Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111)
Abstract
While surface science has provided fundamental insights into a variety a materials, the most used catalysts in the industry, namely zeolites, still remain a challenge. The recent preparation of two-dimensional versions of MFI zeolite frameworks and the possibility of their deposition on electrically conductive supports provides for the first time a viable strategy to perform detailed studies on industrially relevant zeolites using the vast toolkit of surface science. In this work we demonstrate the use of infrared reflection absorption spectroscopy (IRRAS) and synchrotron-based x-ray photoelectron spectroscopy (XPS) to study these materials. Furthermore, polarization modulation IRRAS is used to study the adsorption of methanol and its effect in phonon vibrations of the zeolite framework. The possibility of using surface science methods, in particular under ambient pressure conditions, for the study of well-defined zeolites and other microporous structures opens new avenues to understand structural and mechanistic aspects of these materials as catalysts, adsorbents and molecular sieves.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Univ. of Minnesota, Minneapolis, MN (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1303014
- Alternate Identifier(s):
- OSTI ID: 1416652
- Report Number(s):
- BNL-112489-2016-JA
Journal ID: ISSN 0920-5861; R&D Project: 16083; KC0403020
- Grant/Contract Number:
- SC00112704; SC0012704; SC000105; 15-010
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Today
- Additional Journal Information:
- Journal Name: Catalysis Today; Journal ID: ISSN 0920-5861
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; Zeolites; Surface Science; X-ray Photoelectron Spectroscopy; Infrared Reflection Absorption Spectroscopy
Citation Formats
J. D. Kestell, Zhong, J. Q., Shete, M., Waluyo, I., Sadowski, J. T., Stacchiola, D. J., Tsapatsis, M., and Boscoboinik, J. A. Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111). United States: N. p., 2016.
Web. doi:10.1016/j.cattod.2016.07.015.
J. D. Kestell, Zhong, J. Q., Shete, M., Waluyo, I., Sadowski, J. T., Stacchiola, D. J., Tsapatsis, M., & Boscoboinik, J. A. Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111). United States. https://doi.org/10.1016/j.cattod.2016.07.015
J. D. Kestell, Zhong, J. Q., Shete, M., Waluyo, I., Sadowski, J. T., Stacchiola, D. J., Tsapatsis, M., and Boscoboinik, J. A. Tue .
"Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111)". United States. https://doi.org/10.1016/j.cattod.2016.07.015. https://www.osti.gov/servlets/purl/1303014.
@article{osti_1303014,
title = {Studying Two-Dimensional Zeolites with the Tools of Surface Science: MFI Nanosheets on Au(111)},
author = {J. D. Kestell and Zhong, J. Q. and Shete, M. and Waluyo, I. and Sadowski, J. T. and Stacchiola, D. J. and Tsapatsis, M. and Boscoboinik, J. A.},
abstractNote = {While surface science has provided fundamental insights into a variety a materials, the most used catalysts in the industry, namely zeolites, still remain a challenge. The recent preparation of two-dimensional versions of MFI zeolite frameworks and the possibility of their deposition on electrically conductive supports provides for the first time a viable strategy to perform detailed studies on industrially relevant zeolites using the vast toolkit of surface science. In this work we demonstrate the use of infrared reflection absorption spectroscopy (IRRAS) and synchrotron-based x-ray photoelectron spectroscopy (XPS) to study these materials. Furthermore, polarization modulation IRRAS is used to study the adsorption of methanol and its effect in phonon vibrations of the zeolite framework. The possibility of using surface science methods, in particular under ambient pressure conditions, for the study of well-defined zeolites and other microporous structures opens new avenues to understand structural and mechanistic aspects of these materials as catalysts, adsorbents and molecular sieves.},
doi = {10.1016/j.cattod.2016.07.015},
journal = {Catalysis Today},
number = ,
volume = ,
place = {United States},
year = {Tue Jul 26 00:00:00 EDT 2016},
month = {Tue Jul 26 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Evolving applications of zeolite molecular sieves
journal, November 2011
- Lin, Christopher C. H.; Dambrowitz, K. Amy; Kuznicki, Steven M.
- The Canadian Journal of Chemical Engineering, Vol. 90, Issue 2
Catalytic Applications of Zeolites in Chemical Industry
journal, April 2009
- Yilmaz, Bilge; Müller, Ulrich
- Topics in Catalysis, Vol. 52, Issue 6-7
Exploring Zeolite Chemistry with the Tools of Surface Science: Challenges, Opportunities, and Limitations
journal, September 2014
- Boscoboinik, J. Anibal; Shaikhutdinov, Shamil
- Catalysis Letters, Vol. 144, Issue 12
Modeling Zeolites with Metal-Supported Two-Dimensional Aluminosilicate Films
journal, April 2012
- Boscoboinik, Jorge Anibal; Yu, Xin; Yang, Bing
- Angewandte Chemie International Edition, Vol. 51, Issue 24
Dispersible Exfoliated Zeolite Nanosheets and Their Application as a Selective Membrane
journal, October 2011
- Varoon, K.; Zhang, X.; Elyassi, B.
- Science, Vol. 334, Issue 6052, p. 72-75
Two-Dimensional Zeolites: Current Status and Perspectives
journal, February 2014
- Roth, Wieslaw J.; Nachtigall, Petr; Morris, Russell E.
