Mastering the interface for advanced all-solid-state lithium rechargeable batteries
Abstract
A solid electrolyte with a high Li-ion conductivity and a small interfacial resistance against a Li metal anode is a key component in all-solid-state Li metal batteries, but there is no ceramic oxide electrolyte available for this application except the thin-film Li-P oxynitride electrolyte; ceramic electrolytes are either easily reduced by Li metal or penetrated by Li dendrites in a short time. In this paper, we introduce a solid electrolyte LiZr2(PO4)3 with rhombohedral structure at room temperature that has a bulk Li-ion conductivity σLi = 2 × 10-4 S∙cm-1 at 25 °C, a high electrochemical stability up to 5.5 V versus Li+/Li, and a small interfacial resistance for Li+ transfer. It reacts with a metallic lithium anode to form a Li+-conducting passivation layer (solid-electrolyte interphase) containing Li3P and Li8ZrO6 that is wet by the lithium anode and also wets the LiZr2(PO4)3 electrolyte. Finally, an all-solid-state Li/LiFePO4 cell with a polymer catholyte shows good cyclability and a long cycle life.
- Authors:
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Univ. of Texas, Austin, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1331220
- Alternate Identifier(s):
- OSTI ID: 1459829
- Report Number(s):
- LA-UR-16-27072
Journal ID: ISSN 0027-8424
- Grant/Contract Number:
- SC0005397; AC52-06NA25396; CBET-1438007; DMR-1229131
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 113 Journal Issue: 47; Journal ID: ISSN 0027-8424
- Publisher:
- National Academy of Sciences, Washington, DC (United States)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; solid electrolyte; lithium anode; polymer catholyte; interfaces; NASICON
Citation Formats
Li, Yutao, Zhou, Weidong, Chen, Xi, Lü, Xujie, Cui, Zhiming, Xin, Sen, Xue, Leigang, Jia, Quanxi, and Goodenough, John B. Mastering the interface for advanced all-solid-state lithium rechargeable batteries. United States: N. p., 2016.
Web. doi:10.1073/pnas.1615912113.
Li, Yutao, Zhou, Weidong, Chen, Xi, Lü, Xujie, Cui, Zhiming, Xin, Sen, Xue, Leigang, Jia, Quanxi, & Goodenough, John B. Mastering the interface for advanced all-solid-state lithium rechargeable batteries. United States. https://doi.org/10.1073/pnas.1615912113
Li, Yutao, Zhou, Weidong, Chen, Xi, Lü, Xujie, Cui, Zhiming, Xin, Sen, Xue, Leigang, Jia, Quanxi, and Goodenough, John B. Mon .
"Mastering the interface for advanced all-solid-state lithium rechargeable batteries". United States. https://doi.org/10.1073/pnas.1615912113.
@article{osti_1331220,
title = {Mastering the interface for advanced all-solid-state lithium rechargeable batteries},
author = {Li, Yutao and Zhou, Weidong and Chen, Xi and Lü, Xujie and Cui, Zhiming and Xin, Sen and Xue, Leigang and Jia, Quanxi and Goodenough, John B.},
abstractNote = {A solid electrolyte with a high Li-ion conductivity and a small interfacial resistance against a Li metal anode is a key component in all-solid-state Li metal batteries, but there is no ceramic oxide electrolyte available for this application except the thin-film Li-P oxynitride electrolyte; ceramic electrolytes are either easily reduced by Li metal or penetrated by Li dendrites in a short time. In this paper, we introduce a solid electrolyte LiZr2(PO4)3 with rhombohedral structure at room temperature that has a bulk Li-ion conductivity σLi = 2 × 10-4 S∙cm-1 at 25 °C, a high electrochemical stability up to 5.5 V versus Li+/Li, and a small interfacial resistance for Li+ transfer. It reacts with a metallic lithium anode to form a Li+-conducting passivation layer (solid-electrolyte interphase) containing Li3P and Li8ZrO6 that is wet by the lithium anode and also wets the LiZr2(PO4)3 electrolyte. Finally, an all-solid-state Li/LiFePO4 cell with a polymer catholyte shows good cyclability and a long cycle life.},
doi = {10.1073/pnas.1615912113},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 47,
volume = 113,
place = {United States},
year = {Mon Nov 07 00:00:00 EST 2016},
month = {Mon Nov 07 00:00:00 EST 2016}
}
https://doi.org/10.1073/pnas.1615912113
Web of Science
Works referenced in this record:
Fast Li⊕ Conducting Ceramic Electrolytes
journal, February 1996
- Adachi, Gin-ya; Imanaka, Nobuhito; Aono, Hiromichi
- Advanced Materials, Vol. 8, Issue 2
Optimizing Li+ conductivity in a garnet framework
journal, January 2012
- Li, Yutao; Han, Jian- Tao; Wang, Chang- An
- Journal of Materials Chemistry, Vol. 22, Issue 30
Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries
journal, June 2016
- Li, Yutao; Zhou, Weidong; Xin, Sen
- Angewandte Chemie International Edition, Vol. 55, Issue 34
Fast Na+-ion transport in skeleton structures
journal, February 1976
- Goodenough, J. B.; Hong, H. Y-P.; Kafalas, J. A.
