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Title: Magnetic ordering-induced multiferroic behavior in [CH3NH3][Co(HCOO)3] metal-organic framework.

Abstract

Here, we present the first example of magnetic ordering-induced multiferroic behavior in a metal–organic framework magnet. This compound is [CH3NH3][Co(HCOO)3] with a perovskite-like structure. The A-site [CH3NH3]+ cation strongly distorts the framework, allowing anisotropic magnetic and electric behavior and coupling between them to occur. This material is a spin canted antiferromagnet below 15.9 K with a weak ferromagnetic component attributable to Dzyaloshinskii–Moriya (DM) interactions and experiences a discontinuous hysteretic magnetic-field-induced switching along [010] and a more continuous hysteresis along [101]. Coupling between the magnetic and electric order is resolved when the field is applied along this [101]: a spin rearrangement occurs at a critical magnetic field in the ac plane that induces a change in the electric polarization along [101] and [10-1]. The electric polarization exhibits an unusual memory effect, as it remembers the direction of the previous two magnetic-field pulses applied. The data are consistent with an inverse-DM mechanism for multiferroic behavior.

Authors:
 [1];  [2];  [1];  [3];  [1];  [1];  [1];  [2]
+ Show Author Affiliations
  1. Univ. of Coruna, Coruna (Spain)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  3. Univ. of Santiago de Compostela, Santiago de Compostela (Spain)
Publication Date:
Research Org.:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Org.:
USDOE Laboratory Directed Research and Development (LDRD) Program
OSTI Identifier:
1296677
Report Number(s):
LA-UR-15-28719
Journal ID: ISSN 0002-7863
Grant/Contract Number:  
AC52-06NA25396
Resource Type:
Accepted Manuscript
Journal Name:
Journal of the American Chemical Society
Additional Journal Information:
Journal Volume: 138; Journal Issue: 4; Journal ID: ISSN 0002-7863
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; high magnetic field science

Citation Formats

Gomez-Aguirre, Lilian Claudia, Zapf, Vivien S., Pato-Doldan, Breogan, Mira, Jorge, Castro-Garcia, Socorro, Senaris-Rodriguez, Maria Antonia, Sanchez-Andujara, Manuel, and Singleton, John. Magnetic ordering-induced multiferroic behavior in [CH3NH3][Co(HCOO)3] metal-organic framework.. United States: N. p., 2015. Web. doi:10.1021/jacs.5b11688.
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Gomez-Aguirre, Lilian Claudia, Zapf, Vivien S., Pato-Doldan, Breogan, Mira, Jorge, Castro-Garcia, Socorro, Senaris-Rodriguez, Maria Antonia, Sanchez-Andujara, Manuel, & Singleton, John. Magnetic ordering-induced multiferroic behavior in [CH3NH3][Co(HCOO)3] metal-organic framework.. United States. https://doi.org/10.1021/jacs.5b11688
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Gomez-Aguirre, Lilian Claudia, Zapf, Vivien S., Pato-Doldan, Breogan, Mira, Jorge, Castro-Garcia, Socorro, Senaris-Rodriguez, Maria Antonia, Sanchez-Andujara, Manuel, and Singleton, John. Wed . "Magnetic ordering-induced multiferroic behavior in [CH3NH3][Co(HCOO)3] metal-organic framework.". United States. https://doi.org/10.1021/jacs.5b11688. https://www.osti.gov/servlets/purl/1296677.
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@article{osti_1296677,
title = {Magnetic ordering-induced multiferroic behavior in [CH3NH3][Co(HCOO)3] metal-organic framework.},
author = {Gomez-Aguirre, Lilian Claudia and Zapf, Vivien S. and Pato-Doldan, Breogan and Mira, Jorge and Castro-Garcia, Socorro and Senaris-Rodriguez, Maria Antonia and Sanchez-Andujara, Manuel and Singleton, John},
abstractNote = {Here, we present the first example of magnetic ordering-induced multiferroic behavior in a metal–organic framework magnet. This compound is [CH3NH3][Co(HCOO)3] with a perovskite-like structure. The A-site [CH3NH3]+ cation strongly distorts the framework, allowing anisotropic magnetic and electric behavior and coupling between them to occur. This material is a spin canted antiferromagnet below 15.9 K with a weak ferromagnetic component attributable to Dzyaloshinskii–Moriya (DM) interactions and experiences a discontinuous hysteretic magnetic-field-induced switching along [010] and a more continuous hysteresis along [101]. Coupling between the magnetic and electric order is resolved when the field is applied along this [101]: a spin rearrangement occurs at a critical magnetic field in the ac plane that induces a change in the electric polarization along [101] and [10-1]. The electric polarization exhibits an unusual memory effect, as it remembers the direction of the previous two magnetic-field pulses applied. The data are consistent with an inverse-DM mechanism for multiferroic behavior.},
doi = {10.1021/jacs.5b11688},
journal = {Journal of the American Chemical Society},
number = 4,
volume = 138,
place = {United States},
year = {Wed Dec 30 00:00:00 EST 2015},
month = {Wed Dec 30 00:00:00 EST 2015}
}
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Works referenced in this record:

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005

Multiferroic and magnetoelectric materials
journal, August 2006

  • Eerenstein, W.; Mathur, N. D.; Scott, J. F.
  • Nature, Vol. 442, Issue 7104
  • DOI: 10.1038/nature05023

Why Are There so Few Magnetic Ferroelectrics?
journal, July 2000

  • Hill, Nicola A.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 29
  • DOI: 10.1021/jp000114x

Classifying multiferroics: Mechanisms and effects
journal, March 2009

Multiferroic memories
journal, March 2007

Electric-field control of local ferromagnetism using a magnetoelectric multiferroic
journal, April 2008

  • Chu, Ying-Hao; Martin, Lane W.; Holcomb, Mikel B.
  • Nature Materials, Vol. 7, Issue 6, p. 478-482
  • DOI: 10.1038/nmat2184

Coexisting Ferromagnetic and Ferroelectric Order in a CuCl 4 -based Organic–Inorganic Hybrid
journal, December 2011

  • Polyakov, Alexey O.; Arkenbout, Anne H.; Baas, Jacob
  • Chemistry of Materials, Vol. 24, Issue 1
  • DOI: 10.1021/cm2023696

Magnetically induced electric polarization in an organometallic magnet
journal, August 2010

Magnetoelectric effects in an organometallic quantum magnet
journal, April 2011

Coexistence of Magnetic and Electric Orderings in the Metal–Formate Frameworks of [NH 4 ][M(HCOO) 3 ]
journal, September 2011

  • Xu, Guan-Cheng; Zhang, Wen; Ma, Xiao-Ming
  • Journal of the American Chemical Society, Vol. 133, Issue 38
  • DOI: 10.1021/ja206891q

Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX 3 Architecture
journal, September 2009

  • Jain, Prashant; Ramachandran, Vasanth; Clark, Ronald J.
  • Journal of the American Chemical Society, Vol. 131, Issue 38
  • DOI: 10.1021/ja904156s

Ferroelectric Metal–Organic Frameworks
journal, September 2011

  • Zhang, Wen; Xiong, Ren-Gen
  • Chemical Reviews, Vol. 112, Issue 2
  • DOI: 10.1021/cr200174w

Multiferroic Materials: The Attractive Approach of Metal-Organic Frameworks (MOFs)
journal, February 2010

  • Rogez, Guillaume; Viart, Nathalie; Drillon, Marc
  • Angewandte Chemie International Edition, Vol. 49, Issue 11
  • DOI: 10.1002/anie.200906660

Characterization of the Order−Disorder Dielectric Transition in the Hybrid Organic−Inorganic Perovskite-Like Formate Mn(HCOO) 3 [(CH 3 ) 2 NH 2 ]
journal, February 2010

  • Sánchez-Andújar, M.; Presedo, S.; Yáñez-Vilar, S.
  • Inorganic Chemistry, Vol. 49, Issue 4
  • DOI: 10.1021/ic901872g

Coexistence of magnetic and electrical order in the new perovskite-like (C3N2H5)[Mn(HCOO)3] formate
journal, January 2013

  • Pato-Doldán, B.; Gómez-Aguirre, L. C.; Bermúdez-García, J. M.
  • RSC Advances, Vol. 3, Issue 44
  • DOI: 10.1039/c3ra43165g

A Multiferroic Perdeutero Metal-Organic Framework
journal, October 2011

  • Fu, Da-Wei; Zhang, Wen; Cai, Hong-Ling
  • Angewandte Chemie International Edition, Vol. 50, Issue 50
  • DOI: 10.1002/anie.201103265

Tuning the Ferroelectric Polarization in a Multiferroic Metal–Organic Framework
journal, November 2013

  • Di Sante, Domenico; Stroppa, Alessandro; Jain, Prashant
  • Journal of the American Chemical Society, Vol. 135, Issue 48
  • DOI: 10.1021/ja408283a

Electric Control of Magnetization and Interplay between Orbital Ordering and Ferroelectricity in a Multiferroic Metal-Organic Framework
journal, May 2011

  • Stroppa, Alessandro; Jain, Prashant; Barone, Paolo
  • Angewandte Chemie International Edition, Vol. 50, Issue 26
  • DOI: 10.1002/anie.201101405

Hybrid Improper Ferroelectricity in a Multiferroic and Magnetoelectric Metal-Organic Framework
journal, February 2013

Electric control of magnetism in a multiferroic metal-organic framework: Electric control of magnetism in a multiferroic metal-organic framework
journal, November 2013

  • Tian, Ying; Cong, Junzhuang; Shen, Shipeng
  • physica status solidi (RRL) - Rapid Research Letters, Vol. 8, Issue 1
  • DOI: 10.1002/pssr.201308230

Magnetoelectric coupling in the paramagnetic state of a metal-organic framework
journal, June 2013

  • Wang, W.; Yan, L. -Q.; Cong, J. -Z.
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02024

Cross coupling between electric and magnetic orders in a multiferroic metal-organic framework
journal, August 2014

  • Tian, Ying; Stroppa, Alessandro; Chai, Yisheng
  • Scientific Reports, Vol. 4, Issue 1
  • DOI: 10.1038/srep06062

Perovskite-like Metal Formates with Weak Ferromagnetism and as Precursors to Amorphous Materials
journal, July 2004

  • Wang, Xin-Yi; Gan, Lin; Zhang, Shi-Wei
  • Inorganic Chemistry, Vol. 43, Issue 15
  • DOI: 10.1021/ic0498081

Poly[methylammonium tris(μ 2 -formato-κ 2 O : O ′)cobalt(II)]
journal, November 2004

  • Boča, Miroslav; Svoboda, Ingrid; Renz, Franz
  • Acta Crystallographica Section C Crystal Structure Communications, Vol. 60, Issue 12
  • DOI: 10.1107/S0108270104025776

Metal-Organic Perovskites: Synthesis, Structures, and Magnetic Properties of [C(NH 2 ) 3 ][M II (HCOO) 3 ] (M=Mn, Fe, Co, Ni, Cu, and Zn; C(NH 2 ) 3 = Guanidinium)
journal, November 2009

  • Hu, Ke-Li; Kurmoo, Mohamedally; Wang, Zheming
  • Chemistry - A European Journal, Vol. 15, Issue 44
  • DOI: 10.1002/chem.200901605

Magnetic control of ferroelectric polarization
journal, November 2003

Field-induced linear magnetoelastic coupling in multiferroic TbMnO 3
journal, January 2006

Successive Magnetic-Field-Induced Transitions and Colossal Magnetoelectric Effect in Ni 3 TeO 6
journal, September 2015

Multiferroicity with coexisting isotropic and anisotropic spins in Ca 3 Co 2 − x Mn x O 6
journal, February 2014

Magnetic Field Induced Transition in Vanadium Spinels
journal, January 2014

The Origin and Coupling Mechanism of the Magnetoelectric Effect in TM Cl 2 -4SC(NH 2 ) 2 ( TM = Ni and Co)
journal, January 2014

  • Mun, Eundeok; Wilcox, Jason; Manson, Jamie L.
  • Advances in Condensed Matter Physics, Vol. 2014
  • DOI: 10.1155/2014/512621

Magnetic-field-induced phases in anisotropic triangular antiferromagnets: Application to CuCrO 2
journal, June 2014

Non-hysteretic colossal magnetoelectricity in a collinear antiferromagnet
journal, January 2014

  • Oh, Yoon Seok; Artyukhin, Sergey; Yang, Jun Jie
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4201

Multiferroicity: the coupling between magnetic and polarization orders
journal, July 2009

Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites
journal, March 2006

Quantum Tunneling of Magnetization in a Metal-Organic Framework
journal, January 2014

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    Works referencing / citing this record:

    Chemically diverse and multifunctional hybrid organic–inorganic perovskites
    journal, February 2017

    Raman and single-crystal X-ray diffraction evidence of pressure-induced phase transitions in a perovskite-like framework of [(C 3 H 7 ) 4 N] [Mn(N(CN) 2 ) 3 ]
    journal, January 2019

    • Mączka, Mirosław; Collings, Ines E.; Leite, Fabio Furtado
    • Dalton Transactions, Vol. 48, Issue 25
    • DOI: 10.1039/c9dt01648a

    Large pyroelectric and thermal expansion coefficients in the [(CH 3 ) 2 NH 2 ]Mn (HCOO) 3 metal-organic framework
    journal, July 2017

    • Ma, Yinina; Cong, Junzhuang; Chai, Yisheng
    • Applied Physics Letters, Vol. 111, Issue 4
    • DOI: 10.1063/1.4989783

    Magnetic-Field Tuning of Hydrogen Bond Order-Disorder Transition in Metal-Organic Frameworks
    journal, June 2019

    Two-dimensional magnetic materials of cobalt( ii ) triangular lattices constructed by a mixed benzimidazole–dicarboxylate strategy
    journal, January 2019

    • Kong, Jiao-Jiao; Jiang, Yu-Xuan; Zhang, Jia-Chen
    • CrystEngComm, Vol. 21, Issue 15
    • DOI: 10.1039/c9ce00129h

    Multiferroicity and magnetoelectric coupling in the paramagnetic state of the metal-organic framework [(CH 3 ) 2 NH 2 ]Ni(HCOO) 3
    journal, March 2019

    • Ma, Yinina; Cong, Junzhuang; Sun, Young
    • Journal of Physics: Condensed Matter, Vol. 31, Issue 20
    • DOI: 10.1088/1361-648x/ab03ef

    An insight into the magnetoelectric coupling effect in the MOF of [NH 2 (CH 3 ) 2 ] n [Fe III Fe II (HCOO) 6 ] n
    journal, May 2017

    • Guo, Jiangbin; Chen, Lihong; Li, Dong
    • Applied Physics Letters, Vol. 110, Issue 19
    • DOI: 10.1063/1.4983169

    Tuning Expanded Pores in Metal-Organic Frameworks for Selective Capture and Catalytic Conversion of Carbon Dioxide
    journal, October 2018

    Multiple phase and dielectric transitions on a novel multi-sensitive [TPrA][M(dca) 3 ] (M: Fe 2+ , Co 2+ and Ni 2+ ) hybrid inorganic–organic perovskite family
    journal, January 2016

    • Bermúdez-García, J. M.; Sánchez-Andújar, M.; Yáñez-Vilar, S.
    • Journal of Materials Chemistry C, Vol. 4, Issue 22
    • DOI: 10.1039/c6tc00723f

    3D Organic–Inorganic Perovskite Ferroelastic Materials with Two Ferroelastic Phases: [Et 3 P(CH 2 ) 2 F][Mn(dca) 3 ] and [Et 3 P(CH 2 ) 2 Cl][Mn(dca) 3 ]
    journal, April 2019

    • Zhao, Meng‐Meng; Zhou, Lin; Shi, Ping‐Ping
    • Chemistry – A European Journal, Vol. 25, Issue 25
    • DOI: 10.1002/chem.201900771

    Order–disorder phase transition in the first thiocyanate-bridged double perovskite-type coordination polymer: [NH 4 ] 2 [NiCd(SCN) 6 ]
    journal, January 2016

    • Xie, Kai-Ping; Xu, Wei-Jian; He, Chun-Ting
    • CrystEngComm, Vol. 18, Issue 24
    • DOI: 10.1039/c6ce00898d

    Giant barocaloric tunability in [(CH 3 CH 2 CH 2 ) 4 N]Cd[N(CN) 2 ] 3 hybrid perovskite
    journal, January 2018

    • Bermúdez-García, Juan Manuel; Yáñez-Vilar, Susana; García-Fernández, Alberto
    • Journal of Materials Chemistry C, Vol. 6, Issue 37
    • DOI: 10.1039/c7tc03136j

    Incommensurate structures of the [CH 3 NH 3 ][Co(COOH) 3 ] compound
    journal, January 2019

    Designing of a Magnetodielectric System in Hybrid Organic–Inorganic Framework, a Perovskite Layered Phosphonate MnO 3 PC 6 H 4 ‐ m ‐Br⋅H 2 O
    journal, June 2019

