pores in Tight Gas Sandstones Using Complex Techniques: A Case Study of a Linxing Tight Gas Sandstone Reservoir". Canada. https://doi.org/10.1155/2021/7670556.
@article{osti_1837480,
title = {Characterization of Nanoscale Pores in Tight Gas Sandstones Using Complex Techniques: A Case Study of a Linxing Tight Gas Sandstone Reservoir},
author = {Lyu, Chaohui and Zhong, Liguo and Ning, Zhengfu and Wang, Qing and Cole, David R. and Fattah, ed., Mohammed},
abstractNote = {Pore structures with rich nanopores and permeability in tight gas reservoirs are poorly understood up to date. Advanced techniques are needed to be employed to accurately characterize pore structures, especially tiny pores which include micron and nanopores. In this study, various experimental techniques such as scanning electron microscopy (SEM), nuclear magnetic resonance (NMR) T 2 , nitrogen adsorption method, and NMR cryoporometry (NMRC) are combined to interrogate the complex pore systems of the tight gas reservoir in the Linxing formation, Ordos Basin, China. Results show that tight gas sandstones are primarily comprised of residual interparticle and clay-dominated pores. Clay and quartz are two dominate minerals while pyrite occupies a nontrivial amount as well. The permeability of tight gas sandstones is very low, exhibiting an extremely poor positive correlation with porosity. While pore types and relative pore contents are more influential factors on the permeability, accurate characterization of pore size distribution is critical for the permeability of tight gas sandstones. Therefore, complementary characterization methods are carried out, indicating that neither small pores with radii < 100   nm (around peak 1 in NMR T 2 distribution) nor large pores with radii > 5   μ m (around peak 3 in NMR T 2 distribution) control the permeability by analyzing the connectivity of the pores in various size ranges, but rather pores averaging approximately 350 ± X   nm (around peak 2 in NMR T 2 distribution) have sufficient connectivity to host and transmit hydrocarbons. The pore size of tight gas sandstones is dominated by the clay-rich mineral assemblage. The study shows that the NMRC technique can be a very promising method, especially when referred to as a promising “roadmap” on how to interrogate tight formations such as the tight gas sands or even shale especially for the nanopore characterization.},
doi = {10.1155/2021/7670556},
journal = {Geofluids},
number = ,
volume = 2021,
place = {Canada},
year = {Mon Dec 27 00:00:00 EST 2021},
month = {Mon Dec 27 00:00:00 EST 2021}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1155/2021/7670556

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Works referenced in this record:

Pore structure of hydrating cement paste by magnetic resonance relaxation analysis and freezing
journal, January 1996


Recommendations for the characterization of porous solids (Technical Report)
journal, January 1994

  • Rouquerol, J.; Avnir, D.; Fairbridge, C. W.
  • Pure and Applied Chemistry, Vol. 66, Issue 8, p. 1739-1758
  • DOI: 10.1351/pac199466081739

NMR cryoporometry characterisation studies of the relation between drug release profile and pore structural evolution of polymeric nanoparticles
journal, July 2014


Comparison of NMR Cryoporometry, Mercury Intrusion Porosimetry, and DSC Thermoporosimetry in Characterizing Pore Size Distributions of Compressed Finely Ground Calcium Carbonate Structures
journal, October 2004

  • Gane, Patrick A. C.; Ridgway, Cathy J.; Lehtinen, Esa
  • Industrial & Engineering Chemistry Research, Vol. 43, Issue 24
  • DOI: 10.1021/ie049448p

Pore structure characteristics of lower Silurian shales in the southern Sichuan Basin, China: Insights to pore development and gas storage mechanism
journal, February 2016


Insight into the Pore Structure of Tight Gas Sandstones: A Case Study in the Ordos Basin, NW China
journal, November 2017


Pore structure characterization, permeability evaluation and enhanced gas recovery techniques of tight gas sandstones
journal, January 2016


Pore structure characterization of coal by NMR cryoporometry
journal, February 2017


Analysis Of Pore Throat Size And Use Of The Waxman-Smits Equation To Determine Ooip In Spindle Field, Colorado
conference, September 1980

