Fe2O3–TiO2 core–shell nanorod arrays for visible light photocatalytic applications
Abstract
By using the glancing angle deposition technique and post-deposition annealing, Fe2O3–TiO2 core-shell nanorod arrays with specific crystalline states can be designed and fabricated. The Fe2O3–TiO2 core-shell samples annealed at temperatures greater than 450°C formed α-Fe2O3 and anatase TiO2, and showed higher catalytic efficiency for the degradation of methylene blue (MB) under visible light illumination when compared with pure anatase TiO2 or α-Fe2O3 nanorod arrays. Solar conversion of carbon dioxide and water vapor in the presence of Fe2O3–TiO2 core-shell nanorod arrays was also investigated. Carbon monoxide, hydrogen, methane, and methanol along with other hydrocarbons were produced after only several hours’ exposure under ambient sunlight. It was determined that the core-shell structure showed greater efficiency for solar CO2 conversion than the pure TiO2 nanorod arrays.
- Authors:
-
- Univ. of Georgia, Athens, GA (United States)
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Georgia Regents Univ, Augusta, GA (United States)
- Publication Date:
- Research Org.:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1254431
- Alternate Identifier(s):
- OSTI ID: 1373342
- Report Number(s):
- SRNL-STI-2015-00609
Journal ID: ISSN 0920-5861; PII: S0920586115006847
- Grant/Contract Number:
- AC09-08SR22470
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Today
- Additional Journal Information:
- Journal Volume: 270; Journal Issue: C; Journal ID: ISSN 0920-5861
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Glancing angle deposition; nanorod arrays; core-shell Fe2O3-TiO2.
Citation Formats
Yao, Kun, Basnet, Pradip, Sessions, Henry, Larsen, George K., Murph, Simona E. Hunyadi, and Zhao, Yiping. Fe2O3–TiO2 core–shell nanorod arrays for visible light photocatalytic applications. United States: N. p., 2015.
Web. doi:10.1016/j.cattod.2015.10.026.
Yao, Kun, Basnet, Pradip, Sessions, Henry, Larsen, George K., Murph, Simona E. Hunyadi, & Zhao, Yiping. Fe2O3–TiO2 core–shell nanorod arrays for visible light photocatalytic applications. United States. https://doi.org/10.1016/j.cattod.2015.10.026
Yao, Kun, Basnet, Pradip, Sessions, Henry, Larsen, George K., Murph, Simona E. Hunyadi, and Zhao, Yiping. Wed .
"Fe2O3–TiO2 core–shell nanorod arrays for visible light photocatalytic applications". United States. https://doi.org/10.1016/j.cattod.2015.10.026. https://www.osti.gov/servlets/purl/1254431.
@article{osti_1254431,
title = {Fe2O3–TiO2 core–shell nanorod arrays for visible light photocatalytic applications},
author = {Yao, Kun and Basnet, Pradip and Sessions, Henry and Larsen, George K. and Murph, Simona E. Hunyadi and Zhao, Yiping},
abstractNote = {By using the glancing angle deposition technique and post-deposition annealing, Fe2O3–TiO2 core-shell nanorod arrays with specific crystalline states can be designed and fabricated. The Fe2O3–TiO2 core-shell samples annealed at temperatures greater than 450°C formed α-Fe2O3 and anatase TiO2, and showed higher catalytic efficiency for the degradation of methylene blue (MB) under visible light illumination when compared with pure anatase TiO2 or α-Fe2O3 nanorod arrays. Solar conversion of carbon dioxide and water vapor in the presence of Fe2O3–TiO2 core-shell nanorod arrays was also investigated. Carbon monoxide, hydrogen, methane, and methanol along with other hydrocarbons were produced after only several hours’ exposure under ambient sunlight. It was determined that the core-shell structure showed greater efficiency for solar CO2 conversion than the pure TiO2 nanorod arrays.},
doi = {10.1016/j.cattod.2015.10.026},
journal = {Catalysis Today},
number = C,
volume = 270,
place = {United States},
year = {Wed Nov 11 00:00:00 EST 2015},
month = {Wed Nov 11 00:00:00 EST 2015}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 36 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Hydrogen Produced from Hydrohalic Acid Solutions by a Two-Electron Mixed-Valence Photocatalyst
journal, August 2001
- Heyduk, A. F.
