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Title: Selective Adsorption of Sulfur Dioxide in a Robust Metal–Organic Framework Material

Abstract

Here, selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.

Authors:
 [1];  [2];  [3];  [1];  [4];  [5];  [4];  [5];  [5];  [5];  [5];  [6];  [7];  [8];  [8];  [9];  [4];  [2];  [1];  [1]
+ Show Author Affiliations
  1. School of Chemistry University of Manchester Manchester M13 9PL UK
  2. The Chemical and Engineering Materials Division (CEMD) Neutron Sciences Directorate Oak Ridge National Laboratory Oak Ridge TN 37831 USA
  3. School of Chemistry Cardiff University Cardiff CF10 3XQ UK
  4. School of Chemistry University of Nottingham University Park Nottingham NG7 2RD UK
  5. Diamond Light Source Harwell Science Campus Oxfordshire OX11 0DE UK
  6. College of Chemistry and Molecular Engineering Peking University Beijing 100871 China
  7. ISIS Neutron &, Muon Source STFC Rutherford Appleton Laboratory Chilton Oxfordshire OX11 0QX UK
  8. Hiden Isochema 422 Europa Boulevard Warrington WA5 7TS UK
  9. European Synchrotron Radiation Facility Grenoble 38043 France
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
Sponsoring Org.:
USDOE
OSTI Identifier:
1331221
Alternate Identifier(s):
OSTI ID: 1331222; OSTI ID: 1342698
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Published Article
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Name: Advanced Materials Journal Volume: 28 Journal Issue: 39; Journal ID: ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Savage, Mathew, Cheng, Yongqiang, Easun, Timothy L., Eyley, Jennifer E., Argent, Stephen P., Warren, Mark R., Lewis, William, Murray, Claire, Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Sun, Junliang, Rudić, Svemir, Murden, Richard T., Benham, Michael J., Fitch, Andrew N., Blake, Alexander J., Ramirez‐Cuesta, Anibal J., Yang, Sihai, and Schröder, Martin. Selective Adsorption of Sulfur Dioxide in a Robust Metal–Organic Framework Material. Germany: N. p., 2016. Web. doi:10.1002/adma.201602338.
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Savage, Mathew, Cheng, Yongqiang, Easun, Timothy L., Eyley, Jennifer E., Argent, Stephen P., Warren, Mark R., Lewis, William, Murray, Claire, Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Sun, Junliang, Rudić, Svemir, Murden, Richard T., Benham, Michael J., Fitch, Andrew N., Blake, Alexander J., Ramirez‐Cuesta, Anibal J., Yang, Sihai, & Schröder, Martin. Selective Adsorption of Sulfur Dioxide in a Robust Metal–Organic Framework Material. Germany. https://doi.org/10.1002/adma.201602338
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Savage, Mathew, Cheng, Yongqiang, Easun, Timothy L., Eyley, Jennifer E., Argent, Stephen P., Warren, Mark R., Lewis, William, Murray, Claire, Tang, Chiu C., Frogley, Mark D., Cinque, Gianfelice, Sun, Junliang, Rudić, Svemir, Murden, Richard T., Benham, Michael J., Fitch, Andrew N., Blake, Alexander J., Ramirez‐Cuesta, Anibal J., Yang, Sihai, and Schröder, Martin. Tue . "Selective Adsorption of Sulfur Dioxide in a Robust Metal–Organic Framework Material". Germany. https://doi.org/10.1002/adma.201602338.
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@article{osti_1331221,
title = {Selective Adsorption of Sulfur Dioxide in a Robust Metal–Organic Framework Material},
author = {Savage, Mathew and Cheng, Yongqiang and Easun, Timothy L. and Eyley, Jennifer E. and Argent, Stephen P. and Warren, Mark R. and Lewis, William and Murray, Claire and Tang, Chiu C. and Frogley, Mark D. and Cinque, Gianfelice and Sun, Junliang and Rudić, Svemir and Murden, Richard T. and Benham, Michael J. and Fitch, Andrew N. and Blake, Alexander J. and Ramirez‐Cuesta, Anibal J. and Yang, Sihai and Schröder, Martin},
abstractNote = {Here, selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.},
doi = {10.1002/adma.201602338},
journal = {Advanced Materials},
number = 39,
volume = 28,
place = {Germany},
year = {Tue Aug 16 00:00:00 EDT 2016},
month = {Tue Aug 16 00:00:00 EDT 2016}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1002/adma.201602338
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Cited by: 179 works
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Figures / Tables:

Figure 1. Figure 1.: View of a) N2, CO2, and SO2 adsorption isotherms of MFM-300(In) to a pressure of 1 bar at 298 K; b) SO2 adsorption isotherms of MFM300(In) between 298 and 348 K; c,d) isosteric heat and entropy of adsorption for N2, CO2, and SO2 in MFM-300(In); e) IAST selectivitymore » of SO2/N2 and SO2/CO2 mixtures in MFM-300(In) to a pressure of 1 bar at 298 K.« less
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