Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method
Abstract
Terpenes can be used as renewable fuels and chemicals and quantifying their presence in biomass is becoming increasingly important. A novel method was developed to rapidly quantify total diterpenoid resin acids using pyrolysis-molecular beam mass spectrometry (py-MBMS). Pine sapling monoterpenes and diterpenoids were extracted from wood using a 1:1 (v/v) mixture of hexane and acetone and analyses were performed before and after extraction to determine the extraction efficiency of the solvent system. The resulting extract was analyzed for total diterpenoid content using py-MBMS and was combined with total monoterpene content that was determined using a low thermal mass modular accelerated column heater (LTM MACH) fast-GC/FID to measure the terpene content present in pine saplings. Oleoresin extruded from larger pine trees was used to validate mass balance closure of the terpene content in the extract solvent.
- Authors:
-
- National Renewable Energy Lab. (NREL), Golden, CO (United States). National Bioenergy Center
- Univ. of Florida, Gainesville, FL (United States). School of Forest Resources and Conservation
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1351152
- Report Number(s):
- NREL/JA-5100-67200
Journal ID: ISSN 0165-2370
- Grant/Contract Number:
- AC36-08GO28308; AR0000209
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Analytical and Applied Pyrolysis
- Additional Journal Information:
- Journal Volume: 124; Journal Issue: C; Journal ID: ISSN 0165-2370
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 09 BIOMASS FUELS; molecular beam mass spectrometry; terpene; diterpenoid; pyrolysis; resin acids; fast GC
Citation Formats
Harman-Ware, Anne E., Davis, Mark F., Peter, Gary F., Wang, Yongsheng, and Sykes, Robert W. Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method. United States: N. p., 2017.
Web. doi:10.1016/j.jaap.2017.01.011.
Harman-Ware, Anne E., Davis, Mark F., Peter, Gary F., Wang, Yongsheng, & Sykes, Robert W. Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method. United States. https://doi.org/10.1016/j.jaap.2017.01.011
Harman-Ware, Anne E., Davis, Mark F., Peter, Gary F., Wang, Yongsheng, and Sykes, Robert W. Mon .
"Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method". United States. https://doi.org/10.1016/j.jaap.2017.01.011. https://www.osti.gov/servlets/purl/1351152.
@article{osti_1351152,
title = {Estimation of terpene content in loblolly pine biomass using a hybrid fast-GC and pyrolysis-molecular beam mass spectrometry method},
author = {Harman-Ware, Anne E. and Davis, Mark F. and Peter, Gary F. and Wang, Yongsheng and Sykes, Robert W.},
abstractNote = {Terpenes can be used as renewable fuels and chemicals and quantifying their presence in biomass is becoming increasingly important. A novel method was developed to rapidly quantify total diterpenoid resin acids using pyrolysis-molecular beam mass spectrometry (py-MBMS). Pine sapling monoterpenes and diterpenoids were extracted from wood using a 1:1 (v/v) mixture of hexane and acetone and analyses were performed before and after extraction to determine the extraction efficiency of the solvent system. The resulting extract was analyzed for total diterpenoid content using py-MBMS and was combined with total monoterpene content that was determined using a low thermal mass modular accelerated column heater (LTM MACH) fast-GC/FID to measure the terpene content present in pine saplings. Oleoresin extruded from larger pine trees was used to validate mass balance closure of the terpene content in the extract solvent.},
doi = {10.1016/j.jaap.2017.01.011},
journal = {Journal of Analytical and Applied Pyrolysis},
number = C,
volume = 124,
place = {United States},
year = {Mon Jan 16 00:00:00 EST 2017},
month = {Mon Jan 16 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 9 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Terpenoid biomaterials
journal, May 2008
- Bohlmann, Jörg; Keeling, Christopher I.
- The Plant Journal, Vol. 54, Issue 4
Methylation of wood fatty and resin acids for production of biodiesel
journal, June 2011
- Demirbas, Ayhan
- Fuel, Vol. 90, Issue 6
Catalytic Conversion of Terpenes into Fine Chemicals
journal, February 2004
- Monteiro, José Luiz F.; Veloso, Cláudia O.
