Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments

Rodriguez, José A.; Liu, Ping; Graciani, Jesús; Senanayake, Sanjaya D.; Grinter, David C.; Stacchiola, Dario; Hrbek, Jan; Fernández-Sanz, Javier

doi:10.1021/acs.jpclett.6b00499

Title: Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments

Abstract

Inverse oxide/metal catalysts have shown to be excellent systems for studying the role of the oxide and oxide–metal interface in catalytic reactions. These systems can have special structural and catalytic properties due to strong oxide–metal interactions difficult to attain when depositing a metal on a regular oxide support. Oxide phases that are not seen or are metastable in a bulk oxide can become stable in an oxide/metal system opening the possibility for new chemical properties. Using these systems, it has been possible to explore fundamental properties of the metal–oxide interface (composition, structure, electronic state), which determine catalytic performance in the oxidation of CO, the water–gas shift and the hydrogenation of CO₂ to methanol. Recently, there has been a significant advance in the preparation of oxide/metal catalysts for technical or industrial applications. In conclusion, one goal is to identify methods able to control in a precise way the size of the deposited oxide particles and their structure on the metal substrate.

Authors:

Rodriguez, José A. ^[1]; Liu, Ping ^[1]; Graciani, Jesús ^[2]; Senanayake, Sanjaya D. ^[3]; Grinter, David C. ^[3]; Stacchiola, Dario ^[3]; Hrbek, Jan ^[3]; Fernández-Sanz, Javier ^[2]

Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York (SUNY), Stony Brook, NY (United States)
Univ. de Sevilla, Sevilla (Spain)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Publication Date:: Tue Jun 21 00:00:00 EDT 2016

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1326742

Report Number(s):: BNL-112633-2016-JA
Journal ID: ISSN 1948-7185; R&D Project: CO027; KC0302010

Grant/Contract Number:: SC00112704

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physical Chemistry Letters

Additional Journal Information:: Journal Volume: 7; Journal Issue: 13; Journal ID: ISSN 1948-7185

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Rodriguez, José A., Liu, Ping, Graciani, Jesús, Senanayake, Sanjaya D., Grinter, David C., Stacchiola, Dario, Hrbek, Jan, and Fernández-Sanz, Javier. Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.jpclett.6b00499.

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                    Rodriguez, José A., Liu, Ping, Graciani, Jesús, Senanayake, Sanjaya D., Grinter, David C., Stacchiola, Dario, Hrbek, Jan, & Fernández-Sanz, Javier. Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments.  United States.  https://doi.org/10.1021/acs.jpclett.6b00499

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                    Rodriguez, José A., Liu, Ping, Graciani, Jesús, Senanayake, Sanjaya D., Grinter, David C., Stacchiola, Dario, Hrbek, Jan, and Fernández-Sanz, Javier. Tue .  
"Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments".  United States.  https://doi.org/10.1021/acs.jpclett.6b00499.  https://www.osti.gov/servlets/purl/1326742.

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@article{osti_1326742,

  title        = {Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments},

  author       = {Rodriguez, José A. and Liu, Ping and Graciani, Jesús and Senanayake, Sanjaya D. and Grinter, David C. and Stacchiola, Dario and Hrbek, Jan and Fernández-Sanz, Javier},

  abstractNote = {Inverse oxide/metal catalysts have shown to be excellent systems for studying the role of the oxide and oxide–metal interface in catalytic reactions. These systems can have special structural and catalytic properties due to strong oxide–metal interactions difficult to attain when depositing a metal on a regular oxide support. Oxide phases that are not seen or are metastable in a bulk oxide can become stable in an oxide/metal system opening the possibility for new chemical properties. Using these systems, it has been possible to explore fundamental properties of the metal–oxide interface (composition, structure, electronic state), which determine catalytic performance in the oxidation of CO, the water–gas shift and the hydrogenation of CO2 to methanol. Recently, there has been a significant advance in the preparation of oxide/metal catalysts for technical or industrial applications. In conclusion, one goal is to identify methods able to control in a precise way the size of the deposited oxide particles and their structure on the metal substrate.},

  doi          = {10.1021/acs.jpclett.6b00499},

  journal      = {Journal of Physical Chemistry Letters},

  number       = 13,

  volume       = 7,

  place        = {United States},

  year         = {Tue Jun 21 00:00:00 EDT 2016},

  month        = {Tue Jun 21 00:00:00 EDT 2016}

}

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1D tungsten oxide nanostructures on a Cu(1 1 0) surface
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Construction of stabilized bulk-nano interfaces for highly promoted inverse CeO2/Cu catalyst
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DOI: 10.1038/s41467-019-11407-2

