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This content will become publicly available on October 12, 2017

Title: Electron Beam Curing of Composite Positive Electrode for Li-Ion Battery

We have successfully used electron beam cured acrylated polyurethanes as novel binders for positive electrodes for Li-ion batteries. Furthermore, the cross-linked polymer after electron beam curing coheres active materials and carbon black together onto Al foil. Electrochemical tests demonstrate the stability of the polymer at a potential window of 2.0 V–4.6 V. The electrode is found to have similar voltage profiles and charge-transfer resistance compared to the conventional electrode using polyvinylidene fluoride as the binder. Finally, when the electrode is tested in full Li-ion cells, they exhibit excellent cycling performance, indicating promising use for this new type of binder in commercial Li-ion batteries in the future.
Authors:
 [1] ;  [2] ;  [1] ;  [1] ;  [3] ;  [1] ;  [3]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Energy and Transportation Science Division
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  3. (United States). Bredesen Center for Interdisciplinary Research and Graduate Education
Publication Date:
OSTI Identifier:
1329741
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
Journal of the Electrochemical Society
Additional Journal Information:
Journal Volume: 163; Journal Issue: 13; Journal ID: ISSN 0013-4651
Publisher:
The Electrochemical Society
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE