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Title: Nanofluid of graphene-based amphiphilic Janus nanosheets for tertiary or enhanced oil recovery: High performance at low concentration

Abstract

Significance Improving crude oil recovery by 1% worldwide would result in a huge amount of crude oil resources becoming available. However, the economic and environmental concerns are too serious to ignore when chemical methods (surfactants or polymers flooding, etc.) are used for an average 10–20% enhancement for tertiary oil recovery. Simple nanofluid (containing only nanoparticles) flooding at low concentration (0.01 wt % or less) is a promising alternative, but the efficiency is below 5% in a saline environment (2 wt % or higher NaCl content). We report a simple nanofluid of graphene-based Janus amphiphilic nanosheets for enhanced oil recovery with efficiency of about 15.2%, comparable to chemical methods, which is both economically and environmentally beneficial to the petroleum industry.

Authors:
 [1];  [2];  [3];  [2];  [2];  [3];  [4];  [3];  [5];  [2]
  1. Department of Physics and Texas Center for Superconductivity, University of Houston, Houston, TX 77204,, Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX 77204,, State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China,
  2. Department of Physics and Texas Center for Superconductivity, University of Houston, Houston, TX 77204,
  3. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan 610500, China,
  4. Department of Chemical and Biomolecular Engineering, University of Houston, Houston, TX 77204,, Departamento de Biotecnología e Ingeniería de Alimentos, Tecnologico de Monterrey, Monterrey, Nuevo Leon 64849, Mexico,
  5. Department of Physics and Texas Center for Superconductivity, University of Houston, Houston, TX 77204,, Lawrence Berkeley National Laboratory, Berkeley, CA 94720
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1259730
Grant/Contract Number:  
FG02-13ER46917; SC0010831
Resource Type:
Published Article
Journal Name:
Proceedings of the National Academy of Sciences of the United States of America
Additional Journal Information:
Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 113 Journal Issue: 28; Journal ID: ISSN 0027-8424
Publisher:
Proceedings of the National Academy of Sciences
Country of Publication:
United States
Language:
English

Citation Formats

Luo, Dan, Wang, Feng, Zhu, Jingyi, Cao, Feng, Liu, Yuan, Li, Xiaogang, Willson, Richard C., Yang, Zhaozhong, Chu, Ching-Wu, and Ren, Zhifeng. Nanofluid of graphene-based amphiphilic Janus nanosheets for tertiary or enhanced oil recovery: High performance at low concentration. United States: N. p., 2016. Web. doi:10.1073/pnas.1608135113.
Luo, Dan, Wang, Feng, Zhu, Jingyi, Cao, Feng, Liu, Yuan, Li, Xiaogang, Willson, Richard C., Yang, Zhaozhong, Chu, Ching-Wu, & Ren, Zhifeng. Nanofluid of graphene-based amphiphilic Janus nanosheets for tertiary or enhanced oil recovery: High performance at low concentration. United States. https://doi.org/10.1073/pnas.1608135113
Luo, Dan, Wang, Feng, Zhu, Jingyi, Cao, Feng, Liu, Yuan, Li, Xiaogang, Willson, Richard C., Yang, Zhaozhong, Chu, Ching-Wu, and Ren, Zhifeng. Mon . "Nanofluid of graphene-based amphiphilic Janus nanosheets for tertiary or enhanced oil recovery: High performance at low concentration". United States. https://doi.org/10.1073/pnas.1608135113.
@article{osti_1259730,
title = {Nanofluid of graphene-based amphiphilic Janus nanosheets for tertiary or enhanced oil recovery: High performance at low concentration},
author = {Luo, Dan and Wang, Feng and Zhu, Jingyi and Cao, Feng and Liu, Yuan and Li, Xiaogang and Willson, Richard C. and Yang, Zhaozhong and Chu, Ching-Wu and Ren, Zhifeng},
abstractNote = {Significance Improving crude oil recovery by 1% worldwide would result in a huge amount of crude oil resources becoming available. However, the economic and environmental concerns are too serious to ignore when chemical methods (surfactants or polymers flooding, etc.) are used for an average 10–20% enhancement for tertiary oil recovery. Simple nanofluid (containing only nanoparticles) flooding at low concentration (0.01 wt % or less) is a promising alternative, but the efficiency is below 5% in a saline environment (2 wt % or higher NaCl content). We report a simple nanofluid of graphene-based Janus amphiphilic nanosheets for enhanced oil recovery with efficiency of about 15.2%, comparable to chemical methods, which is both economically and environmentally beneficial to the petroleum industry.},
doi = {10.1073/pnas.1608135113},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 28,
volume = 113,
place = {United States},
year = {Mon Jun 27 00:00:00 EDT 2016},
month = {Mon Jun 27 00:00:00 EDT 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1073/pnas.1608135113