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Title: Inverse oxide/metal catalysts in fundamental studies and practical applications: A perspective of recent developments

Abstract

Citation Formats

Low-temperature synthesis of Mn-based mixed metal oxides with novel fluffy structures as efficient catalysts for selective reduction of nitrogen oxides by ammonia journal, January 2014

Tailoring metal–oxide interfaces of inverse catalysts of TiO 2 /nanoporous-Au under hydrogen oxidation journal, January 2015

Precisely Applying TiO 2 Overcoat on Supported Au Catalysts Using Atomic Layer Deposition for Understanding the Reaction Mechanism and Improved Activity in CO Oxidation journal, December 2015

Nanostructured Oxides in Chemistry: Characterization and Properties journal, September 2004

Effect of titania on the chemisorption and reaction properties of platinum journal, March 1985

Structure of an ultrathin TiOx film, formed by the strong metal support interaction (SMSI), on Pt nanocrystals on TiO2(110) journal, October 2001

CO oxidation over ZnO films on Pt(111) at near-atmospheric pressures journal, May 2013

Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction journal, December 2007

CO Oxidation on a CeO x /Pt(111) Inverse Model Catalyst Surface: Catalytic Promotion and Tuning of Kinetic Phase Diagrams journal, November 2008

CO oxidation on inverse Fe2O3/Au(111) model catalysts journal, October 2012

Active Sites for Hydrogen Dissociation over TiO x /Au(111) Surfaces journal, July 2011

Adsorption and reaction of CO on a ceria–Rh(111) “inverse model catalyst” surface journal, June 2003

Inverse CeO 2 /CuO Catalyst As an Alternative to Classical Direct Configurations for Preferential Oxidation of CO in Hydrogen-Rich Stream journal, January 2010

Noble Metal Core−Ceria Shell Catalysts For Water−Gas Shift Reaction journal, March 2009

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions journal, February 2015

Promoting Strong Metal Support Interaction: Doping ZnO for Enhanced Activity of Cu/ZnO:M (M = Al, Ga, Mg) Catalysts journal, April 2015

In situ time-resolved characterization of novel Cu–MoO2 catalysts during the water–gas shift reaction journal, January 2007

Reversibility of strong metal-support interactions on Rh/TiO2 journal, July 1989

Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles journal, March 2011

Influence of the CeO 2 Support on the Reduction Properties of Cu/CeO 2 and Ni/CeO 2 Nanoparticles journal, November 2015

Strong metal-support interactions journal, November 1987

Electron Transfer at Oxide Surfaces. The MgO Paradigm: from Defects to Ultrathin Films journal, November 2012

Oxidation of a Zn-deposited Cu() surface studied by XPS and STM journal, August 2002

Inverse oxide/metal catalysts: A versatile approach for activity tests and mechanistic studies journal, February 2010

Nature of Interface Confinement Effect in Oxide/Metal Catalysts journal, November 2015

CO Oxidation on Gold-Supported Iron Oxides: New Insights into Strong Oxide–Metal Interactions journal, July 2015

A Surface Science Investigation of Methanol Synthesis over a Zn-Deposited Polycrystalline Cu Surface journal, April 1996

Hydrogenation of CO 2 to Methanol on CeO x /Cu(111) and ZnO/Cu(111) Catalysts: Role of the Metal–Oxide Interface and Importance of Ce 3+ Sites journal, January 2016

Growth, Structure, and Stability of the High-Index TbO x (112) Surface on Cu(111) journal, June 2015

Selective Growth of Fe 2 O 3 Nanoparticles and Islands on Au(111) journal, May 2009

Nucleation and growth of Fe and FeO nanoparticles and films on Au(111) journal, February 2008

Density functional study of water-gas shift reaction on M3O3x/Cu(111) journal, January 2012

Unraveling the Nature of the Oxide–Metal Interaction in Ceria-Based Noble Metal Inverse Catalysts journal, November 2014

Monolayer iron oxide film on platinum promotes low temperature CO oxidation journal, September 2009

