Ultrafast band engineering and transient spin currents in antiferromagnetic oxides
Abstract
Here, we report a dynamic structure and band engineering strategy with experimental protocols to induce indirect-to-direct band gap transitions and coherently oscillating pure spin-currents in three-dimensional antiferromagnets (AFM) using selective phononic excitations. In the Mott insulator LaTiO3, we show that a photo-induced nonequilibrium phonon mode amplitude destroys the spin and orbitally degenerate ground state, reduces the band gap by 160 meV and renormalizes the carrier masses. The time scale of this process is a few hundreds of femtoseconds. Then in the hole-doped correlated metallic titanate, we show how pure spin-currents can be achieved to yield spin-polarizations exceeding those observed in classic semiconductors. Last, we demonstrate the generality of the approach by applying it to the non-orbitally degenerate AFM CaMnO3. These results advance our understanding of electron-lattice interactions in structures out-of-equilibrium and establish a rational framework for designing dynamic phases that may be exploited in ultrafast optoelectronic and optospintronic devices.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States)
- Publication Date:
- Research Org.:
- Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1257759
- Grant/Contract Number:
- SC0012375
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; electronic properties and materials; electronic structure; ultrafast photonics
Citation Formats
Gu, Mingqiang, and Rondinelli, James M. Ultrafast band engineering and transient spin currents in antiferromagnetic oxides. United States: N. p., 2016.
Web. doi:10.1038/srep25121.
Gu, Mingqiang, & Rondinelli, James M. Ultrafast band engineering and transient spin currents in antiferromagnetic oxides. United States. https://doi.org/10.1038/srep25121
Gu, Mingqiang, and Rondinelli, James M. Fri .
"Ultrafast band engineering and transient spin currents in antiferromagnetic oxides". United States. https://doi.org/10.1038/srep25121. https://www.osti.gov/servlets/purl/1257759.
@article{osti_1257759,
title = {Ultrafast band engineering and transient spin currents in antiferromagnetic oxides},
author = {Gu, Mingqiang and Rondinelli, James M.},
abstractNote = {Here, we report a dynamic structure and band engineering strategy with experimental protocols to induce indirect-to-direct band gap transitions and coherently oscillating pure spin-currents in three-dimensional antiferromagnets (AFM) using selective phononic excitations. In the Mott insulator LaTiO3, we show that a photo-induced nonequilibrium phonon mode amplitude destroys the spin and orbitally degenerate ground state, reduces the band gap by 160 meV and renormalizes the carrier masses. The time scale of this process is a few hundreds of femtoseconds. Then in the hole-doped correlated metallic titanate, we show how pure spin-currents can be achieved to yield spin-polarizations exceeding those observed in classic semiconductors. Last, we demonstrate the generality of the approach by applying it to the non-orbitally degenerate AFM CaMnO3. These results advance our understanding of electron-lattice interactions in structures out-of-equilibrium and establish a rational framework for designing dynamic phases that may be exploited in ultrafast optoelectronic and optospintronic devices.},
doi = {10.1038/srep25121},
journal = {Scientific Reports},
number = ,
volume = 6,
place = {United States},
year = {Fri Apr 29 00:00:00 EDT 2016},
month = {Fri Apr 29 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Control of the electronic phase of a manganite by mode-selective vibrational excitation
journal, September 2007
- Rini, Matteo; Tobey, Ra'anan; Dean, Nicky
- Nature, Vol. 449, Issue 7158
Ultrafast Switching to a Stable Hidden Quantum State in an Electronic Crystal
journal, April 2014
- Stojchevska, L.; Vaskivskyi, I.; Mertelj, T.
- Science, Vol. 344, Issue 6180
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
High-fluence femtosecond laser ablation of silica glass: effects of laser-induced pressure
journal, March 2011
- Hu, Haofeng; Wang, Xiaolei; Zhai, Hongchen
- Journal of Physics D: Applied Physics, Vol. 44, Issue 13
An updated version of wannier90: A tool for obtaining maximally-localised Wannier functions
journal, August 2014
- Mostofi, Arash A.; Yates, Jonathan R.; Pizzi, Giovanni
- Computer Physics Communications, Vol. 185, Issue 8
How chemistry controls electron localization in 3d 1 perovskites: a Wannier-function study
journal, January 2005
- Pavarini, E.; Yamasaki, A.; Nuss, J.
- New Journal of Physics, Vol. 7
Light-Induced Superconductivity in a Stripe-Ordered Cuprate
journal, January 2011
- Fausti, D.; Tobey, R. I.; Dean, N.
- Science, Vol. 331, Issue 6014
First principles phonon calculations in materials science
journal, November 2015
- Togo, Atsushi; Tanaka, Isao
- Scripta Materialia, Vol. 108
Dynamics and Control in Complex Transition Metal Oxides
journal, July 2014
- Zhang, J.; Averitt, R. D.
- Annual Review of Materials Research, Vol. 44, Issue 1
Optically enhanced coherent transport in YBa2Cu3O6.5 by ultrafast redistribution of interlayer coupling
journal, May 2014
- Hu, W.; Kaiser, S.; Nicoletti, D.
- Nature Materials, Vol. 13, Issue 7
Mode-Selective Control of the Crystal Lattice
journal, January 2015
- Först, M.; Mankowsky, R.; Cavalleri, A.
- Accounts of Chemical Research, Vol. 48, Issue 2
Nonlinear lattice dynamics as a basis for enhanced superconductivity in YBa2Cu3O6.5
journal, December 2014
- Mankowsky, R.; Subedi, A.; Först, M.
- Nature, Vol. 516, Issue 7529
Terahertz-field-induced insulator-to-metal transition in vanadium dioxide metamaterial
journal, July 2012
- Liu, Mengkun; Hwang, Harold Y.; Tao, Hu
- Nature, Vol. 487, Issue 7407
Characterisation And Dielectric Property Analysis Of A-Site Doped LaTiO3-Δ Perovskites Synthesised By Ball Milling Method
journal, May 2015
- Madhavan, Bradha
- Advanced Materials Letters, Vol. 6, Issue 5
Hole spin relaxation: optical deformation potential scattering
journal, June 2005
- Dargys, A.
- Semiconductor Science and Technology, Vol. 20, Issue 8
Nonlinear phononics as an ultrafast route to lattice control
journal, August 2011
- Först, M.; Manzoni, C.; Kaiser, S.
- Nature Physics, Vol. 7, Issue 11
Zeeman-type spin splitting controlled by an electric field
journal, July 2013
- Yuan, Hongtao; Bahramy, Mohammad Saeed; Morimoto, Kazuhiro
- Nature Physics, Vol. 9, Issue 9
Electronic Origin of Ultrafast Photoinduced Strain in
journal, January 2013
- Wen, Haidan; Chen, Pice; Cosgriff, Margaret P.
- Physical Review Letters, Vol. 110, Issue 3
Optically induced lattice dynamics probed with ultrafast x-ray diffraction
journal, April 2008
- Lee, H. J.; Workman, J.; Wark, J. S.
- Physical Review B, Vol. 77, Issue 13
Theory of nonlinear phononics for coherent light control of solids
journal, June 2014
- Subedi, Alaska; Cavalleri, Andrea; Georges, Antoine
- Physical Review B, Vol. 89, Issue 22
Driving magnetic order in a manganite by ultrafast lattice excitation
journal, December 2011
- Först, M.; Tobey, R. I.; Wall, S.
- Physical Review B, Vol. 84, Issue 24
Ultrafast Electronic Phase Transition in by Coherent Vibrational Excitation: Evidence for Nonthermal Melting of Orbital Order
journal, November 2008
- Tobey, R. I.; Prabhakaran, D.; Boothroyd, A. T.
- Physical Review Letters, Vol. 101, Issue 19
Melting of Charge Stripes in Vibrationally Driven : Assessing the Respective Roles of Electronic and Lattice Order in Frustrated Superconductors
journal, April 2014
- Först, M.; Tobey, R. I.; Bromberger, H.
- Physical Review Letters, Vol. 112, Issue 15
Coherent modulation of the atomic structure by displacive stimulated ionic Raman scattering
journal, March 2015
- Mankowsky, R.; Först, M.; Loew, T.
- Physical Review B, Vol. 91, Issue 9
Femtosecond multiple-pulse impulsive stimulated Raman scattering spectroscopy
journal, January 1991
- Weiner, A. M.; Wiederrecht, Gary P.; Nelson, Keith A.
