Determining the location and nearest neighbours of aluminium in zeolites with atom probe tomography
Abstract
Zeolite catalysis is determined by a combination of pore architecture and Brønsted acidity. As Brønsted acid sites are formed by the substitution of AlO4 for SiO4 tetrahedra, it is of utmost importance to have information on the number as well as the location and neighbouring sites of framework aluminium. Unfortunately, such detailed information has not yet been obtained, mainly due to the lack of suitable characterization methods. Here we report, using the powerful atomic-scale analysis technique known as atom probe tomography, the quantitative spatial distribution of individual aluminium atoms, including their three-dimensional extent of segregation. Ultimately, using a nearest-neighbour statistical analysis, we precisely determine the short-range distribution of aluminium over the different T-sites and determine the most probable Al–Al neighbouring distance within parent and steamed ZSM-5 crystals, as well as assess the long-range redistribution of aluminium upon zeolite steaming.
- Authors:
-
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Inst. for Integrated Catalysis
- Univ. of Utrecht (Netherlands)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Inst. for Integrated Catalysis; Technische Univ. of Munich, Garching (Germany)
- UOP LLC, Des Plaines, IL (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1260735
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Perea, Daniel E., Arslan, Ilke, Liu, Jia, Ristanović, Zoran, Kovarik, Libor, Arey, Bruce W., Lercher, Johannes A., Bare, Simon R., and Weckhuysen, Bert M.. Determining the location and nearest neighbours of aluminium in zeolites with atom probe tomography. United States: N. p., 2015.
Web. doi:10.1038/ncomms8589.
Perea, Daniel E., Arslan, Ilke, Liu, Jia, Ristanović, Zoran, Kovarik, Libor, Arey, Bruce W., Lercher, Johannes A., Bare, Simon R., & Weckhuysen, Bert M.. Determining the location and nearest neighbours of aluminium in zeolites with atom probe tomography. United States. https://doi.org/10.1038/ncomms8589
Perea, Daniel E., Arslan, Ilke, Liu, Jia, Ristanović, Zoran, Kovarik, Libor, Arey, Bruce W., Lercher, Johannes A., Bare, Simon R., and Weckhuysen, Bert M.. Thu .
"Determining the location and nearest neighbours of aluminium in zeolites with atom probe tomography". United States. https://doi.org/10.1038/ncomms8589. https://www.osti.gov/servlets/purl/1260735.
@article{osti_1260735,
title = {Determining the location and nearest neighbours of aluminium in zeolites with atom probe tomography},
author = {Perea, Daniel E. and Arslan, Ilke and Liu, Jia and Ristanović, Zoran and Kovarik, Libor and Arey, Bruce W. and Lercher, Johannes A. and Bare, Simon R. and Weckhuysen, Bert M.},
abstractNote = {Zeolite catalysis is determined by a combination of pore architecture and Brønsted acidity. As Brønsted acid sites are formed by the substitution of AlO4 for SiO4 tetrahedra, it is of utmost importance to have information on the number as well as the location and neighbouring sites of framework aluminium. Unfortunately, such detailed information has not yet been obtained, mainly due to the lack of suitable characterization methods. Here we report, using the powerful atomic-scale analysis technique known as atom probe tomography, the quantitative spatial distribution of individual aluminium atoms, including their three-dimensional extent of segregation. Ultimately, using a nearest-neighbour statistical analysis, we precisely determine the short-range distribution of aluminium over the different T-sites and determine the most probable Al–Al neighbouring distance within parent and steamed ZSM-5 crystals, as well as assess the long-range redistribution of aluminium upon zeolite steaming.},
doi = {10.1038/ncomms8589},
journal = {Nature Communications},
number = ,
volume = 6,
place = {United States},
year = {Thu Jul 02 00:00:00 EDT 2015},
month = {Thu Jul 02 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
X-ray Imaging of Zeolite Particles at the Nanoscale: Influence of Steaming on the State of Aluminum and the Methanol-To-Olefin Reaction
journal, March 2012
- Aramburo, Luis R.; de Smit, Emiel; Arstad, Bjørnar
- Angewandte Chemie International Edition, Vol. 51, Issue 15
3D Nanoscale Chemical Imaging of the Distribution of Aluminum Coordination Environments in Zeolites with Soft X-Ray Microscopy
journal, January 2013
- Aramburo, Luis R.; Liu, Yijin; Tyliszczak, Tolek
- ChemPhysChem, Vol. 14, Issue 3
Creation of Hollow Zeolite Architectures by Controlled Desilication of Al-Zoned ZSM-5 Crystals
journal, August 2005
- Groen, Johan C.; Bach, Torkel; Ziese, Ulrike
- Journal of the American Chemical Society, Vol. 127, Issue 31
Theoretical determination of proton affinity differences in zeolites
journal, April 1993
- Kramer, G. J.; Van Santen, R. A.