    • Basu, Tathamay; Bloyet, Clarisse; Beaubras, Félicien
    • Advanced Functional Materials, Vol. 29, Issue 33
    • DOI: 10.1002/adfm.201901878

    Room-temperature magnetoelectric effect in a chiral smectic liquid crystal
    journal, December 2017

    • Ueda, H.; Akita, T.; Uchida, Y.
    • Applied Physics Letters, Vol. 111, Issue 26
    • DOI: 10.1063/1.5007317

    Magnetoelectric behavior via a spin state transition
    journal, September 2019

    Coexistence of Three Ferroic Orders in the Multiferroic Compound [(CH 3 ) 4 N][Mn(N 3 ) 3 ] with Perovskite-Like Structure
    journal, April 2016

    • Gómez-Aguirre, L. Claudia; Pato-Doldán, Breogán; Stroppa, Alessandro
    • Chemistry - A European Journal, Vol. 22, Issue 23
    • DOI: 10.1002/chem.201503445

    Magnetic field-temperature phase diagram of multiferroic (NH4)2FeCl5·H2O
    journal, August 2019

    Synthesis and temperature-dependent studies of a perovskite-like manganese formate framework templated with protonated acetamidine
    journal, January 2017

    • Mączka, Mirosław; Janczak, Jan; Trzebiatowska, Monika
    • Dalton Transactions, Vol. 46, Issue 26
    • DOI: 10.1039/c7dt01251a

    A Series of Bimetallic Ammonium AlNa Formates
    journal, June 2017

    Static disorder in a perovskite mixed-valence metal–organic framework
    journal, January 2020

    • Collings, Ines E.; Saines, Paul J.; Mikolasek, Mirko
    • CrystEngComm, Vol. 22, Issue 16
    • DOI: 10.1039/d0ce00119h

    Giant Room-Temperature Magnetodielectric Response in a MOF at 0.1 Tesla
    journal, October 2017

    Coupling of Magnetic and Elastic Domains in the Organic-Inorganic Layered Perovskite-Like (C 6 H 5 C 2 H 4 NH 3 ) 2 Fe II Cl 4 Crystal
    journal, July 2017

    • Nakayama, Yuki; Nishihara, Sadafumi; Inoue, Katsuya
    • Angewandte Chemie International Edition, Vol. 56, Issue 32
    • DOI: 10.1002/anie.201703898

    Multiferroic Nanopatterned Hybrid Material with Room-Temperature Magnetic Switching of the Electric Polarization
    journal, December 2016

    • Cai, Ronggang; Antohe, Vlad-Andrei; Hu, Zhijun
    • Advanced Materials, Vol. 29, Issue 6
    • DOI: 10.1002/adma.201604604

    Zn( ii )-based metal–organic framework: an exceptionally thermally stable, guest-free low dielectric material
    journal, January 2017

    • Mendiratta, Shruti; Usman, Muhammad; Chang, Chun-Chi
    • Journal of Materials Chemistry C, Vol. 5, Issue 6
    • DOI: 10.1039/c6tc05314a

    Microscopic Insights on the Multiferroic Perovskite-Like [CH 3 NH 3 ][Co(COOH) 3 ] Compound
    journal, October 2017

    • Mazzuca, Lidia; Cañadillas-Delgado, Laura; Fabelo, Oscar
    • Chemistry - A European Journal, Vol. 24, Issue 2
    • DOI: 10.1002/chem.201703140

    Thermal conductivity of a perovskite-type metal–organic framework crystal
    journal, January 2017

    • Gunatilleke, Wilarachchige D. C. B.; Wei, Kaya; Niu, Zheng
    • Dalton Transactions, Vol. 46, Issue 39
    • DOI: 10.1039/c7dt02927f

    Pressure dependence of spin canting in ammonium metal formate antiferromagnets
    journal, January 2018

    • Collings, Ines E.; Manna, Rudra Sekhar; Tsirlin, Alexander A.
    • Physical Chemistry Chemical Physics, Vol. 20, Issue 37
    • DOI: 10.1039/c8cp03761b

    Anisotropic heat conduction in the metal organic framework perovskites [C(NH 2 ) 3 ]X(HCOO) 3 (X = Cu, Zn)
    journal, February 2019