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Cited by: 160 works
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Works referenced in this record:

Improved Synthesis of Graphene Oxide
journal, July 2010

  • Marcano, Daniela C.; Kosynkin, Dmitry V.; Berlin, Jacob M.
  • ACS Nano, Vol. 4, Issue 8, p. 4806-4814
  • DOI: 10.1021/nn1006368

Janus graphene oxide nanosheets prepared via Pickering emulsion template
journal, November 2015


Metal oxide-based nanoparticles: revealing their potential to enhance oil recovery in different wettability systems
journal, March 2014


Spreading of nanofluids on solids
journal, May 2003


Directed self-assembly of a colloidal kagome lattice
journal, January 2011

  • Chen, Qian; Bae, Sung Chul; Granick, Steve
  • Nature, Vol. 469, Issue 7330
  • DOI: 10.1038/nature09713

Wettability Alteration in Carbonates using Zirconium Oxide Nanofluids: EOR Implications
journal, January 2012

  • Karimi, Ali; Fakhroueian, Zahra; Bahramian, Alireza
  • Energy & Fuels, Vol. 26, Issue 2
  • DOI: 10.1021/ef201475u

Particles as surfactants—similarities and differences
journal, March 2002


Enhancement of surfactant flooding performance by the use of silica nanoparticles
journal, March 2015


Enhanced Oil Recovery (EOR) Using Nanoparticle Dispersions: Underlying Mechanism and Imbibition Experiments
journal, April 2014

  • Zhang, Hua; Nikolov, Alex; Wasan, Darsh
  • Energy & Fuels, Vol. 28, Issue 5
  • DOI: 10.1021/ef500272r

Wettability Alteration of Sandstone Cores by Alumina-Based Nanofluids
journal, June 2013

  • Giraldo, Juliana; Benjumea, Pedro; Lopera, Sergio
  • Energy & Fuels, Vol. 27, Issue 7
  • DOI: 10.1021/ef4002956

Dynamic Spreading of Nanofluids on Solids Part II: Modeling
journal, November 2012

  • Liu, Kuan-Liang; Kondiparty, Kirtiprakash; Nikolov, Alex D.
  • Langmuir, Vol. 28, Issue 47
  • DOI: 10.1021/la302702g

A coreflood investigation of nanofluid enhanced oil recovery
journal, November 2013


Improved Oil Recovery by Nanofluids Flooding: An Experimental Study
conference, April 2013

  • Torsater, Ole; Engeset, Bjernar; Hendraningrat, Luky
  • SPE Kuwait International Petroleum Conference and Exhibition
  • DOI: 10.2118/163335-MS

Film climbing of particle-laden interfaces
journal, February 2008

  • Cheng, Hsin-Ling; Velankar, Sachin S.
  • Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 315, Issue 1-3
  • DOI: 10.1016/j.colsurfa.2007.08.018

Growth of Gold Nanoparticle Films Driven by the Coalescence of Particle-Stabilized Emulsion Drops
journal, April 2006

  • Binks, B. P.; Clint, J. H.; Fletcher, P. D. I.
  • Langmuir, Vol. 22, Issue 9
  • DOI: 10.1021/la052752i

Nanofluids Alter the Surface Wettability of Solids
journal, May 2015


Simple Method to Produce Janus Colloidal Particles in Large Quantity
journal, November 2006

  • Hong, Liang; Jiang, Shan; Granick, Steve
  • Langmuir, Vol. 22, Issue 23
  • DOI: 10.1021/la062716z

Enhancing Oil Recovery of Low-Permeability Berea Sandstone through Optimised Nanofluids Concentration
conference, July 2013

  • Hendraningrat, Luky; Li, Shidong; Torsaeter, Ole
  • SPE Enhanced Oil Recovery Conference
  • DOI: 10.2118/165283-MS

Stabilizing Liquid Drops in Nonequilibrium Shapes by the Interfacial Jamming of Nanoparticles
journal, October 2013


Colloidal Jamming at Interfaces: A Route to Fluid-Bicontinuous Gels
journal, September 2005

  • Stratford, K.; Adhikari, R.; Pagonabarraga, I.
  • Science, Vol. 309, Issue 5744, p. 2198-2201
  • DOI: 10.1126/science.1116589

Preparation and characterization of graphene oxide paper
journal, July 2007

  • Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J.
  • Nature, Vol. 448, Issue 7152, p. 457-460
  • DOI: 10.1038/nature06016

Dynamic Spreading of Nanofluids on Solids. Part I: Experimental
journal, October 2012

  • Kondiparty, Kirtiprakash; Nikolov, Alex D.; Wasan, Darsh
  • Langmuir, Vol. 28, Issue 41
  • DOI: 10.1021/la3027013