Galvanostatic Intermittent Titration and Performance Based Analysis of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode
Abstract
Galvanostatic intermittent titration technique (GITT) - a popular method for characterizing kinetic and transport properties of battery electrodes - is predicated on the proper evaluation of electrode active area. LiNi0.5044Co0.1986Mn0.2970O2 (NCM523) material exhibits a complex morphology in which sub-micron primary particles aggregate to form secondary particle agglomerates. Our work proposes a new active area formulation for primary/secondary particle agglomerate materials to better mimic the morphology of NCM532 electrodes. Furthermore, this formulation is then coupled with macro-homogeneous models to simulate GITT and half-cell performance of NCM523 electrodes. Subsequently, the model results are compared against the experimental results to refine the area formulation. A single parameter, the surface roughness factor, is proposed to mimic the change in interfacial area, diffusivity and exchange current density simultaneously and detailed modeling results are presented to provide valuable insights into the efficacy of the formulation.
- Authors:
-
- Purdue Univ., West Lafayette, IN (United States). School of Mechanical Engineering
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
- OSTI Identifier:
- 1411322
- Report Number(s):
- NREL/JA-5400-70071
Journal ID: ISSN 0013-4651; TRN: US1800207
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 164; Journal Issue: 13; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 30 DIRECT ENERGY CONVERSION; galvanostatic intermittent titration technique; lithium-ion battery; nickel-cobalt-manganese
Citation Formats
Verma, Ankit, Smith, Kandler, Santhanagopalan, Shriram, Abraham, Daniel, Yao, Koffi Pierre, and Mukherjee, Partha P. Galvanostatic Intermittent Titration and Performance Based Analysis of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode. United States: N. p., 2017.
Web. doi:10.1149/2.1701713jes.
Verma, Ankit, Smith, Kandler, Santhanagopalan, Shriram, Abraham, Daniel, Yao, Koffi Pierre, & Mukherjee, Partha P. Galvanostatic Intermittent Titration and Performance Based Analysis of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode. United States. https://doi.org/10.1149/2.1701713jes
Verma, Ankit, Smith, Kandler, Santhanagopalan, Shriram, Abraham, Daniel, Yao, Koffi Pierre, and Mukherjee, Partha P. Fri .
"Galvanostatic Intermittent Titration and Performance Based Analysis of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode". United States. https://doi.org/10.1149/2.1701713jes. https://www.osti.gov/servlets/purl/1411322.
@article{osti_1411322,
title = {Galvanostatic Intermittent Titration and Performance Based Analysis of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode},
author = {Verma, Ankit and Smith, Kandler and Santhanagopalan, Shriram and Abraham, Daniel and Yao, Koffi Pierre and Mukherjee, Partha P.},
abstractNote = {Galvanostatic intermittent titration technique (GITT) - a popular method for characterizing kinetic and transport properties of battery electrodes - is predicated on the proper evaluation of electrode active area. LiNi0.5044Co0.1986Mn0.2970O2 (NCM523) material exhibits a complex morphology in which sub-micron primary particles aggregate to form secondary particle agglomerates. Our work proposes a new active area formulation for primary/secondary particle agglomerate materials to better mimic the morphology of NCM532 electrodes. Furthermore, this formulation is then coupled with macro-homogeneous models to simulate GITT and half-cell performance of NCM523 electrodes. Subsequently, the model results are compared against the experimental results to refine the area formulation. A single parameter, the surface roughness factor, is proposed to mimic the change in interfacial area, diffusivity and exchange current density simultaneously and detailed modeling results are presented to provide valuable insights into the efficacy of the formulation.},
doi = {10.1149/2.1701713jes},
journal = {Journal of the Electrochemical Society},
number = 13,
volume = 164,
place = {United States},
year = {Fri Nov 03 00:00:00 EDT 2017},
month = {Fri Nov 03 00:00:00 EDT 2017}
}
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