Easy-Processable and Aging-Free All-Polymer Polysiloxane Composites

Shen, Liyang; Wang, Tung-ping; Goyal, Shailja; Lee, Ting-Han; Lin, Fang-Yi; Torres, Sabrina; Robison, Thomas; Cochran, Eric W.

doi:10.1021/acsapm.0c01088

Title: Easy-Processable and Aging-Free All-Polymer Polysiloxane Composites

Abstract

In this work, we report all-polymer polysiloxane composites that overcome the long-standing processing problems of silica-reinforced silicone rubbers. Polystyrene fillers are dispersed with styrene/dimethylsiloxane symmetric diblock and triblock copolymers that control the filler morphology, filler–matrix interactions, and filler–filler interactions. Surprisingly, the composites not only rival the traditional silica-reinforced polysiloxane in mechanical properties of cured materials but also have better processability and stability than the silica-filled compound before curing. Large amplitude oscillatory shear experiments demonstrate that the triblock copolymer addition strongly affects the rheological properties. We hypothesize that the bridges and entangled loops that were formed by the triblock copolymer can connect different PS domains to provide additional reinforcement. The aging effect that originates from PDMS chain adsorption on the filler particle surface is also avoided because of the thermodynamic repulsion between PS and PDMS phases.

Authors:

^[1];

^[1]; Goyal, Shailja ^[1]; Lee, Ting-Han ^[1];

^[1]; Torres, Sabrina ^[2]; Robison, Thomas ^[2];

^[1]

Iowa State Univ., Ames, IA (United States)
Kansas City National Security Campus (KCNSC), Kansas City, MO (United States)

Publication Date:: Thu Nov 19 00:00:00 EST 2020

Research Org.:: Kansas City Nuclear Security Campus (KCNSC), Kansas City, MO (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1826745

Grant/Contract Number:: NA0002839

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Polymer Materials

Additional Journal Information:: Journal Volume: 2; Journal Issue: 12; Journal ID: ISSN 2637-6105

Publisher:: ACS Publications

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; polysiloxane composites; block copolymers; polystyrene-b-polydimethylsiloxane; mechanical reinforcement; large amplitude oscillatory shear; transmission electron microscopy

Citation Formats


                    Shen, Liyang, Wang, Tung-ping, Goyal, Shailja, Lee, Ting-Han, Lin, Fang-Yi, Torres, Sabrina, Robison, Thomas, and Cochran, Eric W. Easy-Processable and Aging-Free All-Polymer Polysiloxane Composites.  United States: N. p., 2020. 
Web.  doi:10.1021/acsapm.0c01088.

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                    Shen, Liyang, Wang, Tung-ping, Goyal, Shailja, Lee, Ting-Han, Lin, Fang-Yi, Torres, Sabrina, Robison, Thomas, & Cochran, Eric W. Easy-Processable and Aging-Free All-Polymer Polysiloxane Composites.  United States.  https://doi.org/10.1021/acsapm.0c01088

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                    Shen, Liyang, Wang, Tung-ping, Goyal, Shailja, Lee, Ting-Han, Lin, Fang-Yi, Torres, Sabrina, Robison, Thomas, and Cochran, Eric W. Thu .  
"Easy-Processable and Aging-Free All-Polymer Polysiloxane Composites".  United States.  https://doi.org/10.1021/acsapm.0c01088.  https://www.osti.gov/servlets/purl/1826745.

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@article{osti_1826745,

  title        = {Easy-Processable and Aging-Free All-Polymer Polysiloxane Composites},

  author       = {Shen, Liyang and Wang, Tung-ping and Goyal, Shailja and Lee, Ting-Han and Lin, Fang-Yi and Torres, Sabrina and Robison, Thomas and Cochran, Eric W.},

  abstractNote = {In this work, we report all-polymer polysiloxane composites that overcome the long-standing processing problems of silica-reinforced silicone rubbers. Polystyrene fillers are dispersed with styrene/dimethylsiloxane symmetric diblock and triblock copolymers that control the filler morphology, filler–matrix interactions, and filler–filler interactions. Surprisingly, the composites not only rival the traditional silica-reinforced polysiloxane in mechanical properties of cured materials but also have better processability and stability than the silica-filled compound before curing. Large amplitude oscillatory shear experiments demonstrate that the triblock copolymer addition strongly affects the rheological properties. We hypothesize that the bridges and entangled loops that were formed by the triblock copolymer can connect different PS domains to provide additional reinforcement. The aging effect that originates from PDMS chain adsorption on the filler particle surface is also avoided because of the thermodynamic repulsion between PS and PDMS phases.},

  doi          = {10.1021/acsapm.0c01088},

  journal      = {ACS Applied Polymer Materials},

  number       = 12,

  volume       = 2,

  place        = {United States},

  year         = {Thu Nov 19 00:00:00 EST 2020},

  month        = {Thu Nov 19 00:00:00 EST 2020}

}

Copy to clipboard

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Title: Easy-Processable and Aging-Free All-Polymer Polysiloxane Composites