- Journal of the American Chemical Society, Vol. 115, Issue 7
Quantitative binomial distribution analyses of nanoscale like‐solute atom clustering and segregation in atom probe tomography data
journal, July 2008
- Moody, Michael P.; Stephenson, Leigh T.; Ceguerra, Anna V.
- Microscopy Research and Technique, Vol. 71, Issue 7
Clustering and nearest neighbour distances in atom-probe tomography
journal, September 2009
- Philippe, T.; De Geuser, F.; Duguay, S.
- Ultramicroscopy, Vol. 109, Issue 10
Aluminium distribution in large ZSM-5 crystals
journal, January 1988
- Chao, Kuei-jung; Chern, Jer-young
- Zeolites, Vol. 8, Issue 1
Aluminum Siting in Silicon-Rich Zeolite Frameworks: A Combined High-Resolution27Al NMR Spectroscopy and Quantum Mechanics / Molecular Mechanics Study of ZSM-5
journal, September 2007
- Sklenak, Stepan; Dědeček, Jiří; Li, Chengbin
- Angewandte Chemie International Edition, Vol. 46, Issue 38
Local Electrode Atom Probe Tomography: A User's Guide
book, January 2013
- Larson, David J.; Prosa, Ty J.; Ulfig, Robert M.
Point process statistics in atom probe tomography
journal, September 2013
- Philippe, T.; Duguay, S.; Grancher, G.
- Ultramicroscopy, Vol. 132
The monoclinic framework structure of zeolite H-ZSM-5. Comparison with the orthorhombic framework of as-synthesized ZSM-5
journal, April 1990
- van Koningsveld, H.; Jansen, J. C.; van Bekkum, H.
- Zeolites, Vol. 10, Issue 4, p. 235-242
Analysis of Three-dimensional Atom-probe Data by the Proximity Histogram
journal, September 2000
- Hellman, Olof C.; Vandenbroucke, Justin A.; Rüsing, Järg
- Microscopy and Microanalysis, Vol. 6, Issue 05
Determining the aluminium occupancy on the active T-sites in zeolites using X-ray standing waves
journal, June 2008
- van Bokhoven, Jeroen A.; Lee, Tien-Lin; Drakopoulos, Michael
- Nature Materials, Vol. 7, Issue 7
Stepwise Dealumination of Zeolite Βeta at Specific T-Sites Observed with 27 Al MAS and 27 Al MQ MAS NMR
journal, December 2000
- van Bokhoven, J. A.; Koningsberger, D. C.; Kunkeler, P.
- Journal of the American Chemical Society, Vol. 122, Issue 51
The local structure of aluminium sites in zeolites
journal, January 2004
- Joyner, Richard W.; Smith, Andy D.; Stockenhuber, Michael
- Physical Chemistry Chemical Physics, Vol. 6, Issue 23
Local Structure of the Zeolitic Catalytically Active Site during Reaction
journal, April 2004
- van Bokhoven, Jeroen A.; van der Eerden, Ad M. J.; Prins, Roel
- Journal of the American Chemical Society, Vol. 126, Issue 14
Understanding Atom Probe Tomography of Oxide-Supported Metal Nanoparticles by Correlation with Atomic-Resolution Electron Microscopy and Field Evaporation Simulation
journal, March 2014
- Devaraj, Arun; Colby, Robert; Vurpillot, François
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 8
Investigation of the Coordination State of Aluminum in β Zeolites by X-ray Photoelectron Spectroscopy
journal, July 2001
- Collignon, F.; Jacobs, P. A.; Grobet, P.