- Journal of the Optical Society of America B, Vol. 8, Issue 6, p. 1264-1275
Orbital Ordering and Local Magnetic Properties of Mott-Hubbard Insulators YTiO 3 and LaTiO 3 : NMR Study
journal, August 1999
- Itoh, Masayuki; Tsuchiya, Michitoshi; Tanaka, Hirotaka
- Journal of the Physical Society of Japan, Vol. 68, Issue 8
Magnetic structure of the Jahn-Teller system
journal, April 2005
- Schmitz, Robert; Entin-Wohlman, Ora; Aharony, Amnon
- Physical Review B, Vol. 71, Issue 14
Jahn-Teller distortion and magnetic structures in
journal, November 1997
- Sawada, H.; Morikawa, Y.; Terakura, K.
- Physical Review B, Vol. 56, Issue 19
Electronic transition in
journal, October 1999
- Hays, C. C.; Zhou, J. -S.; Markert, J. T.
- Physical Review B, Vol. 60, Issue 14
Theory of Spin-Dependent Phonon-Assisted Optical Transitions in Silicon
journal, July 2010
- Li, Pengke; Dery, Hanan
- Physical Review Letters, Vol. 105, Issue 3
Generating coherent THz phonons with light pulses
journal, April 1997
- Merlin, R.
- Solid State Communications, Vol. 102, Issue 2-3
Optical spectra in (La,Y) : Variation of Mott-Hubbard gap features with change of electron correlation and band filling
journal, April 1995
- Okimoto, Y.; Katsufuji, T.; Okada, Y.
- Physical Review B, Vol. 51, Issue 15
Mott Transition and Suppression of Orbital Fluctuations in Orthorhombic Perovskites
journal, April 2004
- Pavarini, E.; Biermann, S.; Poteryaev, A.
- Physical Review Letters, Vol. 92, Issue 17
Structural phase transitions of the metal oxide perovskites SrTiO , LaAlO , and LaTiO studied with a screened hybrid functional
journal, January 2013
- El-Mellouhi, Fedwa; Brothers, Edward N.; Lucero, Melissa J.
- Physical Review B, Vol. 87, Issue 3
Assessing the Perdew-Burke-Ernzerhof exchange-correlation density functional revised for metallic bulk and surface systems
journal, May 2008
- Ropo, M.; Kokko, K.; Vitos, L.
- Physical Review B, Vol. 77, Issue 19
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Projector augmented-wave method
journal, December 1994
- Blöchl, P. E.
- Physical Review B, Vol. 50, Issue 24, p. 17953-17979
Maximally localized generalized Wannier functions for composite energy bands
journal, November 1997
- Marzari, Nicola; Vanderbilt, David
- Physical Review B, Vol. 56, Issue 20
Correlation effects in the ground-state charge density of Mott insulating NiO: A comparison of ab initio calculations and high-energy electron diffraction measurements
journal, January 2000
- Dudarev, S. L.; Peng, L. -M.; Savrasov, S. Y.
- Physical Review B, Vol. 61, Issue 4
versus all 3 d localization in La M perovskites ( M =Ti–Cu): First-principles study
journal, March 1996
- Solovyev, Igor; Hamada, Noriaki; Terakura, Kiyoyuki
- Physical Review B, Vol. 53, Issue 11
Spin-phonon coupling effects in transition-metal perovskites: A DFT + and hybrid-functional study
journal, February 2012
- Hong, Jiawang; Stroppa, Alessandro; Íñiguez, Jorge
- Physical Review B, Vol. 85, Issue 5
Raman scattering in the family of Mott-Hubbard insulators
journal, January 1997
- Reedyk, M.; Crandles, D. A.; Cardona, M.
- Physical Review B, Vol. 55, Issue 3
Dielectric properties and dynamical conductivity of From dc to optical frequencies
journal, December 2003
- Lunkenheimer, P.; Rudolf, T.; Hemberger, J.
- Physical Review B, Vol. 68, Issue 24
Laser Excitation of Lattice-Driven Anharmonic Magnetization Dynamics in Dielectric
journal, April 2014
- Afanasiev, D.; Razdolski, I.; Skibinsky, K. M.
- Physical Review Letters, Vol. 112, Issue 14
Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021
- Chen, Ruyi; Cui, Qirui; Liao, Liyang
- Nature Communications, Vol. 12, Issue 1
High-resolution X-ray luminescence extension imaging
journal, February 2021
- Ou, Xiangyu; Qin, Xian; Huang, Bolong
- Nature, Vol. 590, Issue 7846
Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020
- Tatemizo, Nobuyuki; Imada, Saki; Okahara, Kizuna
- Scientific Reports, Vol. 10, Issue 1
Optically induced lattice dynamics probed with ultrafast X-ray diffraction
conference, January 2005
- Lee, H. J.; Workman, J. B.; Averitt, R. D.
