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Title: Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface

Abstract

We describe a high-resolution patterning approach that combines the spatial control inherent to laser direct writing with the versatility of benchtop chemical synthesis. By taking advantage of the steep thermal gradient that occurs while laser heating a metal edge in contact with solution, diverse materials comprising transition metals are patterned with feature size resolution nearing 1 μm. We demonstrate fabrication of reduced metallic nickel in one step and examine electrical properties and air stability through direct-write integration onto a device platform. In conclusion, this strategy expands the chemistries and materials that can be used in combination with laser direct writing.

Authors:
 [1];  [2];  [3];  [3];  [4]
  1. The Pennsylvania State Univ., University Park, PA (United States)
  2. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
  3. Univ. of Virginia, Charlottesville, VA (United States)
  4. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); The Univ. of New Mexico, Albuquerque, NM (United States)
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1330208
Report Number(s):
SAND-2016-10660J
Journal ID: ISSN 1944-8244; 648515
Grant/Contract Number:  
AC04-94AL85000
Resource Type:
Accepted Manuscript
Journal Name:
ACS Applied Materials and Interfaces
Additional Journal Information:
Journal Volume: 8; Journal Issue: 33; Journal ID: ISSN 1944-8244
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; laser direct write; laser-induced heating; metals; microstructures; Ni electrode; solvothermal synthesis

Citation Formats

Zarzar, Lauren D., Swartzentruber, B. S., Donovan, Brian F., Hopkins, Patrick E., and Kaehr, Bryan. Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface. United States: N. p., 2016. Web. doi:10.1021/acsami.6b06625.
Zarzar, Lauren D., Swartzentruber, B. S., Donovan, Brian F., Hopkins, Patrick E., & Kaehr, Bryan. Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface. United States. https://doi.org/10.1021/acsami.6b06625
Zarzar, Lauren D., Swartzentruber, B. S., Donovan, Brian F., Hopkins, Patrick E., and Kaehr, Bryan. Fri . "Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface". United States. https://doi.org/10.1021/acsami.6b06625. https://www.osti.gov/servlets/purl/1330208.
@article{osti_1330208,
title = {Using laser-induced thermal voxels to pattern diverse materials at the solid–liquid interface},
author = {Zarzar, Lauren D. and Swartzentruber, B. S. and Donovan, Brian F. and Hopkins, Patrick E. and Kaehr, Bryan},
abstractNote = {We describe a high-resolution patterning approach that combines the spatial control inherent to laser direct writing with the versatility of benchtop chemical synthesis. By taking advantage of the steep thermal gradient that occurs while laser heating a metal edge in contact with solution, diverse materials comprising transition metals are patterned with feature size resolution nearing 1 μm. We demonstrate fabrication of reduced metallic nickel in one step and examine electrical properties and air stability through direct-write integration onto a device platform. In conclusion, this strategy expands the chemistries and materials that can be used in combination with laser direct writing.},
doi = {10.1021/acsami.6b06625},
journal = {ACS Applied Materials and Interfaces},
number = 33,
volume = 8,
place = {United States},
year = {Fri Aug 05 00:00:00 EDT 2016},
month = {Fri Aug 05 00:00:00 EDT 2016}
}

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Free Publicly Available Full Text
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Cited by: 18 works
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Works referencing / citing this record:

Simultaneous laser-induced synthesis and micro-patterning of a metal organic framework
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Substrate thermal conductivity controls the ability to manufacture microstructures via laser-induced direct write
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Nanostructure and Mechanism of Metal Deposition by a Laser‐Induced Photothermal Reaction
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The laser writing of highly conductive and anti-oxidative copper structures in liquid
journal, January 2020