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Title: Novel cross-linked polystyrenes with large space network as tailor-made catalyst supports for sustainable media

For a novel class of polystyrene-based gel-type resins (SPACeR, SP), containing the large 1,4-bis (4-vinylphenoxy)benzene cross-linker, is introduced; SP-immobilized 1,5,7-triazabicyclo [4.4.0]dec-5-ene (TBD) and triethylamine (TEA) bases are synthesized and characterized in terms of their structural, thermal and morphological features, and their catalytic efficiency in a series of fundamental chemical transformations under solvent-free conditions is investigated.
Authors:
 [1] ;  [2] ;  [1] ;  [3] ;  [2] ;  [3] ;  [3] ;  [1] ;  [2] ;  [1]
  1. Univ. of Perugia (Italy)
  2. Hasselt Univ., Diepenbeek (Belgium)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
OSTI Identifier:
1265889
Grant/Contract Number:
AC05-00OR22725
Type:
Accepted Manuscript
Journal Name:
European Polymer Journal
Additional Journal Information:
Journal Volume: 73; Journal Issue: C; Journal ID: ISSN 0014-3057
Publisher:
Elsevier
Research Org:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org:
USDOE Office of Science (SC)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE