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Title: Strongly Coupled Quantum Heat Machines

Abstract

Energy conversion of heat into work at the quantum level is modeled by quantum heat machines (QHMs) generally assumed to operate at weak coupling to the baths. This supposition is grounded in the separability principle between systems and allows the derivation of the evolution equation. In the weak coupling regime, the machine’s output is limited by the coupling strength, restricting their application. Seeking to overcome this limitation, we analyze QHMs in the virtually unexplored strong coupling regime here, where separability, as well as other standard thermodynamic assumptions, may no longer hold. We demonstrate that strongly coupled QHMs may be as efficient as their weakly coupled counterparts. Furthermore, we find a novel turnover behavior where their output saturates and disappears in the limit of ultrastrong coupling.

Authors:
 [1];  [1]
  1. Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1415264
Alternate Identifier(s):
OSTI ID: 1370897
Grant/Contract Number:  
SC0001088
Resource Type:
Published Article
Journal Name:
Journal of Physical Chemistry Letters
Additional Journal Information:
Journal Name: Journal of Physical Chemistry Letters Journal Volume: 6 Journal Issue: 17; Journal ID: ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Energy conversion; Open quantum systems; Polaron transformation

Citation Formats

Gelbwaser-Klimovsky, David, and Aspuru-Guzik, Alán. Strongly Coupled Quantum Heat Machines. United States: N. p., 2015. Web. doi:10.1021/acs.jpclett.5b01404.
Gelbwaser-Klimovsky, David, & Aspuru-Guzik, Alán. Strongly Coupled Quantum Heat Machines. United States. https://doi.org/10.1021/acs.jpclett.5b01404
Gelbwaser-Klimovsky, David, and Aspuru-Guzik, Alán. Mon . "Strongly Coupled Quantum Heat Machines". United States. https://doi.org/10.1021/acs.jpclett.5b01404.
@article{osti_1415264,
title = {Strongly Coupled Quantum Heat Machines},
author = {Gelbwaser-Klimovsky, David and Aspuru-Guzik, Alán},
abstractNote = {Energy conversion of heat into work at the quantum level is modeled by quantum heat machines (QHMs) generally assumed to operate at weak coupling to the baths. This supposition is grounded in the separability principle between systems and allows the derivation of the evolution equation. In the weak coupling regime, the machine’s output is limited by the coupling strength, restricting their application. Seeking to overcome this limitation, we analyze QHMs in the virtually unexplored strong coupling regime here, where separability, as well as other standard thermodynamic assumptions, may no longer hold. We demonstrate that strongly coupled QHMs may be as efficient as their weakly coupled counterparts. Furthermore, we find a novel turnover behavior where their output saturates and disappears in the limit of ultrastrong coupling.},
doi = {10.1021/acs.jpclett.5b01404},
journal = {Journal of Physical Chemistry Letters},
number = 17,
volume = 6,
place = {United States},
year = {Mon Aug 24 00:00:00 EDT 2015},
month = {Mon Aug 24 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1021/acs.jpclett.5b01404

Citation Metrics:
Cited by: 67 works
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