Catalytic Properties of Ceria and CeO 2 -Containing Materials journal, November 1996

Strain-induced formation of arrays of catalytically active sites at the metal–oxide interface journal, April 2004

Spectromicroscopy of a Model Water–Gas Shift Catalyst: Gold Nanoparticles Supported on Ceria journal, August 2014

Morphology and defect structure of the CeO2(111) films grown on Ru(0001) as studied by scanning tunneling microscopy journal, November 2006

Growth and Morphology of Ceria on Ruthenium (0001) journal, December 2012

Ordered cerium oxide thin films grown on Ru(0001) and Ni(111) journal, June 1999

The growth, structure and stability of ceria overlayers on Pd(111) journal, December 1994

Cerium oxides and cerium-platinum surface alloys on Pt(111) single-crystal surfaces studied by scanning tunneling microscopy journal, May 2002

Ultrathin ordered CeO2 overlayers on Pt(111): interaction with NO2, NO, H2O and CO journal, November 2000

Defect Structure of Ultrathin Ceria Films on Pt(111): Atomic Views from Scanning Tunnelling Microscopy journal, June 2010

Photoemission Spectroscopy Study of Cu/CeO 2 Systems: Cu/CeO 2 Nanosized Catalyst and CeO 2 (111)/Cu(111) Inverse Model Catalyst journal, March 2008

CO Oxidation on Inverse CeO x /Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O 2 journal, March 2011

Nanopattering in CeO x /Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity journal, March 2012

Oxidation State Imaging of Ceria Island Growth on Re(0001) journal, August 2013

Reaction of water with Ce–Au(111) and CeOx/Au(111) surfaces: Photoemission and STM studies journal, June 2007

Growth of Ceria Nano-Islands on a Stepped Au(788) Surface journal, August 2015

Approaching nanoscale oxides: models and theoretical methods journal, January 2009

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Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2 journal, July 2014

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy journal, April 2013

Kinetics and mechanism of the water-gas shift reaction catalysed by the clean and Cs-promoted Cu(110) surface: a comparison with Cu(111) journal, January 1990

A surface science investigation of the water-gas shift reaction on Cu(111) journal, March 1987

On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper journal, January 2008

Unraveling the Active Site in Copper−Ceria Systems for the Water−Gas Shift Reaction: In Situ Characterization of an Inverse Powder CeO 2− x /CuO−Cu Catalyst journal, February 2010

Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄) journal, January 2010

Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties journal, January 1997

Surface studies of supported model catalysts journal, January 1998

Formation of TiO 2 Nanoparticles by Reactive-Layer-Assisted Deposition and Characterization by XPS and STM journal, July 2005

Surface Structures of Ultrathin TiO x Films on Au(111) journal, April 2011

Preparation of TiO 2 Nanocrystallites by Oxidation of Ti−Au(111) Surface Alloy journal, June 2009

Mechanism and Active Sites of the Oxidation of CO over Au/TiO2 journal, September 2011

Activating Nonreducible Oxides via Doping journal, April 2015

A Case of Strong Metal-Support Interactions: Combining Advanced Microscopy and Model Systems to Elucidate the Atomic Structure of Interfaces journal, May 2014

First principles studies of complex oxide surfaces and interfaces journal, June 2004

Preparation and Structural Characterization of RuS 2 Nanoislands on Au(111) journal, July 2004

In Situ Detection of Active Edge Sites in Single-Layer MoS 2 Catalysts journal, July 2015

CO2 Hydrogenation over Carbide Catalysts. journal, January 1992

Surface Chemistry of Transition Metal Carbides journal, January 2005

Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts journal, July 2007

Atomic-scale insight into structure and morphology changes of MoS2 nanoclusters in hydrotreating catalysts journal, January 2004

Thermal reduction of ceria nanostructures on rhodium(111) and re-oxidation by CO 2 journal, January 2018

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CO oxidation activity of Pt, Zn and ZnPt nanocatalysts: a comparative study by in situ near-ambient pressure X-ray photoelectron spectroscopy journal, January 2018

Low-temperature synthesis of Mn-based mixed metal oxides with novel fluffy structures as efficient catalysts for selective reduction of nitrogen oxides by ammonia
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Precisely Applying TiO ₂ Overcoat on Supported Au Catalysts Using Atomic Layer Deposition for Understanding the Reaction Mechanism and Improved Activity in CO Oxidation
journal, December 2015

