A graphite oxide (GO)-based remote readable tamper evident seal
Abstract
Here, this paper presents a prototype of a remotely readable graphite oxide (GO) paper-based tamper evident seal. The proposed device combines the tunable electrical properties offered by reduced graphite oxide (RGO) with a compressive sampling scheme. The benefit of using RGO as a tamper evident seal material is the sensitivity of its electrical properties to the common mechanisms adopted to defeat tamper-evident seals. RGO’s electrical properties vary upon local stress or cracks induced by mechanical action (e.g., produced by shimming or lifting attacks). Further, modification of the seal’s electrical properties can result from the incidence of other defeat mechanisms, such as temperature changes, solvent treatment and steam application. The electrical tunability of RGO enables the engraving of a circuit on the area of the tamper evident seal intended to be exposed to malicious attacks. The operation of the tamper evident seal, as well as its remote communication functionality, is supervised by a microcontroller unit (MCU). The MCU uses the RGO-engraved circuitry to physically implement a compressive sampling acquisition procedure. The compressive sampling scheme provides the seal with self-authentication and self-state-of-health awareness capabilities. Finally, the prototype shows potential for use in low-power, embedded, remote-operation nonproliferation security related applications.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Engineering Inst.
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies
- Prairie View A&M Univ., Prairie View, TX (United States). Thermal Science Research Center
- Univ. of New Mexico, Albuquerque, NM (United States). Mechanical Engineering Dept.
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Safeguards Science and Technology
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE; US Dept. of State
- OSTI Identifier:
- 1329859
- Report Number(s):
- LA-UR-15-20701
Journal ID: ISSN 0964-1726
- Grant/Contract Number:
- AC52-06NA25396; 20130527ER
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Smart Materials and Structures
- Additional Journal Information:
- Journal Volume: 24; Journal Issue: 10; Journal ID: ISSN 0964-1726
- Publisher:
- IOP Publishing
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; 36 MATERIALS SCIENCE
Citation Formats
Cattaneo, Alessandro, Bossert, Jason Andrew, Guzman, Christian, Haaker, Axel, Gupta, Gautam, Mohite, Aditya, Dumont, Joseph Henry, Purdy, Geraldine Maxine, Miller, Karen Ann, Marchi, Alexandria Nicole, Farrar, Charles Reed, and Mascarenas, David Dennis L. A graphite oxide (GO)-based remote readable tamper evident seal. United States: N. p., 2016.
Web. doi:10.1088/0964-1726/24/10/105014.
Cattaneo, Alessandro, Bossert, Jason Andrew, Guzman, Christian, Haaker, Axel, Gupta, Gautam, Mohite, Aditya, Dumont, Joseph Henry, Purdy, Geraldine Maxine, Miller, Karen Ann, Marchi, Alexandria Nicole, Farrar, Charles Reed, & Mascarenas, David Dennis L. A graphite oxide (GO)-based remote readable tamper evident seal. United States. https://doi.org/10.1088/0964-1726/24/10/105014
Cattaneo, Alessandro, Bossert, Jason Andrew, Guzman, Christian, Haaker, Axel, Gupta, Gautam, Mohite, Aditya, Dumont, Joseph Henry, Purdy, Geraldine Maxine, Miller, Karen Ann, Marchi, Alexandria Nicole, Farrar, Charles Reed, and Mascarenas, David Dennis L. Thu .
"A graphite oxide (GO)-based remote readable tamper evident seal". United States. https://doi.org/10.1088/0964-1726/24/10/105014. https://www.osti.gov/servlets/purl/1329859.
@article{osti_1329859,
title = {A graphite oxide (GO)-based remote readable tamper evident seal},
author = {Cattaneo, Alessandro and Bossert, Jason Andrew and Guzman, Christian and Haaker, Axel and Gupta, Gautam and Mohite, Aditya and Dumont, Joseph Henry and Purdy, Geraldine Maxine and Miller, Karen Ann and Marchi, Alexandria Nicole and Farrar, Charles Reed and Mascarenas, David Dennis L.},
abstractNote = {Here, this paper presents a prototype of a remotely readable graphite oxide (GO) paper-based tamper evident seal. The proposed device combines the tunable electrical properties offered by reduced graphite oxide (RGO) with a compressive sampling scheme. The benefit of using RGO as a tamper evident seal material is the sensitivity of its electrical properties to the common mechanisms adopted to defeat tamper-evident seals. RGO’s electrical properties vary upon local stress or cracks induced by mechanical action (e.g., produced by shimming or lifting attacks). Further, modification of the seal’s electrical properties can result from the incidence of other defeat mechanisms, such as temperature changes, solvent treatment and steam application. The electrical tunability of RGO enables the engraving of a circuit on the area of the tamper evident seal intended to be exposed to malicious attacks. The operation of the tamper evident seal, as well as its remote communication functionality, is supervised by a microcontroller unit (MCU). The MCU uses the RGO-engraved circuitry to physically implement a compressive sampling acquisition procedure. The compressive sampling scheme provides the seal with self-authentication and self-state-of-health awareness capabilities. Finally, the prototype shows potential for use in low-power, embedded, remote-operation nonproliferation security related applications.},
doi = {10.1088/0964-1726/24/10/105014},
journal = {Smart Materials and Structures},
number = 10,
volume = 24,
place = {United States},
year = {Thu Sep 08 00:00:00 EDT 2016},
month = {Thu Sep 08 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 4 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Tamper detection for safeguards and treaty monitoring: Fantasies, realities, and potentials
journal, March 2001
- Johnston, Roger G.