  • Kolodzie, Stanley
  • SPE Annual Technical Conference and Exhibition, All Days
  • DOI: 10.2118/9382-MS

Experimental study of boundary condition effects on spontaneous imbibition in tight sandstones
journal, January 2019


Size Distribution and Fractal Characteristics of Coal Pores through Nuclear Magnetic Resonance Cryoporometry
journal, July 2017


Characterisation of porous solids using small-angle scattering and NMR cryoporometry
journal, July 2004

  • Dore, J. C.; Webber, J. B. W.; Strange, J. H.
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 241, Issue 1-3
  • DOI: 10.1016/j.colsurfa.2004.04.005

Tight Gas Sands
journal, June 2006

  • Holditch, Stephen A.
  • Journal of Petroleum Technology, Vol. 58, Issue 06
  • DOI: 10.2118/103356-JPT

Molecular simulation and experimental characterization of the nanoporous structures of coal and gas shale
journal, January 2014


Application of NMR T 2 to Pore Size Distribution and Movable Fluid Distribution in Tight Sandstones
journal, January 2018


Tight gas sands permeability estimation from mercury injection capillary pressure and nuclear magnetic resonance data
journal, June 2012


Combined MR-Relaxation and MR-Cryoporometry in the study of bone microstructure
journal, April 2001


Porosity type analysis and permeability model for micro-trans-pores, meso-macro-pores and cleats of coal samples
journal, November 2015


Relationships between characteristics of interfacial water and human bone tissues
journal, November 2006


Characterization of Brazilian tight gas sandstones relating permeability and Angstrom-to micron-scale pore structures
journal, November 2015

  • Schmitt, Mayka; Fernandes, Celso Peres; Wolf, Fabiano G.
  • Journal of Natural Gas Science and Engineering, Vol. 27
  • DOI: 10.1016/j.jngse.2015.09.027

Characteristics of microscopic pore structure and its influence on spontaneous imbibition of tight gas reservoir in the Ordos Basin, China
journal, January 2019


The permeability of natural soft clays. Part II: Permeability characteristics
journal, November 1983

  • Tavenas, F.; Jean, P.; Leblond, P.
  • Canadian Geotechnical Journal, Vol. 20, Issue 4
  • DOI: 10.1139/t83-073

Characterization of Nanoporous Systems in Gas Shales by Low Field NMR Cryoporometry
journal, October 2016


A review on pore structure characterization in tight sandstones
journal, February 2018


Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrock pores
journal, June 2012

  • Loucks, Robert G.; Reed, Robert M.; Ruppel, Stephen C.
  • AAPG Bulletin, Vol. 96, Issue 6
  • DOI: 10.1306/08171111061

Characterization and Analysis of Porosity and Pore Structures
journal, January 2015

  • Anovitz, Lawrence M.; Cole, David R.
  • Reviews in Mineralogy and Geochemistry, Vol. 80, Issue 1
  • DOI: 10.2138/rmg.2015.80.04

NMR cryoporometry to study the fiber wall structure and the effect of drying
journal, November 2009


Effects of hydration on fractures and shale permeability under different confining pressures: An experimental study
journal, May 2019


Nuclear magnetic resonance cryoporometry as a tool to measure pore size distribution of shale rock
journal, July 2016

  • Zhang, Qian; Dong, YanHui; Tong, ShaoQing
  • Chinese Science Bulletin, Vol. 61, Issue 21
  • DOI: 10.1360/N972015-01267

Formation damage prevention using microemulsion in tight sandstone gas reservoir
journal, February 2019


Effect of pore structure on the producibility of tight-gas sandstones
journal, April 2014


Pore network modelling of fluid flow in tight formations considering boundary layer effect and media deformation
journal, September 2019


NMR and nuclear spin relaxation of cement and concrete materials
journal, June 2009


NMR cryoporometry: Principles, applications and potential
journal, February 2009

  • Petrov, Oleg V.; Furó, István
  • Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 54, Issue 2
  • DOI: 10.1016/j.pnmrs.2008.06.001

Fractal Analysis of Pore Network in Tight Gas Sandstones Using NMR Method: A Case Study from the Ordos Basin, China
journal, September 2017


Tight gas sandstone reservoirs in China: characteristics and recognition criteria
journal, June 2012