- The Journal of Physical Chemistry B, Vol. 105, Issue 29
Structure of synthetic zeolite ZSM-5
journal, March 1978
- Kokotailo, G. T.; Lawton, S. L.; Olson, D. H.
- Nature, Vol. 272, Issue 5652
Zoned aluminium distribution in synthetic zeolite ZSM-5
journal, February 1981
- von Ballmoos, R.; Meier, W. M.
- Nature, Vol. 289, Issue 5800
Al K-Edge Near-Edge X-ray Absorption Fine Structure (NEXAFS) Study on the Coordination Structure of Aluminum in Minerals and Y Zeolites
journal, September 1999
- van Bokhoven, J. A.; Sambe, H.; Ramaker, D. E.
- The Journal of Physical Chemistry B, Vol. 103, Issue 36
Morphology-dependent zeolite intergrowth structures leading to distinct internal and outer-surface molecular diffusion barriers
journal, September 2009
- Karwacki, Lukasz; Kox, Marianne H. F.; Matthijs de Winter, D. A.
- Nature Materials, Vol. 8, Issue 12
Influence of Steam Activation on Pore Structure and Acidity of Zeolite Beta: An Al K Edge XANES Study of Aluminum Coordination
journal, October 2002
- van Bokhoven, J.
- Journal of Catalysis, Vol. 211, Issue 2
Intergrowth Structure and Aluminium Zoning of a Zeolite ZSM-5 Crystal as Resolved by Synchrotron-Based Micro X-Ray Diffraction Imaging
journal, October 2013
- Ristanović, Zoran; Hofmann, Jan P.; Deka, Upakul
- Angewandte Chemie International Edition, Vol. 52, Issue 50
3D Nanoscale Chemical Imaging of the Distribution of Aluminum Coordination Environments in Zeolites with Soft X-Ray Microscopy
journal, January 2013
- Aramburo, Luis R.; Liu, Yijin; Tyliszczak, Tolek
- ChemPhysChem, Vol. 14, Issue 3
Crystal Structure of Dehydrated CsZSM-5 (5.8Al): Evidence for Nonrandom Aluminum Distribution †
journal, May 2000
- Olson, David H.; Khosrovani, Nazy; Peters, Alan W.
- The Journal of Physical Chemistry B, Vol. 104, Issue 20
Quantitatively Probing the Al Distribution in Zeolites
journal, May 2014
- Vjunov, Aleksei; Fulton, John L.; Huthwelker, Thomas
- Journal of the American Chemical Society, Vol. 136, Issue 23
Crystal structure and structure-related properties of ZSM-5
journal, July 1981
- Olson, D. H.; Kokotailo, G. T.; Lawton, S. L.
- The Journal of Physical Chemistry, Vol. 85, Issue 15
Detailed Determination of the Tl + Positions in Zeolite Tl−ZSM-5. Single-Crystal Structures of Fully Dehydrated Tl−ZSM-5 and H−ZSM-5 (MFI, Si/Al = 29). Additional Evidence for a Nonrandom Distribution of Framework Aluminum
journal, October 2009
- Heo, Nam Ho; Kim, Cheol Woong; Kwon, Hyeok Jeong
- The Journal of Physical Chemistry C, Vol. 113, Issue 46
In situ site-specific specimen preparation for atom probe tomography
journal, February 2007
- Thompson, K.; Lawrence, D.; Larson, D. J.
- Ultramicroscopy, Vol. 107, Issue 2-3
Intergrowth Structure and Aluminium Zoning of a Zeolite ZSM-5 Crystal as Resolved by Synchrotron-Based Micro X-Ray Diffraction Imaging
journal, October 2013
- Ristanović, Zoran; Hofmann, Jan P.; Deka, Upakul
- Angewandte Chemie International Edition, Vol. 52, Issue 50
Direct Evidence for the Nonrandom Nature of Al Substitution in Zeolite ZSM-5: An Investigation by 27Al MAS and MQ MAS NMR
journal, January 2002
- Han, Oc Hee; Kim, Chang-Sam; Hong, Suk Bong
- Angewandte Chemie International Edition, Vol. 41, Issue 3
Theoretical determination of proton affinity differences in zeolites
journal, April 1993
- Kramer, G. J.; Van Santen, R. A.
- Journal of the American Chemical Society, Vol. 115, Issue 7
Quantitative binomial distribution analyses of nanoscale like‐solute atom clustering and segregation in atom probe tomography data
journal, July 2008
- Moody, Michael P.; Stephenson, Leigh T.; Ceguerra, Anna V.
- Microscopy Research and Technique, Vol. 71, Issue 7
Atom probe tomography
journal, June 2009
- Miller, M. K.; Forbes, R. G.
- Materials Characterization, Vol. 60, Issue 6
Three-Coordinate Aluminum in Zeolites Observed with In situ X-ray Absorption Near-Edge Spectroscopy at the Al K-Edge: Flexibility of Aluminum Coordinations in Zeolites
journal, June 2003
- van Bokhoven, Jeroen A.; van der Eerden, Ad M. J.; Koningsberger, Diek C.
- Journal of the American Chemical Society, Vol. 125, Issue 24
Local Structure of the Zeolitic Catalytically Active Site during Reaction
journal, April 2004
- van Bokhoven, Jeroen A.; van der Eerden, Ad M. J.; Prins, Roel
- Journal of the American Chemical Society, Vol. 126, Issue 14
Where Are the Active Sites in Zeolites? Origin of Aluminum Zoning in ZSM-5
journal, March 2010
- Danilina, Nadiya; Krumeich, Frank; Castelanelli, Stefano A.
- The Journal of Physical Chemistry C, Vol. 114, Issue 14
Dealumination of HZSM-5 zeolites: Effect of steaming on acidity and aromatization activity
journal, June 1997
- de Lucas, Antonio; Canizares, P.; Durán, A.
- Applied Catalysis A: General, Vol. 154, Issue 1-2
The development of strong acidity in hexafluorosilicate-modified Y-type zeolites
journal, August 1992
- Lonyi, F.; Lunsford, J.
- Journal of Catalysis, Vol. 136, Issue 2
Trajectory overlaps and local magnification in three-dimensional atom probe
journal, May 2000
- Vurpillot, F.; Bostel, A.; Blavette, D.
- Applied Physics Letters, Vol. 76, Issue 21
Point process statistics in atom probe tomography
journal, September 2013
- Philippe, T.; Duguay, S.; Grancher, G.
- Ultramicroscopy, Vol. 132
Clustering and nearest neighbour distances in atom-probe tomography
journal, September 2009
- Philippe, T.; De Geuser, F.; Duguay, S.
- Ultramicroscopy, Vol. 109, Issue 10
Controlling the spatial distribution of aluminum in ZSM-5 crystals
journal, June 1993
- Althoff, R.; Schulz-Dobrick, B.; Schüth, F.
- Microporous Materials, Vol. 1, Issue 3
In situ site-specific specimen preparation for atom probe tomography
journal, February 2007
- Thompson, K.; Lawrence, D.; Larson, D. J.
- Ultramicroscopy, Vol. 107, Issue 2-3
Morphology-dependent zeolite intergrowth structures leading to distinct internal and outer-surface molecular diffusion barriers
journal, September 2009
- Karwacki, Lukasz; Kox, Marianne H. F.; Matthijs de Winter, D. A.
- Nature Materials, Vol. 8, Issue 12
Influence of Steam Activation on Pore Structure and Acidity of Zeolite Beta: An Al K Edge XANES Study of Aluminum Coordination
journal, October 2002
- van Bokhoven, J. A.; Koningsberger, D. C.; Kunkeler, P.
- Journal of Catalysis, Vol. 211, Issue 2
X-ray Imaging of Zeolite Particles at the Nanoscale: Influence of Steaming on the State of Aluminum and the Methanol-To-Olefin Reaction
journal, March 2012
- Aramburo, Luis R.; de Smit, Emiel; Arstad, Bjørnar
- Angewandte Chemie, Vol. 124, Issue 15
Quantitatively Probing the Al Distribution in Zeolites
journal, May 2014
- Vjunov, Aleksei; Fulton, John L.; Huthwelker, Thomas
- Journal of the American Chemical Society, Vol. 136, Issue 23
The Porosity, Acidity, and Reactivity of Dealuminated Zeolite ZSM-5 at the Single Particle Level: The Influence of the Zeolite Architecture
journal, November 2011
- Aramburo, Luis R.; Karwacki, Lukasz; Cubillas, Pablo
- Chemistry - A European Journal, Vol. 17, Issue 49
Determining the aluminium occupancy on the active T-sites in zeolites using X-ray standing waves
journal, June 2008
- van Bokhoven, Jeroen A.; Lee, Tien-Lin; Drakopoulos, Michael
- Nature Materials, Vol. 7, Issue 7
Catalytically Active Sites: Generation and Characterization
book, April 2010
- Hunger, Michael
- Zeolites and Catalysis: Synthesis, Reactions and Applications
Aluminum in Zeolites: Where is it and What is its Structure?
book, April 2010
- van Bokhoven, Jeroen A.; Danilina, Nadiya
- Zeolites and Catalysis: Synthesis, Reactions and Applications
Industrial Potential of Zeolites
book, April 2010
- Bellussi, Giuseppe; Carati, ANgela; Millini, Roberto
- Zeolites and Catalysis: Synthesis, Reactions and Applications
Works referencing / citing this record:
Discerning the Location and Nature of Coke Deposition from Surface to Bulk of Spent Zeolite Catalysts
journal, November 2016
- Devaraj, Arun; Vijayakumar, Murugesan; Bao, Jie
- Scientific Reports, Vol. 6, Issue 1
Acidity enhancement through synergy of penta- and tetra-coordinated aluminum species in amorphous silica networks
text, January 2020
- Wang, Zichun; Li, Tong; Jiang, Yijiao
- ETH Zurich
An environmental transfer hub for multimodal atom probe tomography
text, January 2017
- Gerstl, Stephan S. A.; Perea, Daniel E.; Gerstl, Stephan S. A.
- ETH Zurich
Nanoscale Chemical Imaging of Zeolites Using Atom Probe Tomography
journal, July 2018
- Schmidt, Joel E.; Peng, Linqing; Poplawsky, Jonathan D.
- Angewandte Chemie International Edition, Vol. 57, Issue 33
Micro-spectroscopy of HKUST-1 metal–organic framework crystals loaded with tetracyanoquinodimethane: effects of water on host–guest chemistry and electrical conductivity
journal, January 2019
- Rivera-Torrente, Miguel; Filez, Matthias; Schneider, Christian
- Physical Chemistry Chemical Physics, Vol. 21, Issue 46
Acidity enhancement through synergy of penta- and tetra-coordinated aluminum species in amorphous silica networks
journal, January 2020
- Wang, Zichun; Li, Tong; Jiang, Yijiao
- Nature Communications, Vol. 11, Issue 1
Mechanistic insights into aqueous phase propanol dehydration in H-ZSM-5 zeolite
journal, October 2016
- Mei, Donghai; Lercher, Johannes A.
- AIChE Journal, Vol. 63, Issue 1
Effect of Location and Distribution of Al Sites in ZSM-5 on the Formation of Cu-Oxo Clusters Active for Direct Conversion of Methane to Methanol
journal, August 2016
- Markovits, Monica A. C.; Jentys, Andreas; Tromp, Moniek
- Topics in Catalysis, Vol. 59, Issue 17-18
Advances in atom probe tomography instrumentation: Implications for materials research
journal, January 2016
- Moody, Michael P.; Vella, Angela; Gerstl, Stephan S. A.