- Materials Research Bulletin, Vol. 11, Issue 2
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Positive Electrode Materials for Li-Ion and Li-Batteries †
journal, February 2010
- Ellis, Brian L.; Lee, Kyu Tae; Nazar, Linda F.
- Chemistry of Materials, Vol. 22, Issue 3
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
High-Temperature Lithium Mobility in α-LiZr 2 (PO 4 ) 3 NASICON by Neutron Diffraction
journal, April 2003
- Catti, M.; Comotti, A.; Di Blas, S.
- Chemistry of Materials, Vol. 15, Issue 8
Study on lithium/air secondary batteries—Stability of NASICON-type lithium ion conducting glass–ceramics with water
journal, April 2009
- Hasegawa, Satoshi; Imanishi, Nobuyuki; Zhang, Tao
- Journal of Power Sources, Vol. 189, Issue 1, p. 371-377
Garnet-type solid-state fast Li ion conductors for Li batteries: critical review
journal, January 2014
- Thangadurai, Venkataraman; Narayanan, Sumaletha; Pinzaru, Dana
- Chemical Society Reviews, Vol. 43, Issue 13
Order–Disorder and Mobility of Li+ in the β′- and β-LiZr2(PO4)3 Ionic Conductors: A Neutron Diffraction Study
journal, July 2000
- Catti, M.; Morgante, N.; Ibberson, R. M.
- Journal of Solid State Chemistry, Vol. 152, Issue 2
First-Principles Modeling of Lithium Ordering in the LLTO (Li x La 2/3 - x /3 TiO 3 ) Superionic Conductor
journal, August 2007
- Catti, Michele
- Chemistry of Materials, Vol. 19, Issue 16
Na ion- Conducting Ceramic as Solid Electrolyte for Rechargeable Seawater Batteries
journal, February 2016
- Kim, Yongil; Kim, Hyojin; Park, Sangmin
- Electrochimica Acta, Vol. 191
A study on lithium/air secondary batteries—Stability of the NASICON-type lithium ion conducting solid electrolyte in alkaline aqueous solutions
journal, June 2011
- Shimonishi, Yuta; Zhang, Tao; Imanishi, Nobuyuki
- Journal of Power Sources, Vol. 196, Issue 11
The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013
- Goodenough, John B.; Park, Kyu-Sung
- Journal of the American Chemical Society, Vol. 135, Issue 4
Li-rich anti-perovskite Li 3 OCl films with enhanced ionic conductivity
journal, January 2014
- Lü, Xujie; Wu, Gang; Howard, John W.
- Chem. Commun., Vol. 50, Issue 78
Li1.2Zr1.9Ca0.1(PO4)3, a room-temperature Li-ion solid electrolyte
journal, September 2011
- Xie, Hui; Goodenough, John B.; Li, Yutao
- Journal of Power Sources, Vol. 196, Issue 18
High Li+ conduction in NASICON-type Li1+xYxZr2−x(PO4)3 at room temperature
journal, October 2013
- Li, Yutao; Liu, Meijing; Liu, Kai
- Journal of Power Sources, Vol. 240
Fast Lithium Ion Conduction in Garnet-Type Li7La3Zr2O12
journal, October 2007
- Murugan, Ramaswamy; Thangadurai, Venkataraman; Weppner, Werner
- Angewandte Chemie International Edition, Vol. 46, Issue 41, p. 7778-7781
Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte
journal, July 2016
- Zhou, Weidong; Wang, Shaofei; Li, Yutao
- Journal of the American Chemical Society, Vol. 138, Issue 30