Abstract

Citation Formats

Silicone Elastomer Developments 1967–1977 journal, July 1979

Effect of reinforcing fillers on the rheology of polymer melts journal, August 1992

Block copolymers of polystyrene and poly(dimethyl siloxane). I. Synthesis and characterization journal, January 1980

Large amplitude oscillatory shear behavior of PEO-PPO-PEO triblock copolymer solutions journal, August 2005

Bound rubber and “crepe hardening” in silicone rubber journal, December 1977

Characterization of chain binding to filler in silicone-silica systems journal, August 1985

Elastomer reinforcement from a glassy polymer polymerized in situ journal, October 1988

A review of nonlinear oscillatory shear tests: Analysis and application of large amplitude oscillatory shear (LAOS) journal, December 2011

Interpenetrating polymer networks derived from silylated soybean oil and polydimethylsiloxane journal, May 2013

Viscosity–molecular weight relationship for polydimethylsiloxane journal, May 1966

Hierarchically Ordered Montmorillonite Block Copolymer Brushes journal, February 2010

Block copolymer compatibilizers for polystyrene/poly(dimethylsiloxane) blends journal, January 2002

Second‐Order Transition Temperatures and Related Properties of Polystyrene. I. Influence of Molecular Weight journal, June 1950

Reinforcement of Silicone Rubber by Particulate Silica journal, September 1975

Morphologies of strongly segregated polystyrene-poly(dimethylsiloxane) diblock copolymers journal, January 1995

Polystyrene- block -Polydimethylsiloxane as a Potential Silica Substitute for Polysiloxane Reinforcement journal, May 2020

The Influence of Fumed Silica Properties on the Processing, Curing, and Reinforcement Properties of Silicone Rubber journal, March 1993

Role of particulate fillers in elastomer reinforcement: a review journal, June 1979

The effect of compatibilization and rheological properties of polystyrene and poly(dimethylsiloxane) on phase structure of polystyrene/poly(dimethylsiloxane) blends: Properties of PS-PDMS Copolymer Blends journal, January 2004

Elastomers based on α,ω-dihydroxy-polydimethylsiloxane/polystyrene blends: Morphology and mechanical properties journal, January 2006

Comicellization of Diblock and Triblock Copolymers in Selective Solvents journal, May 2003

Melt rheology of organoclay and fumed silica nanocomposites journal, April 2008

Influence of Polystyrene on PDMS IPNs Blend Membrane Performance journal, February 2012

Thermoplastic polydimethylsiloxane with l ‐phenylalanine‐based hydrogen‐bond networks journal, June 2017

Diblock copolymers as emulsifying agents in polymer blends: Influence of molecular weight, architecture, and chemical composition journal, July 1996

Preparation and Properties of Polydimethylsiloxane and Its Block Copolymers with Styrene journal, September 1975

Rheology and structure of precipitated silica and poly(dimethyl siloxane) system journal, March 2004

High χ–Low N Block Polymers: How Far Can We Go? journal, September 2015

Block Copolymers of Polydimethylsiloxane and Polystyrene journal, January 1970

Rheology of fumed silica/polydimethylsiloxane suspensions journal, January 2017

Aging effects of precipitated silica in poly(dimethylsiloxane) journal, May 2007

Generation of glassy ellipsoidal particles within an elastomer by in situ polymerization, elongation at an elevated temperature, and finally cooling under strain journal, September 1990

Morphology and electrical conductivity of polyethylene/polypropylene blend filled with thermally reduced graphene oxide and surfactant exfoliated graphene journal, September 2015

The effect of block copolymer architecture on the coalescence and interfacial elasticity in compatibilized polymer blends journal, May 2005

Structure & strength of silica-PDMS nanocomposites journal, April 2010

Phase structural formation and oscillation in polystyrene-block-polydimethylsiloxane thin films journal, January 2012

Biobased interpenetrating polymers networks derived from oligomerized soybean oil and polydimethylsiloxane journal, December 2014

Rheological behaviors of fumed silica filled polydimethylsiloxane suspensions journal, October 2013

Aging Phenomena in Silica-Filled Polydimethylsiloxane journal, September 1999

Preparation, morphology, and mechanical properties of elastomers based on ?,?-dihydroxy-polydimethylsiloxane/polystyrene blends journal, January 2004

Solvent Dependence of the Morphology of Spin-Coated Thin Films of Polydimethylsiloxane-Rich Polystyrene- block -Polydimethylsiloxane Copolymers journal, June 2012

Miniature universal testing platform: from extensional melt rheology to solid-state deformation behavior journal, August 2004

Compounding Fumed Silicas into Polydimethylsiloxane: Bound Rubber and Final Aggregate Size journal, November 1997

Preparation, morphology, and mechanical properties of elastomers based on polydimethylsiloxane/ polystyrene blends journal, April 2009

Reinforcement of elastomeric poly(dimethylsiloxane) by glassy poly(diphenylsiloxane) journal, January 1990