Nanostructured Oxides in Chemistry: Characterization and Properties
journal, September 2004

Effect of titania on the chemisorption and reaction properties of platinum
journal, March 1985

Structure of an ultrathin TiOx film, formed by the strong metal support interaction (SMSI), on Pt nanocrystals on TiO2(110)
journal, October 2001

CO oxidation over ZnO films on Pt(111) at near-atmospheric pressures
journal, May 2013

Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction
journal, December 2007

CO Oxidation on a CeO _x /Pt(111) Inverse Model Catalyst Surface: Catalytic Promotion and Tuning of Kinetic Phase Diagrams
journal, November 2008

CO oxidation on inverse Fe2O3/Au(111) model catalysts
journal, October 2012

Active Sites for Hydrogen Dissociation over TiO _x /Au(111) Surfaces
journal, July 2011

Adsorption and reaction of CO on a ceria–Rh(111) “inverse model catalyst” surface
journal, June 2003

Inverse CeO ₂ /CuO Catalyst As an Alternative to Classical Direct Configurations for Preferential Oxidation of CO in Hydrogen-Rich Stream
journal, January 2010

Noble Metal Core−Ceria Shell Catalysts For Water−Gas Shift Reaction
journal, March 2009

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al ₂ O ₃ Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015

Promoting Strong Metal Support Interaction: Doping ZnO for Enhanced Activity of Cu/ZnO:M (M = Al, Ga, Mg) Catalysts
journal, April 2015

In situ time-resolved characterization of novel Cu–MoO2 catalysts during the water–gas shift reaction
journal, January 2007

Reversibility of strong metal-support interactions on Rh/TiO2
journal, July 1989

Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles
journal, March 2011

Influence of the CeO ₂ Support on the Reduction Properties of Cu/CeO ₂ and Ni/CeO ₂ Nanoparticles
journal, November 2015

Strong metal-support interactions
journal, November 1987

Electron Transfer at Oxide Surfaces. The MgO Paradigm: from Defects to Ultrathin Films
journal, November 2012

Oxidation of a Zn-deposited Cu() surface studied by XPS and STM
journal, August 2002

Inverse oxide/metal catalysts: A versatile approach for activity tests and mechanistic studies
journal, February 2010

Nature of Interface Confinement Effect in Oxide/Metal Catalysts
journal, November 2015

CO Oxidation on Gold-Supported Iron Oxides: New Insights into Strong Oxide–Metal Interactions
journal, July 2015

A Surface Science Investigation of Methanol Synthesis over a Zn-Deposited Polycrystalline Cu Surface
journal, April 1996

Hydrogenation of CO ₂ to Methanol on CeO _x /Cu(111) and ZnO/Cu(111) Catalysts: Role of the Metal–Oxide Interface and Importance of Ce ³⁺ Sites
journal, January 2016

Growth, Structure, and Stability of the High-Index TbO _x (112) Surface on Cu(111)
journal, June 2015

Selective Growth of Fe ₂ O ₃ Nanoparticles and Islands on Au(111)
journal, May 2009

Nucleation and growth of Fe and FeO nanoparticles and films on Au(111)
journal, February 2008

Density functional study of water-gas shift reaction on M3O3x/Cu(111)
journal, January 2012

Unraveling the Nature of the Oxide–Metal Interaction in Ceria-Based Noble Metal Inverse Catalysts
journal, November 2014

Monolayer iron oxide film on platinum promotes low temperature CO oxidation
journal, September 2009

Catalytic Properties of Ceria and CeO ₂ -Containing Materials
journal, November 1996

Strain-induced formation of arrays of catalytically active sites at the metal–oxide interface
journal, April 2004

Spectromicroscopy of a Model Water–Gas Shift Catalyst: Gold Nanoparticles Supported on Ceria
journal, August 2014

Morphology and defect structure of the CeO2(111) films grown on Ru(0001) as studied by scanning tunneling microscopy
journal, November 2006

Growth and Morphology of Ceria on Ruthenium (0001)
journal, December 2012

Ordered cerium oxide thin films grown on Ru(0001) and Ni(111)
journal, June 1999

The growth, structure and stability of ceria overlayers on Pd(111)
journal, December 1994

Cerium oxides and cerium-platinum surface alloys on Pt(111) single-crystal surfaces studied by scanning tunneling microscopy
journal, May 2002