- 2005 Quantum Electronics and Laser Science Conference (QELS)
Silicon Spintronics
journal, December 2008
- Appelbaum, Ian
- International Journal of High Speed Electronics and Systems, Vol. 18, Issue 04
Silicon spintronics
conference, March 2009
- Appelbaum, Ian
- 2009 10th International Conference on Ultimate Integration on Silicon (ULIS, 2009 10th International Conference on Ultimate Integration of Silicon
Spin-phonon coupling effects in transition-metal perovskites:a DFT+$U$ and hybrid-functional study
text, January 2011
- Hong, Jiawang; Stroppa, Alessandro; Íñiguez, Jorge
- arXiv
Structural Phase Transitions of the Metal Oxide Perovskites SrTiO3, LaAlO3 and LaTiO3 Studied with a Screened Hybrid Functional
text, January 2012
- El-Mellouhi, Fedwa; Brothers, Edward N.; Lucero, Melissa J.
- arXiv
Optically enhanced coherent transport in YBa2Cu3O6.5 by ultrafast redistribution of interlayer coupling
text, January 2013
- Hu, W.; Kaiser, S.; Nicoletti, D.
- arXiv
Theory of nonlinear phononics for coherent light-control of solids
text, January 2013
- Subedi, Alaska; Cavalleri, Andrea; Georges, Antoine
- arXiv
First principles phonon calculations in materials science
preprint, January 2015
- Togo, Atsushi; Tanaka, Isao
- arXiv
The magnetic structure of the Jahn-Teller System LaTiO3
text, January 2004
- Schmitz, Robert; Entin-Wohlman, Ora; Aharony, Amnon
- arXiv
How chemistry controls electron localization in 3d1 perovskites: A Wannier-function study
text, January 2005
- Pavarini, E.; Yamasaki, A.; Nuss, J.
- arXiv
Silicon Spintronics
conference, October 2009
- Jansen, R.
- Extended Abstracts of the 2009 International Conference on Solid State Devices and Materials
Mode-Selective Control of the Crystal Lattice
journal, January 2015
- Först, M.; Mankowsky, R.; Cavalleri, A.
- Accounts of Chemical Research, Vol. 48, Issue 2
Control of the electronic phase of a manganite by mode-selective vibrational excitation
journal, September 2007
- Rini, Matteo; Tobey, Ra'anan; Dean, Nicky
- Nature, Vol. 449, Issue 7158
Terahertz-field-induced insulator-to-metal transition in vanadium dioxide metamaterial
journal, July 2012
- Liu, Mengkun; Hwang, Harold Y.; Tao, Hu
- Nature, Vol. 487, Issue 7407
Hole spin relaxation: optical deformation potential scattering
journal, June 2005
- Dargys, A.
- Semiconductor Science and Technology, Vol. 20, Issue 8
Light-Induced Superconductivity in a Stripe-Ordered Cuprate
journal, January 2011
- Fausti, D.; Tobey, R. I.; Dean, N.
- Science, Vol. 331, Issue 6014
Ultrafast Switching to a Stable Hidden Quantum State in an Electronic Crystal
journal, April 2014
- Stojchevska, L.; Vaskivskyi, I.; Mertelj, T.
- Science, Vol. 344, Issue 6180
Normal Mode Determination of Perovskite Crystal Structures with Octahedral Rotations: Theory and Applications
text, January 2012
- Islam, Mohammad A.; Rondinelli, James M.; Spanier, Jonathan E.
- arXiv
Nonlinear lattice dynamics as a basis for enhanced superconductivity in YBa2Cu3O6.5
text, January 2014
- Mankowsky, R.; Subedi, A.; Först, M.
- arXiv
Melting of Charge Stripes in Vibrationally Driven La1.875Ba0.125CuO4: Assessing the Respective Roles of Electronic and Lattice Order in Frustrated Superconductors
text, January 2014
- Först, M.; Tobey, R. I.; Bromberger, H.
- arXiv
Dielectric properties and dynamical conductivity of LaTiO3: From dc to optical frequencies
text, January 2003
- Lunkenheimer, P.; Rudolf, T.; Hemberger, J.
- arXiv
Works referencing / citing this record:
Impact ionization dynamics in small band-gap two-dimensional materials from a coherent phonon mechanism
journal, July 2019
- Michael, Stephan; Schneider, Hans Christian
- Physical Review B, Vol. 100, Issue 3