The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19

Kan, W. H.; Huq, A.; Manthiram, A.

doi:10.1039/C5CC03070F

Title: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe₃P₅SiO₁₉

Abstract

We report the synthesis, structure, and electrochemistry of the first Na⁺-ion cathode with two distinct types of polyanions: Fe₃P₅SiO₁₉. The Fe-based cathode has a reversible capacity of ca. 70 mAh g^-1; ca. 1.7 Na⁺ ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na⁺/Na.

Authors:

Kan, W. H. ^[1]; Huq, A. ^[2]; Manthiram, A. ^[1]

Univ. of Texas at Austin, Austin, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Science Division

Publication Date:: Fri May 15 00:00:00 EDT 2015

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Org.:: USDOE: NSF

OSTI Identifier:: 1261442

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 51; Journal Issue: 52; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Kan, W. H., Huq, A., and Manthiram, A. The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19.  United States: N. p., 2015. 
Web.  doi:10.1039/C5CC03070F.

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                    Kan, W. H., Huq, A., & Manthiram, A. The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19.  United States.  https://doi.org/10.1039/C5CC03070F

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                    Kan, W. H., Huq, A., and Manthiram, A. Fri .  
"The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19".  United States.  https://doi.org/10.1039/C5CC03070F.  https://www.osti.gov/servlets/purl/1261442.

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@article{osti_1261442,

  title        = {The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19},

  author       = {Kan, W. H. and Huq, A. and Manthiram, A.},

  abstractNote = {We report the synthesis, structure, and electrochemistry of the first Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. The Fe-based cathode has a reversible capacity of ca. 70 mAh g-1; ca. 1.7 Na+ ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na+/Na.},

  doi          = {10.1039/C5CC03070F},

  journal      = {ChemComm},

  number       = 52,

  volume       = 51,

  place        = {United States},

  year         = {Fri May 15 00:00:00 EDT 2015},

  month        = {Fri May 15 00:00:00 EDT 2015}

}

Copy to clipboard

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Works referencing / citing this record:

Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt–Structured Li _1.3 Ta _0.3 Mn _0.4 O ₂ Cathode
journal, February 2019

Kan, Wang Hay; Wei, Chenxi; Chen, Dongchang
Advanced Functional Materials, Vol. 29, Issue 17
DOI: 10.1002/adfm.201808294

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Similar Records

Title: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19

Abstract

Citation Formats

3DBVSMAPPER : a program for automatically generating bond-valence sum landscapes journal, August 2012

EXPGUI , a graphical user interface for GSAS journal, April 2001

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides journal, September 1976

Electroceramics: Characterization by Impedance Spectroscopy journal, March 1990

Crystal Structure and Magnetic Properties of a New Iron(III) Silicophosphate Fe3P5SiO19 Studied by Neutron Diffraction and Mössbauer Techniques journal, February 2002

Mo3P5SiO19: A molybdenum phosphate containing a confacial bioctahedral molybdenum(III) dimer with a MoMo bond journal, June 1988

A 3.8-V earth-abundant sodium battery electrode journal, July 2014

Screening of the alkali-metal ion containing materials from the Inorganic Crystal Structure Database (ICSD) for high ionic conductivity pathways using the bond valence method journal, October 2012

Materials Challenges and Opportunities of Lithium Ion Batteries journal, January 2011

Experimental visualization of lithium diffusion in LixFePO4 journal, August 2008

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries journal, April 1997

Formation of a Complete Solid Solution between the Triphylite and Fayalite Olivine Structures journal, November 2008

Crystal Structure Revision and Identification of Li + -Ion Migration Pathways in the Garnet-like Li 5 La 3 M 2 O 12 (M = Nb, Ta) Oxides journal, August 2004

Lithium insertion into Fe2(SO4)3 frameworks journal, May 1989

VALENCE: a program for calculating bond valences journal, August 1996

V3P5SiO19, a vanadosilicophosphate built up from V2O9 octahedra clusters journal, November 1986

Research Development on Sodium-Ion Batteries journal, October 2014

A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries journal, August 2013

Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt–Structured Li 1.3 Ta 0.3 Mn 0.4 O 2 Cathode journal, February 2019

Title: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe₃P₅SiO₁₉

3DBVSMAPPER : a program for automatically generating bond-valence sum landscapes
journal, August 2012

EXPGUI , a graphical user interface for GSAS
journal, April 2001

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976

Electroceramics: Characterization by Impedance Spectroscopy
journal, March 1990

Crystal Structure and Magnetic Properties of a New Iron(III) Silicophosphate Fe3P5SiO19 Studied by Neutron Diffraction and Mössbauer Techniques
journal, February 2002

Mo3P5SiO19: A molybdenum phosphate containing a confacial bioctahedral molybdenum(III) dimer with a MoMo bond
journal, June 1988

A 3.8-V earth-abundant sodium battery electrode
journal, July 2014

Screening of the alkali-metal ion containing materials from the Inorganic Crystal Structure Database (ICSD) for high ionic conductivity pathways using the bond valence method
journal, October 2012

Materials Challenges and Opportunities of Lithium Ion Batteries
journal, January 2011

Experimental visualization of lithium diffusion in LixFePO4
journal, August 2008

Phospho-olivines as Positive-Electrode Materials for Rechargeable Lithium Batteries
journal, April 1997

Formation of a Complete Solid Solution between the Triphylite and Fayalite Olivine Structures
journal, November 2008

Crystal Structure Revision and Identification of Li ⁺ -Ion Migration Pathways in the Garnet-like Li ₅ La ₃ M ₂ O ₁₂ (M = Nb, Ta) Oxides
journal, August 2004

Lithium insertion into Fe2(SO4)3 frameworks
journal, May 1989

VALENCE: a program for calculating bond valences
journal, August 1996

V3P5SiO19, a vanadosilicophosphate built up from V2O9 octahedra clusters
journal, November 1986

Research Development on Sodium-Ion Batteries
journal, October 2014

A zero-strain layered metal oxide as the negative electrode for long-life sodium-ion batteries
journal, August 2013

Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt–Structured Li _1.3 Ta _0.3 Mn _0.4 O ₂ Cathode
journal, February 2019