- Science, Vol. 293, Issue 5535
Toward Solar Fuels: Photocatalytic Conversion of Carbon Dioxide to Hydrocarbons
journal, February 2010
- Roy, Somnath C.; Varghese, Oomman K.; Paulose, Maggie
- ACS Nano, Vol. 4, Issue 3
Visible-light driven heterojunction photocatalysts for water splitting – a critical review
journal, January 2015
- Moniz, Savio J. A.; Shevlin, Stephen A.; Martin, David James
- Energy & Environmental Science, Vol. 8, Issue 3
Manipulation of Charge Transfer Across Semiconductor Interface. A Criterion That Cannot Be Ignored in Photocatalyst Design
journal, February 2012
- Kamat, Prashant V.
- The Journal of Physical Chemistry Letters, Vol. 3, Issue 5
Plasmonic photocatalysis
journal, March 2013
- Zhang, Xuming; Chen, Yu Lim; Liu, Ru-Shi
- Reports on Progress in Physics, Vol. 76, Issue 4
Nitrogen-Doped Titanium Dioxide as Visible-Light-Sensitive Photocatalyst: Designs, Developments, and Prospects
journal, May 2014
- Asahi, Ryoji; Morikawa, Takeshi; Irie, Hiroshi
- Chemical Reviews, Vol. 114, Issue 19
Highly active Fe2O3-doped TiO2 photocatalyst for degradation of trichloroethylene in air under UV and visible light irradiation: Experimental and computational studies
journal, April 2015
- Banisharif, Alireza; Khodadadi, Abbas Ali; Mortazavi, Yadollah
- Applied Catalysis B: Environmental, Vol. 165
Semiconductor-based photocatalysts and photoelectrochemical cells for solar fuel generation: a review
journal, January 2015
- Li, Jiangtian; Wu, Nianqiang
- Catalysis Science & Technology, Vol. 5, Issue 3
Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972
- Fujishima, Akira; Honda, Kenichi
- Nature, Vol. 238, Issue 5358, p. 37-38
Ethanol Photocatalysis on TiO 2 -Coated Optical Microfiber, Supported Monolayer, and Powdered Catalysts: An in Situ NMR Study
journal, December 1999
- Pilkenton, Sarah; Hwang, Son-Jong; Raftery, Daniel
- The Journal of Physical Chemistry B, Vol. 103, Issue 50
Photocatalytic reduction of carbon dioxide into gaseous hydrocarbon using TiO2 pellets
journal, June 2006
- Tan, Seng Sing; Zou, Linda; Hu, Eric
- Catalysis Today, Vol. 115, Issue 1-4, p. 269-273
High-Rate Solar Photocatalytic Conversion of CO 2 and Water Vapor to Hydrocarbon Fuels
journal, February 2009
- Varghese, Oomman K.; Paulose, Maggie; LaTempa, Thomas J.
- Nano Letters, Vol. 9, Issue 2
Quasi-core-shell TiO2/WO3 and WO3/TiO2 nanorod arrays fabricated by glancing angle deposition for solar water splitting
journal, January 2011
- Smith, Wilson; Wolcott, Abraham; Fitzmorris, Robert Carl
- Journal of Materials Chemistry, Vol. 21, Issue 29
Hybrid CuO-TiO2−xNx Hollow Nanocubes for Photocatalytic Conversion of CO2 into Methane under Solar Irradiation
journal, March 2012
- In, Su-Il; Vaughn, Dimitri D.; Schaak, Raymond E.
- Angewandte Chemie International Edition, Vol. 51, Issue 16
Robust Hollow Spheres Consisting of Alternating Titania Nanosheets and Graphene Nanosheets with High Photocatalytic Activity for CO2 Conversion into Renewable Fuels
journal, January 2012
- Tu, Wenguang; Zhou, Yong; Liu, Qi
- Advanced Functional Materials, Vol. 22, Issue 6
Enhancement of Sunlight Photocatalysis of Nano TiO2 by Ag Nanoparticles Stabilized with D-Glucosamine
journal, February 2011
- Thomas, Jesty; Kumar, K. Praveen; Mathew, Suresh
- Science of Advanced Materials, Vol. 3, Issue 1
Enhanced Photocatalytic Activity by Aligned WO 3 /TiO 2 Two-Layer Nanorod Arrays
journal, November 2008
- Smith, Wilson; Zhao, Yiping
- The Journal of Physical Chemistry C, Vol. 112, Issue 49
Improved photocatalytic activity and mechanism of Cu2O/N–TiO2 prepared by a two-step method
journal, January 2014
- Luo, Zhengwei; Jiang, Hui; Li, Dan
- RSC Advances, Vol. 4, Issue 34
Synergistic Effects of B/N Doping on the Visible-Light Photocatalytic Activity of Mesoporous TiO2
journal, June 2008
- Liu, Gang; Zhao, Yanning; Sun, Chenghua
- Angewandte Chemie International Edition, Vol. 47, Issue 24
Janus Au-TiO 2 Photocatalysts with Strong Localization of Plasmonic Near-Fields for Efficient Visible-Light Hydrogen Generation
journal, March 2012
- Seh, Zhi Wei; Liu, Shuhua; Low, Michelle
- Advanced Materials, Vol. 24, Issue 17
The photocatalytic activity and photo-absorption of plasma sprayed TiO2–Fe3O4 binary oxide coatings
journal, October 2002
- Ye, Fuxing; Ohmori, Akira
- Surface and Coatings Technology, Vol. 160, Issue 1
Preparation and characterization of visible light responsive Fe2O3–TiO2 composites
journal, April 2011
- Liu, Hong; Shon, H. K.; Sun, Xuan
- Applied Surface Science, Vol. 257, Issue 13
Morphological, optical and photocatalytic properties of TiO2–Fe2O3 multilayers
journal, September 2007
- Sánchez Mora, Enrique; Gómez Barojas, Estela; Rojas Rojas, Esmeralda
- Solar Energy Materials and Solar Cells, Vol. 91, Issue 15-16
One-dimensional mesoporous Fe2O3@TiO2 core–shell nanocomposites: Rational design, synthesis and application as high-performance photocatalyst in visible and UV light region
journal, October 2014
- Zhang, Xiao; Xie, Yaping; Chen, Haoxin
- Applied Surface Science, Vol. 317
Preparation and Properties of Nanocrystalline alpha-Fe2O3-Sensitized TiO2 Nanosheets as a Visible Light Photocatalyst
journal, January 2006
- Liu, Hongyan; Gao, Lian
- Journal of the American Ceramic Society, Vol. 89, Issue 1
Core–shell structured α-Fe2O3@TiO2 nanocomposites with improved photocatalytic activity in the visible light region
journal, January 2013
- Xia, Yubing; Yin, Longwei
- Physical Chemistry Chemical Physics, Vol. 15, Issue 42
Synthesis, photoelectric properties and photocatalytic activity of the Fe2O3/TiO2 heterogeneous photocatalysts
journal, January 2010
- Peng, Linlin; Xie, Tengfeng; Lu, Yongchun
- Physical Chemistry Chemical Physics, Vol. 12, Issue 28
Recent progress in magnetic iron oxide–semiconductor composite nanomaterials as promising photocatalysts
journal, January 2015
- Wu, Wei; Changzhong Jiang, Changzhong Jiang; Roy, Vellaisamy A. L.
- Nanoscale, Vol. 7, Issue 1
Designing nanostructures by glancing angle deposition
conference, October 2003
- Zhao, Yiping; Ye, Dexian; Wang, Gwo-Ching
- Optical Science and Technology, SPIE's 48th Annual Meeting, SPIE Proceedings
Glancing angle deposition: Fabrication, properties, and applications of micro- and nanostructured thin films
journal, January 2007
- Hawkeye, Matthew M.; Brett, Michael J.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 25, Issue 5, Article No. 1317
Superior dye adsorption capacity of amorphous WO 3 sub-micrometer rods fabricated by glancing angle deposition
journal, January 2014
- Basnet, Pradip; Zhao, Yiping
- J. Mater. Chem. A, Vol. 2, Issue 4
Superior photocatalytic performance by vertically aligned core–shell TiO2/WO3 nanorod arrays
journal, March 2009
- Smith, W.; Zhao, Y. -P.
