Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding

Chen, Xinyue; Li, Hui; Yin, Panchao; Liu, Tianbo

doi:10.1039/C5CC00239G

Title: Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding

Abstract

In this study, polyoxometalates (POMs) covalently functionalized with methyl methacrylate groups were applied as surfactants in the emulsion polymerization reaction of styrene. Due to the copolymerization of the methyl methacrylate groups and the styrene monomers, the polyoxometalate clusters are covalently grafted onto the surface of polystyrene latex nanoparticles. Finally, such latex particles are fully covered with catalytic POM clusters and might serve as quasi-homogeneous catalysts.

Authors:

Chen, Xinyue ^[1]; Li, Hui ^[1]; Yin, Panchao ^[2]; Liu, Tianbo ^[1]

Univ. of Akron, OH (United States). Dept. of Polymer Science
Univ. of Akron, OH (United States). Dept. of Polymer Science; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division. Neutron Science Directorate

Publication Date:: Fri Feb 27 00:00:00 EST 2015

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1265540

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 51; Journal Issue: 28; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Chen, Xinyue, Li, Hui, Yin, Panchao, and Liu, Tianbo. Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding.  United States: N. p., 2015. 
Web.  doi:10.1039/C5CC00239G.

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                    Chen, Xinyue, Li, Hui, Yin, Panchao, & Liu, Tianbo. Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding.  United States.  https://doi.org/10.1039/C5CC00239G

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                    Chen, Xinyue, Li, Hui, Yin, Panchao, and Liu, Tianbo. Fri .  
"Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding".  United States.  https://doi.org/10.1039/C5CC00239G.  https://www.osti.gov/servlets/purl/1265540.

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@article{osti_1265540,

  title        = {Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding},

  author       = {Chen, Xinyue and Li, Hui and Yin, Panchao and Liu, Tianbo},

  abstractNote = {In this study, polyoxometalates (POMs) covalently functionalized with methyl methacrylate groups were applied as surfactants in the emulsion polymerization reaction of styrene. Due to the copolymerization of the methyl methacrylate groups and the styrene monomers, the polyoxometalate clusters are covalently grafted onto the surface of polystyrene latex nanoparticles. Finally, such latex particles are fully covered with catalytic POM clusters and might serve as quasi-homogeneous catalysts.},

  doi          = {10.1039/C5CC00239G},

  journal      = {ChemComm},

  number       = 28,

  volume       = 51,

  place        = {United States},

  year         = {Fri Feb 27 00:00:00 EST 2015},

  month        = {Fri Feb 27 00:00:00 EST 2015}

}

Copy to clipboard

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https://doi.org/10.1039/C5CC00239G

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Title: Design of polystyrene latex particles covered with polyoxometalate clusters via multiple covalent bonding

Abstract

Citation Formats

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