skip to main content

DOE PAGESDOE PAGES

Title: Nucleophilic substitution reaction for post-functionalization of polyoxometalates

In this study, a hexamolybdate-based organic inorganic hybrid molecule containing a chloralkane fragment is synthesized and its Cl atom can be substituted by iodine and nitrate through nucleophilic substitution reactions in high yields, which provide a post-functionalization protocol to bring in various additional functional groups into polyoxometalate-based hybrid materials under mild conditions.
Authors:
 [1] ;  [2] ;  [3] ;  [3] ;  [3] ;  [4]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Tsinghua Univ., Beijing (People's Republic of China); Beijing Forestry Univ., Beijing (People's Republic of China)
  3. Tsinghua Univ., Beijing (People's Republic of China)
  4. Tsinghua Univ., Beijing (People's Republic of China); Peking Univ., Beijing (People's Republic of China)
Publication Date:
OSTI Identifier:
1267049
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
New Journal of Chemistry
Additional Journal Information:
Journal Volume: 40; Journal Issue: 2; Journal ID: ISSN 1144-0546
Publisher:
Royal Society of Chemistry
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE