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Title: Optimization of strength and ductility in nanotwinned ultrafine grained Ag: twin density and grain orientations

Abstract

Nanotwinned ultrafine grained Ag thick films with different twin densities and orientations have been synthesized by magnetron sputtering with a wide-range of deposition rates. The twin boundary (TB) spacings and orientations as well as the grain size for the different deposition conditions have been characterized by both synchrotron X-ray scattering and transmission electron microscopy (TEM). Structural characterization combined with uniaxial tensile tests of the free-standing films reveals a large increase in the yield strength for films deposited at high deposition rates without any accompanying change in the TB spacing – a behavior that is in contrast with what has been reported in the literature. We find that films deposited at lower deposition rates exhibit more randomly oriented grains with a lower overall twin density (averaged over all the grains) than the more heavily twinned grains with strong <111> fiber texture in the films deposited at higher deposition rates. The TB spacing in the twinned grains, however, does not show any significant dependence on the deposition rate. The dependence of the strength and ductility on the twin density and orientations can be described by two different soft deformation modes: 1) untwinned grains and 2) nanowinned grains that are not oriented withmore » <111> along the growth direction. The untwinned grains provide relatively low resistance to slip, and thus decreased strength, while the nanotwinned grains that are not oriented with <111> along the growth direction are softer than nanotwinned grains that are oriented with <111> along the growth direction. We reveal that an ultrafine-grained (150-200 nm) structure consisting of a mixture of nanotwinned (~ 8-12 nm spacing) and untwined grains yields the best combination of high strength and uniform tensile ductility.« less

Authors:
 [1];  [1];  [1];  [2];  [3];  [1];  [2];  [1]
  1. Ames Lab., Ames, IA (United States)
  2. Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
  3. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1257296
Alternate Identifier(s):
OSTI ID: 1251848
Report Number(s):
LLNL-JRNL-694384
Journal ID: ISSN 1359-6454
Grant/Contract Number:  
AC52-07NA27344; AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
Acta Materialia
Additional Journal Information:
Journal Volume: 96; Journal ID: ISSN 1359-6454
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Ott, R. T., Geng, J., Besser, M. F., Kramer, M. J., Wang, Y. M., Park, E. S., LeSar, R., and King, A. H. Optimization of strength and ductility in nanotwinned ultrafine grained Ag: twin density and grain orientations. United States: N. p., 2015. Web. doi:10.1016/j.actamat.2015.06.030.
Ott, R. T., Geng, J., Besser, M. F., Kramer, M. J., Wang, Y. M., Park, E. S., LeSar, R., & King, A. H. Optimization of strength and ductility in nanotwinned ultrafine grained Ag: twin density and grain orientations. United States. https://doi.org/10.1016/j.actamat.2015.06.030
Ott, R. T., Geng, J., Besser, M. F., Kramer, M. J., Wang, Y. M., Park, E. S., LeSar, R., and King, A. H. Sat . "Optimization of strength and ductility in nanotwinned ultrafine grained Ag: twin density and grain orientations". United States. https://doi.org/10.1016/j.actamat.2015.06.030. https://www.osti.gov/servlets/purl/1257296.
@article{osti_1257296,
title = {Optimization of strength and ductility in nanotwinned ultrafine grained Ag: twin density and grain orientations},
author = {Ott, R. T. and Geng, J. and Besser, M. F. and Kramer, M. J. and Wang, Y. M. and Park, E. S. and LeSar, R. and King, A. H.},
abstractNote = {Nanotwinned ultrafine grained Ag thick films with different twin densities and orientations have been synthesized by magnetron sputtering with a wide-range of deposition rates. The twin boundary (TB) spacings and orientations as well as the grain size for the different deposition conditions have been characterized by both synchrotron X-ray scattering and transmission electron microscopy (TEM). Structural characterization combined with uniaxial tensile tests of the free-standing films reveals a large increase in the yield strength for films deposited at high deposition rates without any accompanying change in the TB spacing – a behavior that is in contrast with what has been reported in the literature. We find that films deposited at lower deposition rates exhibit more randomly oriented grains with a lower overall twin density (averaged over all the grains) than the more heavily twinned grains with strong <111> fiber texture in the films deposited at higher deposition rates. The TB spacing in the twinned grains, however, does not show any significant dependence on the deposition rate. The dependence of the strength and ductility on the twin density and orientations can be described by two different soft deformation modes: 1) untwinned grains and 2) nanowinned grains that are not oriented with <111> along the growth direction. The untwinned grains provide relatively low resistance to slip, and thus decreased strength, while the nanotwinned grains that are not oriented with <111> along the growth direction are softer than nanotwinned grains that are oriented with <111> along the growth direction. We reveal that an ultrafine-grained (150-200 nm) structure consisting of a mixture of nanotwinned (~ 8-12 nm spacing) and untwined grains yields the best combination of high strength and uniform tensile ductility.},
doi = {10.1016/j.actamat.2015.06.030},
journal = {Acta Materialia},
number = ,
volume = 96,
place = {United States},
year = {Sat Jun 27 00:00:00 EDT 2015},
month = {Sat Jun 27 00:00:00 EDT 2015}
}

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