    • Shukla, Dharmendra; Prasai, Narayan; Carlino, Thomas M.
    • Applied Physics Letters, Vol. 114, Issue 8
    • DOI: 10.1063/1.5086978

    Magnetic field tuning of quantum spin excitations in a weakly coupled S = 1 2 Heisenberg spin chain as seen from NMR
    journal, September 2019

    Electric and magnetic transitions with 90° turning of polarizations in a layered perovskite of [NH 4 Cl] 2 [Ni(HCOO) 2 (NH 3 ) 2 ]
    journal, November 2018

    • Chen, Sa; Shang, Ran; Wang, Bing-Wu
    • APL Materials, Vol. 6, Issue 11
    • DOI: 10.1063/1.5040688

    Temperature- and pressure-dependent studies of a highly flexible and compressible perovskite-like cadmium dicyanamide framework templated with protonated tetrapropylamine
    journal, January 2019

    • Mączka, Mirosław; Ptak, Maciej; Gągor, Anna
    • Journal of Materials Chemistry C, Vol. 7, Issue 8
    • DOI: 10.1039/c8tc06401f

    A breakthrough in the intrinsic multiferroic temperature region in Prussian blue analogues
    journal, January 2019

    • Kong, Qingrong; Qin, Ruixuan; Li, Dong
    • RSC Advances, Vol. 9, Issue 71
    • DOI: 10.1039/c9ra09224b

    Tuning the structure and properties of a multiferroic metal–organic-framework via growing under high magnetic fields
    journal, January 2018

    Spin-reorientation-induced magnetodielectric coupling effects in two layered perovskite magnets
    journal, January 2018

    • Huang, Bo; Zhang, Jian-Yu; Huang, Rui-Kang
    • Chemical Science, Vol. 9, Issue 37
    • DOI: 10.1039/c8sc02917b

    Origin of Ferrimagnetism and Ferroelectricity in Room-Temperature Multiferroic ϵ − Fe 2 O 3
    journal, April 2018

    Co/Cu-MFF derived mesoporous ternary metal oxide microcubes for enhancing the catalytic activity of the CO oxidation reaction
    journal, January 2018

    • Song, Huijun; Zhang, Li; Xu, Guancheng
    • RSC Advances, Vol. 8, Issue 44
    • DOI: 10.1039/c8ra04081h

    A Variety of Phase-Transition Behaviors in a Niccolite Series of [NH 3 (CH 2 ) 4 NH 3 ][M(HCOO) 3 ] 2
    journal, March 2016

    • Shang, Ran; Chen, Sa; Hu, Ke-Li
    • Chemistry - A European Journal, Vol. 22, Issue 18
    • DOI: 10.1002/chem.201600689

    Metal–organic ferroelectric complexes: enantiomer directional induction achieved above-room-temperature homochiral molecular ferroelectrics
    journal, January 2020

    • Liu, Yu-Ling; Ge, Jia-Zhen; Wang, Zhong-Xia
    • Inorganic Chemistry Frontiers, Vol. 7, Issue 1
    • DOI: 10.1039/c9qi01197h

    Magnetic transitions and isotropic versus anisotropic magnetic behaviour of [CH 3 NH 3 ][M(HCOO) 3 ] M = Mn 2+ , Co 2+ , Ni 2+ , Cu 2+ metal–organic perovskites
    journal, January 2016

    • Pato-Doldán, B.; Gómez-Aguirre, L. C.; Hansen, A. P.
    • Journal of Materials Chemistry C, Vol. 4, Issue 47
    • DOI: 10.1039/c6tc03992h

    Formation of the layered conductive magnet CrCl2(pyrazine)2 through redox-active coordination chemistry
    journal, September 2018

    • Pedersen, Kasper S.; Perlepe, Panagiota; Aubrey, Michael L.
    • Nature Chemistry, Vol. 10, Issue 10
    • DOI: 10.1038/s41557-018-0107-7

    Importing spontaneous polarization into a Heisenberg ferromagnet for a potential single-phase multiferroic
    journal, January 2016

    • Huang, Bo; Wang, Bao-Ying; Du, Zi-Yi
    • Journal of Materials Chemistry C, Vol. 4, Issue 37
    • DOI: 10.1039/c6tc02715f

    Effect of solvent, temperature and pressure on the stability of chiral and perovskite metal formate frameworks of [NH 2 NH 3 ][M(HCOO) 3 ] (M = Mn, Fe, Zn)
    journal, January 2016