- The Nonproliferation Review, Vol. 8, Issue 1
An Introduction To Compressive Sampling
journal, March 2008
- Candes, E. J.; Wakin, M. B.
- IEEE Signal Processing Magazine, Vol. 25, Issue 2
The secrecy of compressed sensing measurements
conference, September 2008
- Rachlin, Yaron; Baron, Dror
- 2008 46th Annual Allerton Conference on Communication, Control, and Computing
On the security and robustness of encryption via compressed sensing
conference, November 2008
- Orsdemir, Adem; Altun, H. Oktay; Sharma, Gaurav
- MILCOM 2008 - 2008 IEEE Military Communications Conference (MILCOM)
Compressed sensing with coherent and redundant dictionaries
journal, July 2011
- Candès, Emmanuel J.; Eldar, Yonina C.; Needell, Deanna
- Applied and Computational Harmonic Analysis, Vol. 31, Issue 1
The rise of graphene
journal, March 2007
- Geim, A. K.; Novoselov, K. S.
- Nature Materials, Vol. 6, Issue 3, p. 183-191
Direct laser writing of micro-supercapacitors on hydrated graphite oxide films
journal, July 2011
- Gao, Wei; Singh, Neelam; Song, Li
- Nature Nanotechnology, Vol. 6, Issue 8
Improved Synthesis of Graphene Oxide
journal, July 2010
- Marcano, Daniela C.; Kosynkin, Dmitry V.; Berlin, Jacob M.
- ACS Nano, Vol. 4, Issue 8, p. 4806-4814
Compressed sensing
journal, April 2006
- Donoho, D. L.
- IEEE Transactions on Information Theory, Vol. 52, Issue 4
Optimized Projections for Compressed Sensing
journal, December 2007
- Elad, M.
- IEEE Transactions on Signal Processing, Vol. 55, Issue 12
Atomic Decomposition by Basis Pursuit
journal, January 1998
- Chen, Scott Shaobing; Donoho, David L.; Saunders, Michael A.
- SIAM Journal on Scientific Computing, Vol. 20, Issue 1, p. 33-61
Dictionaries for Sparse Representation Modeling
journal, June 2010
- Rubinstein, Ron; Bruckstein, Alfred M.; Elad, Michael
- Proceedings of the IEEE, Vol. 98, Issue 6
Alternating Direction Algorithms for $\ell_1$-Problems in Compressive Sensing
journal, January 2011
- Yang, Junfeng; Zhang, Yin
- SIAM Journal on Scientific Computing, Vol. 33, Issue 1
Public-key-based optical image cryptosystem based on data embedding techniques
journal, January 2003
- Lin, Guo-Shiang; Chang, Hsuan T.; Lie, Wen-Nung
- Optical Engineering, Vol. 42, Issue 8
Ensuring Security to the Compressed Sensing Data Using a Steganographic Approach
journal, March 2013
- A. V., Sreedhanya
- Bonfring International Journal of Advances in Image Processing, Vol. 3, Issue 1
Graphene Oxide, Highly Reduced Graphene Oxide, and Graphene: Versatile Building Blocks for Carbon-Based Materials
journal, March 2010
- Compton, Owen C.; Nguyen, SonBinh T.
- Small, Vol. 6, Issue 6, p. 711-723
Preparation and characterization of graphene oxide paper
journal, July 2007
- Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J.
- Nature, Vol. 448, Issue 7152, p. 457-460
Flexible, Transparent, Conducting Films of Randomly Stacked Graphene from Surfactant‐Stabilized, Oxide‐Free Graphene Dispersions
journal, January 2010
- De, Sukanta; King, Paul J.; Lotya, Mustafa
- Small, Vol. 6, Issue 3
Harnessing the chemistry of graphene oxide
journal, January 2014
- Dreyer, Daniel R.; Todd, Alexander D.; Bielawski, Christopher W.
- Chemical Society Reviews, Vol. 43, Issue 15
Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004
- Novoselov, K. S.