- MRS Bulletin, Vol. 41, Issue 1
X-ray Excited Optical Fluorescence and Diffraction Imaging of Reactivity and Crystallinity in a Zeolite Crystal: Crystallography and Molecular Spectroscopy in One
journal, May 2016
- Ristanović, Zoran; Hofmann, Jan P.; Richard, Marie-Ingrid
- Angewandte Chemie International Edition, Vol. 55, Issue 26
Decarboxylation of stearic acid over Ni/MOR catalysts
journal, October 2019
- Crawford, James M.; Zaccarine, Sarah F.; Kovach, Nolan C.
- Journal of Chemical Technology & Biotechnology, Vol. 95, Issue 1
Probing the Location and Speciation of Elements in Zeolites with Correlated Atom Probe Tomography and Scanning Transmission X‐Ray Microscopy
journal, October 2018
- Schmidt, Joel E.; Ye, Xinwei; van Ravenhorst, Ilse K.
- ChemCatChem, Vol. 11, Issue 1
Nanoscale Chemical Imaging of Zeolites Using Atom Probe Tomography
journal, July 2018
- Schmidt, Joel E.; Peng, Linqing; Poplawsky, Jonathan D.
- Angewandte Chemie International Edition, Vol. 57, Issue 33
Conversion of Palmitic Acid Over Bi-functional Ni/ZSM-5 Catalyst: Effect of Stoichiometric Ni/Al Molar Ratio
journal, August 2018
- Ojeda, Manuel; Osterman, Nika; Dražić, Goran
- Topics in Catalysis, Vol. 61, Issue 15-17
Nanoscale tomography reveals the deactivation of automotive copper-exchanged zeolite catalysts
journal, November 2017
- Schmidt, Joel E.; Oord, Ramon; Guo, Wei
- Nature Communications, Vol. 8, Issue 1
Atom Probe Tomography for Catalysis Applications: A Review
journal, July 2019
- Barroo, Cédric; Akey, Austin J.; Bell, David C.
- Applied Sciences, Vol. 9, Issue 13
Reversible and Site-Dependent Proton-Transfer in Zeolites Uncovered at the Single-Molecule Level
journal, October 2018
- Ristanović, Zoran; Chowdhury, Abhishek Dutta; Brogaard, Rasmus Y.
- Journal of the American Chemical Society, Vol. 140, Issue 43
In-line three-dimensional holography of nanocrystalline objects at atomic resolution
journal, February 2016
- Chen, F. -R.; Van Dyck, D.; Kisielowski, C.
- Nature Communications, Vol. 7, Issue 1
Coke Formation in a Zeolite Crystal During the Methanol-to-Hydrocarbons Reaction as Studied with Atom Probe Tomography
journal, August 2016
- Schmidt, Joel E.; Poplawsky, Jonathan D.; Mazumder, Baishakhi
- Angewandte Chemie International Edition, Vol. 55, Issue 37
Defining Aluminum-Zoning during Synthesis of ZSM-5 Zeolites
text, January 2020
- Li, Teng; Krumeich, Frank; Chen, Ming
- ETH Zurich
Characterization of Metal‐zeolite Composite Catalysts: Determining the Environment of the Active Phase
journal, April 2020
- Juneau, Mitchell; Liu, Renjie; Peng, Yikang
- ChemCatChem, Vol. 12, Issue 7
Acidity enhancement through synergy of penta- and tetra-coordinated aluminum species in amorphous silica networks
journal, January 2020
- Wang, Zichun; Li, Tong; Jiang, Yijiao
- Nature Communications, Vol. 11, Issue 1
An environmental transfer hub for multimodal atom probe tomography
journal, May 2017
- Perea, Daniel E.; Gerstl, Stephan S. A.; Chin, Jackson
- Advanced Structural and Chemical Imaging, Vol. 3, Issue 1
In-line three-dimensional holography of nanocrystalline objects at atomic resolution
journal, February 2016
- Chen, F. -R.; Van Dyck, D.; Kisielowski, C.