    • Mączka, Mirosław; Pasińska, Katarzyna; Ptak, Maciej
    • Physical Chemistry Chemical Physics, Vol. 18, Issue 46
    • DOI: 10.1039/c6cp06648h

    Study of the relationship between magnetic field and dielectric properties in two ferromagnetic complexes
    journal, January 2017

    Three coordination frameworks with copper formate based low dimensional motifs: synthesis, structure and magnetic properties
    journal, January 2017

    • Bovill, Sally M.; Dixey, Richard J. C.; Saines, Paul J.
    • CrystEngComm, Vol. 19, Issue 13
    • DOI: 10.1039/c6ce01601d

    Phonon mode links ferroicities in multiferroic [ ( CH 3 ) 2 NH 2 ] Mn ( HCOO ) 3
    journal, November 2017

    Magnetodielectric coupling in a non-perovskite metal–organic framework
    journal, January 2017

    • Basu, Tathamay; Jesche, Anton; Bredenkötter, Björn
    • Mater. Horiz., Vol. 4, Issue 6
    • DOI: 10.1039/c7mh00716g

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    journal, January 2018

    • Collings, Ines E.; Bykov, Maxim; Bykova, Elena
    • CrystEngComm, Vol. 20, Issue 25
    • DOI: 10.1039/c8ce00617b

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    journal, January 2018

    • Basu, Tathamay; Bloyet, Clarisse; Rueff, Jean-Michel
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    • DOI: 10.1039/c8tc04328k

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    journal, January 2016

    • Collings, Ines E.; Bykov, Maxim; Bykova, Elena
    • CrystEngComm, Vol. 18, Issue 46
    • DOI: 10.1039/c6ce01891b

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    • Han, Shiguo; Zhang, Jing; Teng, Bing
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    • DOI: 10.1039/c7tc01085k

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    • DOI: 10.1088/1361-6463/ab6bed

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    journal, January 2018

    • Liu, Shu; Wang, Bing-Wu; Wang, Zhe-Ming
    • Dalton Transactions, Vol. 47, Issue 34
    • DOI: 10.1039/c8dt01729h

    Pressure dependence of spin canting in ammonium metal formate antiferromagnets
    text, January 2018

    • Collings, Ines; Manna, Rudra Sekhar; Tsirlin, Alexander A.
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2019-00174

    Coupling of Magnetic and Elastic Domains in the Organic-Inorganic Layered Perovskite-Like (C 6 H 5 C 2 H 4 NH 3 ) 2 Fe II Cl 4 Crystal
    journal, July 2017

    • Nakayama, Yuki; Nishihara, Sadafumi; Inoue, Katsuya
    • Angewandte Chemie, Vol. 129, Issue 32
    • DOI: 10.1002/ange.201703898

    Structural distortions in the high-pressure polar phases of ammonium metal formates
    text, January 2016

    • Collings, Ines E.; Bykov, Maxim; Bykova, Elena
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2016-05963

    Disorder–order transitions in the perovskite metal–organic frameworks $[(CH_{3})_{2}NH_{2} ][M(HCOO)_{3}]$ at high pressure
    text, January 2018

    • Collings, Ines; Bykov, Maxim; Bykova, Elena
    • Deutsches Elektronen-Synchrotron, DESY, Hamburg
    • DOI: 10.3204/pubdb-2019-00414

    Magnetodielectric coupling in a non-perovskite metal-organic framework
    text, January 2017

    A Variety of Phase-Transition Behaviors in a Niccolite Series of [NH 3 (CH 2 ) 4 NH 3 ][M(HCOO) 3 ] 2
    journal, March 2016

    • Shang, Ran; Chen, Sa; Hu, Ke-Li
    • Chemistry - A European Journal, Vol. 22, Issue 18
    • DOI: 10.1002/chem.201600689

    Giant barocaloric effect in the ferroic organic-inorganic hybrid [TPrA][Mn(dca)3] perovskite under easily accessible pressures
    journal, June 2017

    • Bermúdez-García, Juan M.; Sánchez-Andújar, Manuel; Castro-García, Socorro
    • Nature Communications, Vol. 8, Issue 1
    • DOI: 10.1038/ncomms15715

    Magnetoelectric behavior via a spin state transition
    journal, September 2019

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