High-energy X-ray focusing and applications to pair distribution function investigation of Pt and Au nanoparticles at high pressures
Abstract
We report development of micro-focusing optics for high-energy x-rays by combining a sagittally bent Laue crystal monchromator with Kirkpatrick-Baez (K–B) X-ray focusing mirrors. The optical system is able to provide a clean, high-flux X-ray beam suitable for pair distribution function (PDF) measurements at high pressure using a diamond anvil cell (DAC). A focused beam of moderate size (10–15 μm) has been achieved at energies of 66 and 81keV. PDF data for nanocrystalline platinum (n-Pt) were collected at 12.5 GPa with a single 5 s X-ray exposure, showing that the in-situ compression, decompression, and relaxation behavior of samples in the DAC can be investigated with this technique. PDFs of n-Pt and nano Au (n-Au) under quasi-hydrostatic loading to as high as 71GPa indicate the existence of substantial reduction of grain or domain size for Pt and Au nanoparticles at pressures below 10 GPa. In conclusion, the coupling of sagittally bent Laue crystals with K–B mirrors provides a useful means to focus high-energy synchrotron X-rays from a bending magnet or wiggler source.
- Authors:
-
- Stony Brook Univ., NY (United States). Mineral Physics Institute
- Stony Brook Univ., NY (United States). Mineral Physics Institute; Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Princeton Univ., NJ (United States). Dept. of Geosciences
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1259266
- Grant/Contract Number:
- AC02-98CH10886; NSF EAR 11-57758
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Hong, Xinguo, Ehm, Lars, Zhong, Zhong, Ghose, Sanjit, Duffy, Thomas S., and Weidner, Donald J. High-energy X-ray focusing and applications to pair distribution function investigation of Pt and Au nanoparticles at high pressures. United States: N. p., 2016.
Web. doi:10.1038/srep21434.
Hong, Xinguo, Ehm, Lars, Zhong, Zhong, Ghose, Sanjit, Duffy, Thomas S., & Weidner, Donald J. High-energy X-ray focusing and applications to pair distribution function investigation of Pt and Au nanoparticles at high pressures. United States. https://doi.org/10.1038/srep21434
Hong, Xinguo, Ehm, Lars, Zhong, Zhong, Ghose, Sanjit, Duffy, Thomas S., and Weidner, Donald J. Tue .
"High-energy X-ray focusing and applications to pair distribution function investigation of Pt and Au nanoparticles at high pressures". United States. https://doi.org/10.1038/srep21434. https://www.osti.gov/servlets/purl/1259266.
@article{osti_1259266,
title = {High-energy X-ray focusing and applications to pair distribution function investigation of Pt and Au nanoparticles at high pressures},
author = {Hong, Xinguo and Ehm, Lars and Zhong, Zhong and Ghose, Sanjit and Duffy, Thomas S. and Weidner, Donald J.},
abstractNote = {We report development of micro-focusing optics for high-energy x-rays by combining a sagittally bent Laue crystal monchromator with Kirkpatrick-Baez (K–B) X-ray focusing mirrors. The optical system is able to provide a clean, high-flux X-ray beam suitable for pair distribution function (PDF) measurements at high pressure using a diamond anvil cell (DAC). A focused beam of moderate size (10–15 μm) has been achieved at energies of 66 and 81keV. PDF data for nanocrystalline platinum (n-Pt) were collected at 12.5 GPa with a single 5 s X-ray exposure, showing that the in-situ compression, decompression, and relaxation behavior of samples in the DAC can be investigated with this technique. PDFs of n-Pt and nano Au (n-Au) under quasi-hydrostatic loading to as high as 71GPa indicate the existence of substantial reduction of grain or domain size for Pt and Au nanoparticles at pressures below 10 GPa. In conclusion, the coupling of sagittally bent Laue crystals with K–B mirrors provides a useful means to focus high-energy synchrotron X-rays from a bending magnet or wiggler source.},
doi = {10.1038/srep21434},
journal = {Scientific Reports},
number = ,
volume = 6,
place = {United States},
year = {Tue Feb 23 00:00:00 EST 2016},
month = {Tue Feb 23 00:00:00 EST 2016}
}
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