Quantitative structure parameters from the NMR spectroscopy of quadrupolar nuclei
Abstract
Here, nuclear magnetic resonance (NMR) spectroscopy is one of the most important characterization tools in chemistry, however, 3/4 of the NMR active nuclei are underutilized due to their quadrupolar nature. This short review centers on the development of methods that use solid-state NMR of quadrupolar nuclei for obtaining quantitative structural information. Namely, techniques using dipolar recoupling as well as the resolution afforded by double-rotation are presented for the measurement of spin–spin coupling between quadrupoles, enabling the measurement of internuclear distances and connectivities.
- Authors:
-
- Ames Lab., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1253765
- Report Number(s):
- IS-J-8951
Journal ID: ISSN 0033-4545
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Pure and Applied Chemistry
- Additional Journal Information:
- Journal Volume: 88; Journal Issue: 1-2; Journal ID: ISSN 0033-4545
- Publisher:
- IUPAC
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; crystal structure refinements; dipolar coupling; IUPAC-SOLVAY International Award for Young Chemists; J coupling; NMR crystallography; NMR spectroscopy; quadrupolar nuclei; solid-state NMR
Citation Formats
Perras, Frederic A. Quantitative structure parameters from the NMR spectroscopy of quadrupolar nuclei. United States: N. p., 2015.
Web. doi:10.1515/pac-2015-0801.
Perras, Frederic A. Quantitative structure parameters from the NMR spectroscopy of quadrupolar nuclei. United States. https://doi.org/10.1515/pac-2015-0801
Perras, Frederic A. Tue .
"Quantitative structure parameters from the NMR spectroscopy of quadrupolar nuclei". United States. https://doi.org/10.1515/pac-2015-0801. https://www.osti.gov/servlets/purl/1253765.
@article{osti_1253765,
title = {Quantitative structure parameters from the NMR spectroscopy of quadrupolar nuclei},
author = {Perras, Frederic A.},
abstractNote = {Here, nuclear magnetic resonance (NMR) spectroscopy is one of the most important characterization tools in chemistry, however, 3/4 of the NMR active nuclei are underutilized due to their quadrupolar nature. This short review centers on the development of methods that use solid-state NMR of quadrupolar nuclei for obtaining quantitative structural information. Namely, techniques using dipolar recoupling as well as the resolution afforded by double-rotation are presented for the measurement of spin–spin coupling between quadrupoles, enabling the measurement of internuclear distances and connectivities.},
doi = {10.1515/pac-2015-0801},
journal = {Pure and Applied Chemistry},
number = 1-2,
volume = 88,
place = {United States},
year = {Tue Dec 15 00:00:00 EST 2015},
month = {Tue Dec 15 00:00:00 EST 2015}
}
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