- Topics in Catalysis, Vol. 27, Issue 1-4
Identification and microbial production of a terpene-based advanced biofuel
journal, September 2011
- Peralta-Yahya, Pamela P.; Ouellet, Mario; Chan, Rossana
- Nature Communications, Vol. 2, Issue 1
Pine oleoresin: tapping green chemicals, biofuels, food protection, and carbon sequestration from multipurpose trees
journal, November 2012
- Rodrigues-Corrêa, Kelly Cristine da Silva; de Lima, Júlio César; Fett-Neto, Arthur Germano
- Food and Energy Security, Vol. 1, Issue 2
Synthesis and antimicrobial activities of novel 1H-dibenzo[a,c]carbazoles from dehydroabietic acid
journal, October 2010
- Gu, Wen; Wang, Shifa
- European Journal of Medicinal Chemistry, Vol. 45, Issue 10
High-Density Renewable Fuels Based on the Selective Dimerization of Pinenes
journal, January 2010
- Harvey, Benjamin G.; Wright, Michael E.; Quintana, Roxanne L.
- Energy & Fuels, Vol. 24, Issue 1
Solvents from Pine
journal, October 1943
- Palmer, R. C.
- Industrial & Engineering Chemistry, Vol. 35, Issue 10
Diterpene resin acids in conifers
journal, November 2006
- Keeling, Christopher I.; Bohlmann, Jörg
- Phytochemistry, Vol. 67, Issue 22
Dimerization of abietic acid for the design of renewable polymers by ADMET
journal, June 2015
- Llevot, Audrey; Grau, Etienne; Carlotti, Stéphane
- European Polymer Journal, Vol. 67
Needle terpene concentrations and emissions of two coexisting subspecies of Scots pine attacked by the pine processionary moth (Thaumetopoea pityocampa)
journal, July 2013
- Achotegui-Castells, Ander; Llusià, Joan; Hódar, José A.
- Acta Physiologiae Plantarum, Vol. 35, Issue 10
Simultaneous analysis of monoterpenes and diterpenoids of conifer oleoresin
journal, September 1993
- Lewinsohn, Efraim; Savage, Thomas J.; Gijzen, Mark
- Phytochemical Analysis, Vol. 4, Issue 5
Methyl Jasmonate Induces Traumatic Resin Ducts, Terpenoid Resin Biosynthesis, and Terpenoid Accumulation in Developing Xylem of Norway Spruce Stems
journal, July 2002
- Martin, Diane; Tholl, Dorothea; Gershenzon, Jonathan
- Plant Physiology, Vol. 129, Issue 3
Determination of Terpenoid Content in Pine by Organic Solvent Extraction and Fast-GC Analysis
journal, January 2016
- Harman-Ware, Anne E.; Sykes, Robert; Peter, Gary F.
- Frontiers in Energy Research, Vol. 4
Identification of Archaeological Adhesives Using Direct Inlet Electron Ionization Mass Spectrometry
journal, March 2002
- Regert, Martine; Rolando, Christian
- Analytical Chemistry, Vol. 74, Issue 5
Determination of Terpenoids in Plant Leaves by GC-MS: Development of the Method and Application to Ocimum basilicum and Nicotiana langsdorffii
journal, February 2013
- Carro, Marina Di; Ianni, Carmela; Magi, Emanuele
- Analytical Letters, Vol. 46, Issue 4
Seasonal and geographical variation of terpenes, resin acids and total phenolics in nursery grown seedlings of Scots pine (Pinus sylvestris L.)
journal, December 1994
- Nerg, A.; Kainulainen, P.; Vuorinen, M.
- New Phytologist, Vol. 128, Issue 4
Works referencing / citing this record:
High Throughput Screening Technologies in Biomass Characterization
journal, November 2018
- Decker, Stephen R.; Harman-Ware, Anne E.; Happs, Renee M.
- Frontiers in Energy Research, Vol. 6
Lignocellulosic Biomass: Understanding Recalcitrance and Predicting Hydrolysis
journal, December 2019
- Zoghlami, Aya; Paës, Gabriel
- Frontiers in Chemistry, Vol. 7