Silicone Elastomer Developments 1967–1977
journal, July 1979

Effect of reinforcing fillers on the rheology of polymer melts
journal, August 1992

Block copolymers of polystyrene and poly(dimethyl siloxane). I. Synthesis and characterization
journal, January 1980

Large amplitude oscillatory shear behavior of PEO-PPO-PEO triblock copolymer solutions
journal, August 2005

Bound rubber and “crepe hardening” in silicone rubber
journal, December 1977

Characterization of chain binding to filler in silicone-silica systems
journal, August 1985

Elastomer reinforcement from a glassy polymer polymerized in situ
journal, October 1988

A review of nonlinear oscillatory shear tests: Analysis and application of large amplitude oscillatory shear (LAOS)
journal, December 2011

Interpenetrating polymer networks derived from silylated soybean oil and polydimethylsiloxane
journal, May 2013

Viscosity–molecular weight relationship for polydimethylsiloxane
journal, May 1966

Hierarchically Ordered Montmorillonite Block Copolymer Brushes
journal, February 2010

Block copolymer compatibilizers for polystyrene/poly(dimethylsiloxane) blends
journal, January 2002

Second‐Order Transition Temperatures and Related Properties of Polystyrene. I. Influence of Molecular Weight
journal, June 1950

Reinforcement of Silicone Rubber by Particulate Silica
journal, September 1975

Morphologies of strongly segregated polystyrene-poly(dimethylsiloxane) diblock copolymers
journal, January 1995

Polystyrene- block -Polydimethylsiloxane as a Potential Silica Substitute for Polysiloxane Reinforcement
journal, May 2020

The Influence of Fumed Silica Properties on the Processing, Curing, and Reinforcement Properties of Silicone Rubber
journal, March 1993

Role of particulate fillers in elastomer reinforcement: a review
journal, June 1979

The effect of compatibilization and rheological properties of polystyrene and poly(dimethylsiloxane) on phase structure of polystyrene/poly(dimethylsiloxane) blends: Properties of PS-PDMS Copolymer Blends
journal, January 2004

Elastomers based on α,ω-dihydroxy-polydimethylsiloxane/polystyrene blends: Morphology and mechanical properties
journal, January 2006

Comicellization of Diblock and Triblock Copolymers in Selective Solvents
journal, May 2003

Melt rheology of organoclay and fumed silica nanocomposites
journal, April 2008

Influence of Polystyrene on PDMS IPNs Blend Membrane Performance
journal, February 2012

Thermoplastic polydimethylsiloxane with l ‐phenylalanine‐based hydrogen‐bond networks
journal, June 2017

Diblock copolymers as emulsifying agents in polymer blends: Influence of molecular weight, architecture, and chemical composition
journal, July 1996

Preparation and Properties of Polydimethylsiloxane and Its Block Copolymers with Styrene
journal, September 1975

Rheology and structure of precipitated silica and poly(dimethyl siloxane) system
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High χ–Low N Block Polymers: How Far Can We Go?
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Block Copolymers of Polydimethylsiloxane and Polystyrene
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Rheology of fumed silica/polydimethylsiloxane suspensions
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Aging effects of precipitated silica in poly(dimethylsiloxane)
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Generation of glassy ellipsoidal particles within an elastomer by in situ polymerization, elongation at an elevated temperature, and finally cooling under strain
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Morphology and electrical conductivity of polyethylene/polypropylene blend filled with thermally reduced graphene oxide and surfactant exfoliated graphene
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The effect of block copolymer architecture on the coalescence and interfacial elasticity in compatibilized polymer blends
journal, May 2005

Structure & strength of silica-PDMS nanocomposites
journal, April 2010

Phase structural formation and oscillation in polystyrene-block-polydimethylsiloxane thin films
journal, January 2012

Biobased interpenetrating polymers networks derived from oligomerized soybean oil and polydimethylsiloxane
journal, December 2014

Rheological behaviors of fumed silica filled polydimethylsiloxane suspensions
journal, October 2013

Aging Phenomena in Silica-Filled Polydimethylsiloxane
journal, September 1999

Preparation, morphology, and mechanical properties of elastomers based on ?,?-dihydroxy-polydimethylsiloxane/polystyrene blends
journal, January 2004

Solvent Dependence of the Morphology of Spin-Coated Thin Films of Polydimethylsiloxane-Rich Polystyrene- block -Polydimethylsiloxane Copolymers
journal, June 2012

Miniature universal testing platform: from extensional melt rheology to solid-state deformation behavior
journal, August 2004

Compounding Fumed Silicas into Polydimethylsiloxane: Bound Rubber and Final Aggregate Size
journal, November 1997

Preparation, morphology, and mechanical properties of elastomers based on polydimethylsiloxane/ polystyrene blends
journal, April 2009

Reinforcement of elastomeric poly(dimethylsiloxane) by glassy poly(diphenylsiloxane)
journal, January 1990