- Catalysis Communications, Vol. 10, Issue 7
Dynamic Shadowing Growth and Its Energy Applications
journal, September 2014
- Zhao, Yiping
- Frontiers in Energy Research, Vol. 2
Flux Engineering To Control In-Plane Crystal and Morphological Orientation
journal, June 2012
- LaForge, Joshua M.; Ingram, Grayson L.; Taschuk, Michael T.
- Crystal Growth & Design, Vol. 12, Issue 7
Fe2O3 single crystals: hydrothermal growth, crystal chemistry and growth morphology
journal, November 2003
- Demianets, L. N.; Pouchko, S. V.; Gaynutdinov, R. V.
- Journal of Crystal Growth, Vol. 259, Issue 1-2
α-Fe 2 O 3 Nanocolumns and Nanorods Fabricated by Electron Beam Evaporation for Visible Light Photocatalytic and Antimicrobial Applications
journal, March 2013
- Basnet, Pradip; Larsen, George K.; Jadeja, Ravirajsinh P.
- ACS Applied Materials & Interfaces, Vol. 5, Issue 6
High Optical Absorption of Indium Sulfide Nanorod Arrays Formed by Glancing Angle Deposition
journal, February 2010
- Cansizoglu, Mehmet F.; Engelken, Robert; Seo, Hye-Won
- ACS Nano, Vol. 4, Issue 2
Optical properties of iron oxide (α-Fe2O3) thin films deposited by the reactive evaporation of iron
journal, April 2012
- Al-Kuhaili, M. F.; Saleem, M.; Durrani, S. M. A.
- Journal of Alloys and Compounds, Vol. 521
Photocatalytic oxygen evolution on α-Fe2O3 films using Fe3+ ion as a sacrificial oxidizing agent
journal, January 2000
- Ohmori, T.; Takahashi, H.; Mametsuka, H.
- Physical Chemistry Chemical Physics, Vol. 2, Issue 15
Oxidative Power of Nitrogen-Doped TiO 2 Photocatalysts under Visible Illumination
journal, November 2004
- Mrowetz, Marta; Balcerski, William; Colussi, A. J.
- The Journal of Physical Chemistry B, Vol. 108, Issue 45
Substrate versus oxidant activation in RuIII(edta) catalyzed dye degradation
journal, January 2013
- Chatterjee, Debabrata; Rothbart, Sabine; van Eldik, Rudi
- RSC Advances, Vol. 3, Issue 11
Pt/titania-nanotube: A potential catalyst for CO2 adsorption and hydrogenation
journal, October 2008
- Yu, Kuo-Pin; Yu, Wen-Yueh; Kuo, Ming-Chih
- Applied Catalysis B: Environmental, Vol. 84, Issue 1-2
Ag Nanoparticle Embedded TiO 2 Composite Nanorod Arrays Fabricated by Oblique Angle Deposition: Toward Plasmonic Photocatalysis
journal, November 2013
- He, Yizhuo; Basnet, Pradip; Murph, Simona E. Hunyadi
- ACS Applied Materials & Interfaces, Vol. 5, Issue 22
Works referencing / citing this record:
Controlled synthesis of Bi 2 O 3 /TiO 2 catalysts with mixed alcohols for the photocatalytic oxidation of HCHO
journal, February 2018
- Huang, Qiong; Wang, Qiu; Tao, Tao
- Environmental Technology, Vol. 40, Issue 15
Dual modification of TiNb 2 O 7 with nitrogen dopants and oxygen vacancies for selective aerobic oxidation of benzylamine to imine under green light
journal, January 2017
- Yu, Zhuobin; Waclawik, Eric R.; Wang, Zhijian
- Journal of Materials Chemistry A, Vol. 5, Issue 9
Shape Controlled Synthesis of Copper Vanadate Platelet Nanostructures, Their Optical Band Edges, and Solar-Driven Water Splitting Properties
journal, October 2017
- Khan, Ibrahim; Qurashi, Ahsanulhaq
- Scientific Reports, Vol. 7, Issue 1