- Science, Vol. 306, Issue 5696, p. 666-669
Experimental observation of the quantum Hall effect and Berry's phase in graphene
journal, November 2005
- Zhang, Yuanbo; Tan, Yan-Wen; Stormer, Horst L.
- Nature, Vol. 438, Issue 7065, p. 201-204
Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
journal, July 2008
- Lee, C.; Wei, X.; Kysar, J. W.
- Science, Vol. 321, Issue 5887, p. 385-388
Graphene gets ready for the big time
journal, March 2009
- Brumfiel, Geoff
- Nature, Vol. 458, Issue 7237
Tunable Electrical Conductivity of Individual Graphene Oxide Sheets Reduced at “Low” Temperatures
journal, December 2008
- Jung, Inhwa; Dikin, Dmitriy A.; Piner, Richard D.
- Nano Letters, Vol. 8, Issue 12, p. 4283-4287
Photothermal Deoxygenation of Graphite Oxide with Laser Excitation in Solution and Graphene-Aided Increase in Water Temperature
journal, September 2010
- Abdelsayed, Victor; Moussa, Sherif; Hassan, Hassan M.
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 19
Pulsed laser assisted reduction of graphene oxide
journal, June 2011
- Huang, Lei; Liu, Yang; Ji, Le-Chun
- Carbon, Vol. 49, Issue 7
Formation of Graphene Features from Direct Laser-Induced Reduction of Graphite Oxide
journal, August 2010
- Sokolov, Denis A.; Shepperd, Kristin R.; Orlando, Thomas M.
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 18
Direct imprinting of microcircuits on graphene oxides film by femtosecond laser reduction
journal, February 2010
- Zhang, Yonglai; Guo, Li; Wei, Shu
- Nano Today, Vol. 5, Issue 1
Microstructuring of Graphene Oxide Nanosheets Using Direct Laser Writing
journal, January 2010
- Zhou, Yong; Bao, Qiaoliang; Varghese, Binni
- Advanced Materials, Vol. 22, Issue 1
Epitaxial-Graphene/Graphene-Oxide Junction: An Essential Step towards Epitaxial Graphene Electronics
journal, July 2008
- Wu, Xiaosong; Sprinkle, Mike; Li, Xuebin
- Physical Review Letters, Vol. 101, Issue 2
Evolution of Electrical, Chemical, and Structural Properties of Transparent and Conducting Chemically Derived Graphene Thin Films
journal, August 2009
- Mattevi, Cecilia; Eda, Goki; Agnoli, Stefano
- Advanced Functional Materials, Vol. 19, Issue 16
Nanoscale Tunable Reduction of Graphene Oxide for Graphene Electronics
journal, June 2010
- Wei, Z.; Wang, D.; Kim, S.
- Science, Vol. 328, Issue 5984
Graphenes prepared by Staudenmaier, Hofmann and Hummers methods with consequent thermal exfoliation exhibit very different electrochemical properties
journal, January 2012
- Poh, Hwee Ling; Šaněk, Filip; Ambrosi, Adriano
- Nanoscale, Vol. 4, Issue 11
Toeplitz Compressed Sensing Matrices With Applications to Sparse Channel Estimation
journal, November 2010
- Haupt, Jarvis; Bajwa, Waheed U.; Raz, Gil
- IEEE Transactions on Information Theory, Vol. 56, Issue 11
Restricted isometries for partial random circulant matrices
journal, March 2012
- Rauhut, Holger; Romberg, Justin; Tropp, Joel A.
- Applied and Computational Harmonic Analysis, Vol. 32, Issue 2
Deterministic Construction of Compressed Sensing Matrices via Algebraic Curves
journal, August 2012
- Li, Shuxing; Gao, Fei; Ge, Gennian
- IEEE Transactions on Information Theory, Vol. 58, Issue 8
Deterministic constructions of compressed sensing matrices
journal, August 2007
- DeVore, Ronald A.
- Journal of Complexity, Vol. 23, Issue 4-6
Structured Compressed Sensing: From Theory to Applications
journal, September 2011
- Duarte, Marco F.; Eldar, Yonina C.
- IEEE Transactions on Signal Processing, Vol. 59, Issue 9
BCS: Compressive sensing for binary sparse signals
conference, October 2012
- Nakarmi, Ukash; Rahnavard, Nazanin
- MILCOM 2012 - 2012 IEEE Military Communications Conference
1-Bit compressive sensing
conference, March 2008
- Boufounos, Petros T.; Baraniuk, Richard G.
- 2008 42nd Annual Conference on Information Sciences and Systems (CISS)
Robust 1-Bit Compressive Sensing via Binary Stable Embeddings of Sparse Vectors
journal, April 2013
- Jacques, Laurent; Laska, Jason N.; Boufounos, Petros T.
- IEEE Transactions on Information Theory, Vol. 59, Issue 4