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This content will become publicly available on December 15, 2016

Title: Quantitative structure parameters from the NMR spectroscopy of quadrupolar nuclei

Here, nuclear magnetic resonance (NMR) spectroscopy is one of the most important characterization tools in chemistry, however, 3/4 of the NMR active nuclei are underutilized due to their quadrupolar nature. This short review centers on the development of methods that use solid-state NMR of quadrupolar nuclei for obtaining quantitative structural information. Namely, techniques using dipolar recoupling as well as the resolution afforded by double-rotation are presented for the measurement of spin–spin coupling between quadrupoles, enabling the measurement of internuclear distances and connectivities.
Authors:
 [1]
  1. Ames Lab., Ames, IA (United States)
Publication Date:
OSTI Identifier:
1253765
Report Number(s):
IS-J--8951
Journal ID: ISSN 0033-4545
Grant/Contract Number:
AC02-07CH11358
Type:
Accepted Manuscript
Journal Name:
Pure and Applied Chemistry
Additional Journal Information:
Journal Volume: 88; Journal Issue: 1-2; Journal ID: ISSN 0033-4545
Publisher:
IUPAC
Research Org:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org:
USDOE
Country of Publication:
United States
Language:
English
Subject:
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY crystal structure refinements; dipolar coupling; IUPAC-SOLVAY International Award for Young Chemists; J coupling; NMR crystallography; NMR spectroscopy; quadrupolar nuclei; solid-state NMR