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Title: Anisotropic storage medium development in a full-scale, sodium alanate-based, hydrogen storage system

Deuterium desorption in an automotive-scale hydrogen storage tube was studied in-situ using neutron diffraction. Gradients in the concentration of the various alanate phases were observed along the length of the tube but no significant radial anisotropy was present. In addition, neutron radiography and computed tomography showed large scale cracks and density fluctuations, confirming the presence of these structures in an undisturbed storage system. These results demonstrate that large scale storage structures are not uniform even after many absorption/desorption cycles and that movement of gaseous hydrogen cannot be properly modeled by a simple porous bed model. In addition, the evidence indicates that there is slow transformation of species at one end of the tube indicating loss of catalyst functionality. These observations explain the unusually fast movement of hydrogen in a full scale system and shows that loss of capacity is not occurring uniformly in this type of hydrogen-storage system.
Authors:
 [1] ;  [2] ;  [3] ;  [3]
  1. General Motors R&D, Warren, MI (United States)
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
OSTI Identifier:
1271870
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
International Journal of Hydrogen Energy
Additional Journal Information:
Journal Volume: 41; Journal Issue: 31; Journal ID: ISSN 0360-3199
Publisher:
Elsevier
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR); High Temperature Materials Laboratory (HTML); Spallation Neutron Source
Sponsoring Org:
USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 08 HYDROGEN Sodium alanate; Neutron diffraction; Neutron computed tomography; Hydrogen storage; Vehicle scale; Catalyzed desorption