- Chemical Reviews, Vol. 114, Issue 9
Solution-processable exfoliated zeolite nanosheets purified by density gradient centrifugation
journal, May 2013
- Agrawal, Kumar Varoon; Topuz, Berna; Jiang, Zheyu
- AIChE Journal, Vol. 59, Issue 9, p. 3458-3467
2D Zeolite Coatings: Langmuir-Schaefer Deposition of 3 nm Thick MFI Zeolite Nanosheets
journal, April 2015
- Rangnekar, Neel; Shete, Meera; Agrawal, Kumar Varoon
- Angewandte Chemie International Edition, Vol. 54, Issue 22
Conversion of Methanol and Glycerol into Gasoline via ZSM-5 Catalysis
journal, November 2013
- Luo, Guanqun; McDonald, Armando G.
- Energy & Fuels, Vol. 28, Issue 1
Methanol-to-hydrocarbons: catalytic materials and their behavior
journal, June 1999
- Stöcker, Michael
- Microporous and Mesoporous Materials, Vol. 29, Issue 1-2
Adsorption of alcohols from aqueous solution by ZSM-5
journal, February 1984
- Milestone, Neil B.; Bibby, David M.
- Journal of Chemical Technology and Biotechnology. Chemical Technology, Vol. 34, Issue 2
Concentration of alcohols by adsorption on silicalite: Alcohol concentration by adsorption
journal, January 1981
- Milestone, Neil B.; Bibby, David M.
- Journal of Chemical Technology and Biotechnology, Vol. 31, Issue 1
Quantification of thickness and wrinkling of exfoliated two-dimensional zeolite nanosheets
journal, May 2015
- Kumar, Prashant; Agrawal, Kumar Varoon; Tsapatsis, Michael
- Nature Communications, Vol. 6, Issue 1
Oxidation and Reduction under Cover: Chemistry at the Confined Space between Ultrathin Nanoporous Silicates and Ru(0001)
journal, April 2016
- Zhong, Jian-Qiang; Kestell, John; Waluyo, Iradwikanari
- The Journal of Physical Chemistry C, Vol. 120, Issue 15
Silicalite characterization. 1. Structure, adsorptive capacity, and IR spectroscopy of the framework and hydroxyl modes
journal, June 1992
- Zecchina, A.; Bordiga, S.; Spoto, G.
- The Journal of Physical Chemistry, Vol. 96, Issue 12
Experimental IR study and ab initio modelling of ethylene adsorption in a MFI-type host zeolite
journal, October 2009
- Zvereva-Loëte, N.; Ballandras, A.; Weber, G.
- Molecular Physics, Vol. 107, Issue 19
The infra-red spectra of layer silicates
journal, July 1964
- Farmer, V. C.; Russell, J. D.
- Spectrochimica Acta, Vol. 20, Issue 7
Probing the surface of nanosheet H-ZSM-5 with FTIR spectroscopy
journal, January 2013
- Lønstad Bleken, Bjørn-Tore; Mino, Lorenzo; Giordanino, Filippo
- Physical Chemistry Chemical Physics, Vol. 15, Issue 32
Pillared MFI Zeolite Nanosheets of a Single-Unit-Cell Thickness
journal, March 2010
- Na, Kyungsu; Choi, Minkee; Park, Woojin
- Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4169-4177
Multicomponent Adsorption of Alcohols onto Silicalite-1 from Aqueous Solution: Isotherms, Structural Analysis, and Assessment of Ideal Adsorbed Solution Theory
journal, October 2012
- Bai, Peng; Tsapatsis, Michael; Siepmann, J. Ilja
- Langmuir, Vol. 28, Issue 44
Molecular Screening of Alcohol and Polyol Adsorption onto MFI-Type Zeolites
journal, February 2012
- Xiong, Ruichang; Sandler, Stanley I.; Vlachos, Dionisios G.
- Langmuir, Vol. 28, Issue 9
Alcohol Adsorption onto Silicalite from Aqueous Solution
journal, September 2011
- Xiong, Ruichang; Sandler, Stanley I.; Vlachos, Dionisios G.
- The Journal of Physical Chemistry C, Vol. 115, Issue 38
Precipitation of amorphous SiO2 particles and their properties
journal, March 2011
- Musić, S.; Filipović-Vinceković, N.; Sekovanić, L.
- Brazilian Journal of Chemical Engineering, Vol. 28, Issue 1
Physicochemical Characterization of Silicalite-1 Nanophase Material
journal, April 1998
- Ravishankar, Raman; Kirschhock, Christine; Schoeman, Brian J.
- The Journal of Physical Chemistry B, Vol. 102, Issue 15
Energy Level Shifts at the Silica/Ru(0001) Heterojunction Driven by Surface and Interface Dipoles
journal, September 2016
- Wang, Mengen; Zhong, Jian-Qiang; Kestell, John
- Topics in Catalysis, Vol. 60, Issue 6-7
Works referencing / citing this record:
Cationic two-dimensional inorganic networks of antimony oxide hydroxide for Lewis acid catalysis
journal, January 2018
- Yin, Jinlin; Fei, Honghan
- Dalton Transactions, Vol. 47, Issue 12
Highly Oriented Growth of Catalytically Active Zeolite ZSM-5 Films with a Broad Range of Si/Al Ratios
journal, July 2017
- Fu, Donglong; Schmidt, Joel E.; Ristanović, Zoran
- Angewandte Chemie, Vol. 129, Issue 37
Chemistry in confined space through the eyes of surface science—2D porous materials
journal, December 2018
- Boscoboinik, J. Anibal
- Journal of Physics: Condensed Matter, Vol. 31, Issue 6
Energy Level Shifts at the Silica/Ru(0001) Heterojunction Driven by Surface and Interface Dipoles
journal, September 2016
- Wang, Mengen; Zhong, Jian-Qiang; Kestell, John
- Topics in Catalysis, Vol. 60, Issue 6-7