- Nature Communications, Vol. 7, Issue 1
Coke Formation in a Zeolite Crystal During the Methanol-to-Hydrocarbons Reaction as Studied with Atom Probe Tomography
journal, August 2016
- Schmidt, Joel E.; Poplawsky, Jonathan D.; Mazumder, Baishakhi
- Angewandte Chemie International Edition, Vol. 55, Issue 37
Coke Formation in a Zeolite Crystal During the Methanol-to-Hydrocarbons Reaction as Studied with Atom Probe Tomography
journal, August 2016
- Schmidt, Joel E.; Poplawsky, Jonathan D.; Mazumder, Baishakhi
- Angewandte Chemie, Vol. 128, Issue 37
Engineering of Transition Metal Catalysts Confined in Zeolites
journal, May 2018
- Kosinov, Nikolay; Liu, Chong; Hensen, Emiel J. M.
- Chemistry of Materials, Vol. 30, Issue 10
Isolating Clusters of Light Elements in Molecular Sieves with Atom Probe Tomography
journal, June 2018
- Schmidt, Joel E.; Peng, Linqing; Paioni, Alessandra Lucini
- Journal of the American Chemical Society, Vol. 140, Issue 29
Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si/Al lower limit
journal, January 2018
- Pereira, Marcelo Maciel; Gomes, Elisa Silva; Silva, Alessandra Vieira
- Chemical Science, Vol. 9, Issue 31
Electron Tomography: A Unique Tool Solving Intricate Hollow Nanostructures
journal, July 2018
- Song, Hao; Yang, Yannan; Geng, Jing
- Advanced Materials, Vol. 31, Issue 38
Recent trends and fundamental insights in the methanol-to-hydrocarbons process
journal, June 2018
- Yarulina, Irina; Chowdhury, Abhishek Dutta; Meirer, Florian
- Nature Catalysis, Vol. 1, Issue 6
Direct Imaging of Atomically Dispersed Molybdenum that Enables Location of Aluminum in the Framework of Zeolite ZSM‐5
journal, December 2019
- Liu, Lingmei; Wang, Ning; Zhu, Chongzhi
- Angewandte Chemie, Vol. 132, Issue 2
Nanoskalige chemische Bildgebung von Zeolithen durch Atomsondentomographie
journal, June 2018
- Schmidt, Joel E.; Peng, Linqing; Poplawsky, Jonathan D.
- Angewandte Chemie, Vol. 130, Issue 33
Short-range atomic ordering in nonequilibrium silicon-germanium-tin semiconductors
journal, April 2017
- Mukherjee, S.; Kodali, N.; Isheim, D.
- Physical Review B, Vol. 95, Issue 16
Location of Framework Al Atoms in the Channels of ZSM-5: Effect of the (Hydrothermal) Synthesis
journal, February 2016
- Pashkova, Veronika; Sklenak, Stepan; Klein, Petr
- Chemistry - A European Journal, Vol. 22, Issue 12
Three-dimensional nanoscale characterisation of materials by atom probe tomography
journal, November 2016
- Devaraj, Arun; Perea, Daniel E.; Liu, Jia
- International Materials Reviews, Vol. 63, Issue 2
Biomass-mediated ZSM-5 zeolite synthesis: when self-assembly allows to cross the Si/Al lower limit
journal, January 2018
- Pereira, Marcelo Maciel; Gomes, Elisa Silva; Silva, Alessandra Vieira
- Chemical Science, Vol. 9, Issue 31
Kinetic modeling of LPG catalytic cracking using Langmuir–Hinshelwood–Hougen–Watson theory
journal, July 2019
- Abbasizadeh, Saeed; Asadi, Sareh; Karimzadeh, Ramin
- Research on Chemical Intermediates, Vol. 45, Issue 11
Direct Imaging of Atomically Dispersed Molybdenum that Enables Location of Aluminum in the Framework of Zeolite ZSM-5
journal, December 2019
- Liu, Lingmei; Wang, Ning; Zhu, Chongzhi
- Angewandte Chemie International Edition, Vol. 59, Issue 2