Ultrathin ordered CeO2 overlayers on Pt(111): interaction with NO2, NO, H2O and CO
journal, November 2000

Defect Structure of Ultrathin Ceria Films on Pt(111): Atomic Views from Scanning Tunnelling Microscopy
journal, June 2010

Photoemission Spectroscopy Study of Cu/CeO ₂ Systems: Cu/CeO ₂ Nanosized Catalyst and CeO ₂ (111)/Cu(111) Inverse Model Catalyst
journal, March 2008

CO Oxidation on Inverse CeO _x /Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O ₂
journal, March 2011

Nanopattering in CeO _x /Cu(111): A New Type of Surface Reconstruction and Enhancement of Catalytic Activity
journal, March 2012

Oxidation State Imaging of Ceria Island Growth on Re(0001)
journal, August 2013

Reaction of water with Ce–Au(111) and CeOx/Au(111) surfaces: Photoemission and STM studies
journal, June 2007

Growth of Ceria Nano-Islands on a Stepped Au(788) Surface
journal, August 2015

Approaching nanoscale oxides: models and theoretical methods
journal, January 2009

Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles
journal, October 2009

Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2
journal, July 2014

Importance of the Metal-Oxide Interface in Catalysis: In Situ Studies of the Water-Gas Shift Reaction by Ambient-Pressure X-ray Photoelectron Spectroscopy
journal, April 2013

Kinetics and mechanism of the water-gas shift reaction catalysed by the clean and Cs-promoted Cu(110) surface: a comparison with Cu(111)
journal, January 1990

A surface science investigation of the water-gas shift reaction on Cu(111)
journal, March 1987

On the Mechanism of Low-Temperature Water Gas Shift Reaction on Copper
journal, January 2008

Unraveling the Active Site in Copper−Ceria Systems for the Water−Gas Shift Reaction: In Situ Characterization of an Inverse Powder CeO _{2− x} /CuO−Cu Catalyst
journal, February 2010

Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄)
journal, January 2010

Ultrathin metal films and particles on oxide surfaces: structural, electronic and chemisorptive properties
journal, January 1997

Surface studies of supported model catalysts
journal, January 1998

Formation of TiO ₂ Nanoparticles by Reactive-Layer-Assisted Deposition and Characterization by XPS and STM
journal, July 2005

Surface Structures of Ultrathin TiO _x Films on Au(111)
journal, April 2011

Preparation of TiO ₂ Nanocrystallites by Oxidation of Ti−Au(111) Surface Alloy
journal, June 2009

Mechanism and Active Sites of the Oxidation of CO over Au/TiO2
journal, September 2011

Activating Nonreducible Oxides via Doping
journal, April 2015

A Case of Strong Metal-Support Interactions: Combining Advanced Microscopy and Model Systems to Elucidate the Atomic Structure of Interfaces
journal, May 2014

First principles studies of complex oxide surfaces and interfaces
journal, June 2004

Preparation and Structural Characterization of RuS ₂ Nanoislands on Au(111)
journal, July 2004

In Situ Detection of Active Edge Sites in Single-Layer MoS ₂ Catalysts
journal, July 2015

CO2 Hydrogenation over Carbide Catalysts.
journal, January 1992

Surface Chemistry of Transition Metal Carbides
journal, January 2005

Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts
journal, July 2007

Atomic-scale insight into structure and morphology changes of MoS₂ nanoclusters in hydrotreating catalysts
journal, January 2004

Thermal reduction of ceria nanostructures on rhodium(111) and re-oxidation by CO ₂
journal, January 2018

Ceria-based model catalysts: fundamental studies on the importance of the metal–ceria interface in CO oxidation, the water–gas shift, CO ₂ hydrogenation, and methane and alcohol reforming
journal, January 2017

CO oxidation activity of Pt, Zn and ZnPt nanocatalysts: a comparative study by in situ near-ambient pressure X-ray photoelectron spectroscopy
journal, January 2018

Facile Preparation of Inverse Nanoporous Cr ₂ O ₃ /Cu Catalysts for Reverse Water‐Gas Shift Reaction
journal, October 2019

Construction of stabilized bulk-nano interfaces for highly promoted inverse CeO2/Cu catalyst
journal, August 2019

Morphology and reactivity of size-selected titanium oxide nanoclusters on Au(111)
journal, February 2020