Strongly Coupled Quantum Heat Machines
Abstract
Energy conversion of heat into work at the quantum level is modeled by quantum heat machines (QHMs) generally assumed to operate at weak coupling to the baths. This supposition is grounded in the separability principle between systems and allows the derivation of the evolution equation. In the weak coupling regime, the machine’s output is limited by the coupling strength, restricting their application. Seeking to overcome this limitation, we analyze QHMs in the virtually unexplored strong coupling regime here, where separability, as well as other standard thermodynamic assumptions, may no longer hold. We demonstrate that strongly coupled QHMs may be as efficient as their weakly coupled counterparts. Furthermore, we find a novel turnover behavior where their output saturates and disappears in the limit of ultrastrong coupling.
- Authors:
-
- Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Excitonics (CE)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1415264
- Alternate Identifier(s):
- OSTI ID: 1370897
- Grant/Contract Number:
- SC0001088
- Resource Type:
- Published Article
- Journal Name:
- Journal of Physical Chemistry Letters
- Additional Journal Information:
- Journal Name: Journal of Physical Chemistry Letters Journal Volume: 6 Journal Issue: 17; Journal ID: ISSN 1948-7185
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Energy conversion; Open quantum systems; Polaron transformation
Citation Formats
Gelbwaser-Klimovsky, David, and Aspuru-Guzik, Alán. Strongly Coupled Quantum Heat Machines. United States: N. p., 2015.
Web. doi:10.1021/acs.jpclett.5b01404.
Gelbwaser-Klimovsky, David, & Aspuru-Guzik, Alán. Strongly Coupled Quantum Heat Machines. United States. https://doi.org/10.1021/acs.jpclett.5b01404
Gelbwaser-Klimovsky, David, and Aspuru-Guzik, Alán. Mon .
"Strongly Coupled Quantum Heat Machines". United States. https://doi.org/10.1021/acs.jpclett.5b01404.
@article{osti_1415264,
title = {Strongly Coupled Quantum Heat Machines},
author = {Gelbwaser-Klimovsky, David and Aspuru-Guzik, Alán},
abstractNote = {Energy conversion of heat into work at the quantum level is modeled by quantum heat machines (QHMs) generally assumed to operate at weak coupling to the baths. This supposition is grounded in the separability principle between systems and allows the derivation of the evolution equation. In the weak coupling regime, the machine’s output is limited by the coupling strength, restricting their application. Seeking to overcome this limitation, we analyze QHMs in the virtually unexplored strong coupling regime here, where separability, as well as other standard thermodynamic assumptions, may no longer hold. We demonstrate that strongly coupled QHMs may be as efficient as their weakly coupled counterparts. Furthermore, we find a novel turnover behavior where their output saturates and disappears in the limit of ultrastrong coupling.},
doi = {10.1021/acs.jpclett.5b01404},
journal = {Journal of Physical Chemistry Letters},
number = 17,
volume = 6,
place = {United States},
year = {Mon Aug 24 00:00:00 EDT 2015},
month = {Mon Aug 24 00:00:00 EDT 2015}
}
https://doi.org/10.1021/acs.jpclett.5b01404
Web of Science
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